Article ; Online: Exsolution Modeling and Control to Improve the Catalytic Activity of Nanostructured Electrodes.
Advanced materials (Deerfield Beach, Fla.)
2023 Volume 35, Issue 16, Page(s) e2208984
Abstract: In situ exsolution for nanoscale electrode design has attracted considerable attention because of its promising activity and high stability. However, fundamental research on the mechanisms underlying particle growth remains insufficient. Herein, cation- ... ...
Abstract | In situ exsolution for nanoscale electrode design has attracted considerable attention because of its promising activity and high stability. However, fundamental research on the mechanisms underlying particle growth remains insufficient. Herein, cation-diffusion-determined exsolution is presented using an analytical model based on classical nucleation and diffusion. In the designed perovskite system, the exsolution trend for particle growth is consistent with this diffusion model, which strongly depends on the initial cation concentration and reduction conditions. Based on the experimental and theoretical results, a highly Ni-doped anode and an electrochemical switching technique are employed to promote exsolution and overcome growth limitations. The optimal cell exhibits an outstanding maximum power density of 1.7 W cm |
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Language | English |
Publishing date | 2023-03-10 |
Publishing country | Germany |
Document type | Journal Article |
ZDB-ID | 1474949-X |
ISSN | 1521-4095 ; 0935-9648 |
ISSN (online) | 1521-4095 |
ISSN | 0935-9648 |
DOI | 10.1002/adma.202208984 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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