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  1. Book ; Online: Chapter Solution-Processed Graphene-Based Transparent Conductive Electrodes as Ideal ITO Alternatives for Organic Solar Cells

    Stylianakis, Minas M. / Konios, Dimitrios / Petridis, Konstantinos / Kymakis, Emmanuel

    2017  

    Keywords Solid state chemistry ; organic solar cells, transparent electrodes, graphene, reduction
    Size 1 Online-Ressource
    Publisher InTechOpen
    Document type Book ; Online
    Note English ; Open Access
    HBZ-ID HT021051201
    Database ZB MED Catalogue: Medicine, Health, Nutrition, Environment, Agriculture

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  2. Article: A Low-Cost and Lithium-Free Hole Transport Layer for Efficient and Stable Normal Perovskite Solar Cells.

    Tzoganakis, Nikolaos / Tsikritzis, Dimitris / Chatzimanolis, Konstantinos / Zhuang, Xiaodong / Kymakis, Emmanuel

    Nanomaterials (Basel, Switzerland)

    2023  Volume 13, Issue 5

    Abstract: The most widely used material as a hole-transport layer (HTL) for effective normal perovskite solar cells (PSCs) is still 2,2',7,7'-Tetrakis[N, N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene (Spiro-OMeTAD), which requires heavy doping with the ... ...

    Abstract The most widely used material as a hole-transport layer (HTL) for effective normal perovskite solar cells (PSCs) is still 2,2',7,7'-Tetrakis[N, N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene (Spiro-OMeTAD), which requires heavy doping with the hydroscopic Lithium bis(trifluoromethanesulfonyl)imide (Li-ΤFSI). However, the long-term stability and performance of PCSs are frequently hampered by the residual insoluble dopants in the HTL, Li
    Language English
    Publishing date 2023-02-26
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2662255-5
    ISSN 2079-4991
    ISSN 2079-4991
    DOI 10.3390/nano13050883
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Resistive switching memories with enhanced durability enabled by mixed-dimensional perfluoroarene perovskite heterostructures.

    Loizos, Michalis / Rogdakis, Konstantinos / Luo, Weifan / Zimmermann, Paul / Hinderhofer, Alexander / Lukić, Jovan / Tountas, Marinos / Schreiber, Frank / Milić, Jovana V / Kymakis, Emmanuel

    Nanoscale horizons

    2024  

    Abstract: Hybrid halide perovskites are attractive candidates for resistive switching memories in neuromorphic computing applications due to their mixed ionic-electronic conductivity. Moreover, their exceptional optoelectronic characteristics make them effective ... ...

    Abstract Hybrid halide perovskites are attractive candidates for resistive switching memories in neuromorphic computing applications due to their mixed ionic-electronic conductivity. Moreover, their exceptional optoelectronic characteristics make them effective as semiconductors in photovoltaics, opening perspectives for self-powered memory elements. These devices, however, remain unexploited, which is related to the variability in their switching characteristics, weak endurance, and retention, which limit their performance and practical use. To address this challenge, we applied low-dimensional perovskite capping layers onto 3D mixed halide perovskites using two perfluoroarene organic cations, namely (perfluorobenzyl)ammonium and (perfluoro-1,4-phenylene)dimethylammonium iodide, forming Ruddlesden-Popper and Dion-Jacobson 2D perovskite phases, respectively. The corresponding mixed-dimensional perovskite heterostructures were used to fabricate resistive switching memories based on perovskite solar cell architectures, showing that the devices based on perfluoroarene heterostructures exhibited enhanced performance and stability in inert and ambient air atmosphere. This opens perspectives for multidimensional perovskite materials in durable self-powered memory elements in the future.
    Language English
    Publishing date 2024-05-20
    Publishing country England
    Document type Journal Article
    ISSN 2055-6764
    ISSN (online) 2055-6764
    DOI 10.1039/d4nh00104d
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: Solution-processed two-dimensional materials for next-generation photovoltaics

    Bellani, Sebastiano / Bartolotta, Antonino / Agresti, Antonio / Calogero, Giuseppe / Grancini, Giulia / Di Carlo, Aldo / Kymakis, Emmanuel / Bonaccorso, Francesco

    Chemical Society reviews. 2021 Nov. 1, v. 50, no. 21

    2021  

    Abstract: In the ever-increasing energy demand scenario, the development of novel photovoltaic (PV) technologies is considered to be one of the key solutions to fulfil the energy request. In this context, graphene and related two-dimensional (2D) materials (GRMs), ...

