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  1. Article ; Online: Cavity Enhanced Multi-Channels Gases Raman Spectrometer.

    Yang, Dewang / Liu, Qingsheng / Guo, Jinjia / Wu, Lulu / Kong, Andong

    Sensors (Basel, Switzerland)

    2021  Volume 21, Issue 11

    Abstract: Raman spectroscopy has the advantages of multi-component detection, with a simple device and wide concentration ranges, and it has been applied in environmental monitoring and gas logging. However, its low sensitivity has limited its further applications. ...

    Abstract Raman spectroscopy has the advantages of multi-component detection, with a simple device and wide concentration ranges, and it has been applied in environmental monitoring and gas logging. However, its low sensitivity has limited its further applications. In fact, the Raman signal is not weak, but the utilization efficiency of the Raman signal is low, and most of the signal is wasted. Given this, in this paper we report a cavity-enhanced multi-channel gas Raman spectrometer with an eight-sided cuvette. First, we simulated the Raman scattering intensity at angles from 30 degrees to 150 degrees. The simulation results showed that the signal intensity at an angle of 45° is 1.4 times that observed at 90°. Based on the simulation results, we designed a three-channel sample cell for higher sensitivity. The results of these experiments showed that the sensitivity could be increased by adding all signal together, and the limit of detection (LOD) for CO
    Language English
    Publishing date 2021-05-31
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2052857-7
    ISSN 1424-8220 ; 1424-8220
    ISSN (online) 1424-8220
    ISSN 1424-8220
    DOI 10.3390/s21113803
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: High-Sensitivity Raman Gas Probe for In Situ Multi-Component Gas Detection.

    Guo, Jinjia / Luo, Zhao / Liu, Qingsheng / Yang, Dewang / Dong, Hui / Huang, Shuke / Kong, Andong / Wu, Lulu

    Sensors (Basel, Switzerland)

    2021  Volume 21, Issue 10

    Abstract: Multiple reflection has been proven to be an effective method to enhance the gas detection sensitivity of Raman spectroscopy, while Raman gas probes based on the multiple reflection principle have been rarely reported on. In this paper, a multi- ... ...

    Abstract Multiple reflection has been proven to be an effective method to enhance the gas detection sensitivity of Raman spectroscopy, while Raman gas probes based on the multiple reflection principle have been rarely reported on. In this paper, a multi-reflection, cavity enhanced Raman spectroscopy (CERS) probe was developed and used for in situ multi-component gas detection. Owing to signal transmission through optical fibers and the miniaturization of multi-reflection cavity, the CERS probe exhibited the advantages of in situ detection and higher detection sensitivity. Compared with the conventional, backscattering Raman layout, the CERS probe showed a better performance for the detection of weak signals with a relatively lower background. According to the 3σ criteria, the detection limits of this CERS probe for methane, hydrogen, carbon dioxide and water vapor are calculated to be 44.5 ppm, 192.9 ppm, 317.5 ppm and 0.67%, respectively. The results presented the development of this CERS probe as having great potential to provide a new method for industrial, multi-component online gas detection.
    Language English
    Publishing date 2021-05-19
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2052857-7
    ISSN 1424-8220 ; 1424-8220
    ISSN (online) 1424-8220
    ISSN 1424-8220
    DOI 10.3390/s21103539
    Database MEDical Literature Analysis and Retrieval System OnLINE

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