Article: Correlation between X-ray crystallography and nuclear quadrupole resonance data: Antimony halides and chalcogenides
Russian journal of inorganic chemistry. 2010 Apr., v. 55, no. 4
2010
Abstract: For 53 compounds containing 73 crystallographic types of SbX n coordination polyhedra (X is a halogen and/or chalcogen), parameters of the Voronoi-Dirichlet (VD) polyhedra characterizing the asymmetry of the crystal field in the vicinity of Sb nuclei—the ...
Abstract | For 53 compounds containing 73 crystallographic types of SbX n coordination polyhedra (X is a halogen and/or chalcogen), parameters of the Voronoi-Dirichlet (VD) polyhedra characterizing the asymmetry of the crystal field in the vicinity of Sb nuclei—the displacement of the Sb nucleus from the centroid of its VD polyhedron (D A) and the noncentrosymmetry parameter of the atomic environment (A ns)—have been determined. There is a linear correlation between the experimental ¹²¹Sb quadrupole coupling constants determined from nuclear quadrupole resonance spectra and the D A and A ns values calculated from crystal-chemical data. |
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Language | English |
Dates of publication | 2010-04 |
Size | p. 523-529. |
Publisher | SP MAIK Nauka/Interperiodica |
Publishing place | Dordrecht |
Document type | Article |
ZDB-ID | 2223897-9 |
ISSN | 1531-8613 ; 0036-0236 |
ISSN (online) | 1531-8613 |
ISSN | 0036-0236 |
DOI | 10.1134/S0036023610040066 |
Database | NAL-Catalogue (AGRICOLA) |
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