    Abstract In the ever-increasing energy demand scenario, the development of novel photovoltaic (PV) technologies is considered to be one of the key solutions to fulfil the energy request. In this context, graphene and related two-dimensional (2D) materials (GRMs), including nonlayered 2D materials and 2D perovskites, as well as their hybrid systems, are emerging as promising candidates to drive innovation in PV technologies. The mechanical, thermal, and optoelectronic properties of GRMs can be exploited in different active components of solar cells to design next-generation devices. These components include front (transparent) and back conductive electrodes, charge transporting layers, and interconnecting/recombination layers, as well as photoactive layers. The production and processing of GRMs in the liquid phase, coupled with the ability to “on-demand” tune their optoelectronic properties exploiting wet-chemical functionalization, enable their effective integration in advanced PV devices through scalable, reliable, and inexpensive printing/coating processes. Herein, we review the progresses in the use of solution-processed 2D materials in organic solar cells, dye-sensitized solar cells, perovskite solar cells, quantum dot solar cells, and organic–inorganic hybrid solar cells, as well as in tandem systems. We first provide a brief introduction on the properties of 2D materials and their production methods by solution-processing routes. Then, we discuss the functionality of 2D materials for electrodes, photoactive layer components/additives, charge transporting layers, and interconnecting layers through figures of merit, which allow the performance of solar cells to be determined and compared with the state-of-the-art values. We finally outline the roadmap for the further exploitation of solution-processed 2D materials to boost the performance of PV devices.
    Keywords energy ; graphene ; liquids ; quantum dots ; solar energy
    Language English
    Dates of publication 2021-1101
    Size p. 11870-11965.
    Publishing place The Royal Society of Chemistry
    Document type Article
    ZDB-ID 1472875-8
    ISSN 1460-4744 ; 0306-0012
    ISSN (online) 1460-4744
    ISSN 0306-0012
    DOI 10.1039/d1cs00106j
    Database NAL-Catalogue (AGRICOLA)

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  5. Article: Metal Halide Perovskites for High-Energy Radiation Detection.

    Kakavelakis, George / Gedda, Murali / Panagiotopoulos, Apostolis / Kymakis, Emmanuel / Anthopoulos, Thomas D / Petridis, Konstantinos

    Advanced science (Weinheim, Baden-Wurttemberg, Germany)

    2020  Volume 7, Issue 22, Page(s) 2002098

    Abstract: Metal halide perovskites (MHPs) have emerged as a frontrunner semiconductor technology for application in third generation photovoltaics while simultaneously making significant strides in other areas of optoelectronics. Photodetectors are one of the ... ...

    Abstract Metal halide perovskites (MHPs) have emerged as a frontrunner semiconductor technology for application in third generation photovoltaics while simultaneously making significant strides in other areas of optoelectronics. Photodetectors are one of the latest additions in an expanding list of applications of this fascinating family of materials. The extensive range of possible inorganic and hybrid perovskites coupled with their processing versatility and ability to convert external stimuli into easily measurable optical/electrical signals makes them an auspicious sensing element even for the high-energy domain of the electromagnetic spectrum. Key to this is the ability of MHPs to accommodate heavy elements while being able to form large, high-quality crystals and polycrystalline layers, making them one of the most promising emerging X-ray and
    Language English
    Publishing date 2020-10-11
    Publishing country Germany
    Document type Journal Article ; Review
    ZDB-ID 2808093-2
    ISSN 2198-3844
    ISSN 2198-3844
    DOI 10.1002/advs.202002098
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Advanced Photonic Processes for Photovoltaic and Energy Storage Systems.

    Sygletou, Maria / Petridis, Constantinos / Kymakis, Emmanuel / Stratakis, Emmanuel

    Advanced materials (Deerfield Beach, Fla.)

    2017  Volume 29, Issue 39

    Abstract: Solar-energy harvesting through photovoltaic (PV) conversion is the most promising technology for long-term renewable energy production. At the same time, significant progress has been made in the development of energy-storage (ES) systems, which are ... ...

    Abstract Solar-energy harvesting through photovoltaic (PV) conversion is the most promising technology for long-term renewable energy production. At the same time, significant progress has been made in the development of energy-storage (ES) systems, which are essential components within the cycle of energy generation, transmission, and usage. Toward commercial applications, the enhancement of the performance and competitiveness of PV and ES systems requires the adoption of precise, but simple and low-cost manufacturing solutions, compatible with large-scale and high-throughput production lines. Photonic processes enable cost-efficient, noncontact, highly precise, and selective engineering of materials via photothermal, photochemical, or photophysical routes. Laser-based processes, in particular, provide access to a plethora of processing parameters that can be tuned with a remarkably high degree of precision to enable innovative processing routes that cannot be attained by conventional approaches. The focus here is on the application of advanced light-driven approaches for the fabrication, as well as the synthesis, of materials and components relevant to PV and ES systems. Besides presenting recent advances on recent achievements, the existing limitations are outlined and future possibilities and emerging prospects discussed.
    Language English
    Publishing date 2017-08-24
    Publishing country Germany
    Document type Journal Article ; Review
    ZDB-ID 1474949-X
    ISSN 1521-4095 ; 0935-9648
    ISSN (online) 1521-4095
    ISSN 0935-9648
    DOI 10.1002/adma.201700335
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Graphene-Based Inverted Planar Perovskite Solar Cells: Advancements, Fundamental Challenges, and Prospects.

    Petridis, Konstantinos / Kakavelakis, George / Stylianakis, Minas M / Kymakis, Emmanuel

    Chemistry, an Asian journal

    2018  Volume 13, Issue 3, Page(s) 240–249

    Abstract: Metal halide based perovskite solar cells (PSCs) are considered among the most promising photovoltaic technologies, and already present certified efficiencies that surpass 22 %. The high performance and low fabrication cost make this technology ... ...

    Abstract Metal halide based perovskite solar cells (PSCs) are considered among the most promising photovoltaic technologies, and already present certified efficiencies that surpass 22 %. The high performance and low fabrication cost make this technology competitive with that of state-of-the-art thin-film photovoltaics. However, PSCs present some striking disadvantages that hinder their commercialization, including short operational lifetimes, high toxicity, and hysteresis effects, which lower both the performance and long-term stability of the devices. Herein, work conducted within the last two years is summarized with regard to addressing the challenges of low-temperature-processed planar inverted PSCs composed of graphene-based materials. In addition, critical challenges and the prospects of this field are discussed and some prospects for future research directions are proposed.
    Language English
    Publishing date 2018-02-02
    Publishing country Germany
    Document type Journal Article ; Review
    ISSN 1861-471X
    ISSN (online) 1861-471X
    DOI 10.1002/asia.201701626
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article: Electron field emission from graphene oxide wrinkles

    Viskadouros, Georgios / Konios, Dimitrios / Kymakis, Emmanuel / Stratakis, Emmanuel

    RSC advances. 2016 Jan. 04, v. 6, no. 4

    2016  

    Abstract: We report a simple and general solution-based methodology to support reduced graphene oxide layers (rGO) onto micro-spikes engraved on Si to produce high-aspect ratio wrinkles and sharp protrusions. It is observed that as the number of deposited rGO ... ...

    Abstract We report a simple and general solution-based methodology to support reduced graphene oxide layers (rGO) onto micro-spikes engraved on Si to produce high-aspect ratio wrinkles and sharp protrusions. It is observed that as the number of deposited rGO layers is increased the wrinkle density progressively increases complemented by a remarkable folding of graphene sheets at the vicinity of the spike tips. Highly efficient and stable field emission with low turn-on fields was observed, attributed to the local enhancement of the electric field at the wrinkled rGO protrusions. The ability to produce wrinkled graphene from solution could allow large area deposition providing prospects for the development of practical electron sources and advanced devices based on graphene oxide field emitters. The contribution of this hierarchical, hybrid film morphology is evaluated and discussed.
    Keywords electric field ; films (materials) ; graphene ; graphene oxide ; silicon
    Language English
    Dates of publication 2016-0104
    Size p. 2768-2773.
    Publishing place The Royal Society of Chemistry
    Document type Article
    ISSN 2046-2069
    DOI 10.1039/c5ra23031d
    Database NAL-Catalogue (AGRICOLA)

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  9. Article ; Online: Quinone-Enriched Conjugated Microporous Polymer as an Organic Cathode for Li-Ion Batteries.

    Ouyang, Zhipeng / Tranca, Diana / Zhao, Yazhen / Chen, Zhenying / Fu, Xiaobin / Zhu, Jinhui / Zhai, Guangqun / Ke, Changchun / Kymakis, Emmanuel / Zhuang, Xiaodong

    ACS applied materials & interfaces

    2021  Volume 13, Issue 7, Page(s) 9064–9073

    Abstract: Among various organic cathode materials, C═O group-enriched structures have attracted wide attention worldwide. However, small organic molecules have long suffered from dissolving in electrolytes during charge-discharge cycles. π-Conjugated microporous ... ...

    Abstract Among various organic cathode materials, C═O group-enriched structures have attracted wide attention worldwide. However, small organic molecules have long suffered from dissolving in electrolytes during charge-discharge cycles. π-Conjugated microporous polymers (CMPs) become one solution to address this issue. However, the synthesis strategy for CMPs with rich C═O groups and stable backbones remains a challenge. In this study, a novel CMP enriched with C═O units was synthesized through a highly efficient Diels-Alder reaction. The as-prepared CMP exhibited a fused carbon backbone and a semiconductive characteristic with a band gap of 1.4 eV. When used as an organic electrode material in LIBs, the insoluble and robust fused structure caused such CMPs to exhibit remarkable cycling stability (a 96.1% capacity retention at 0.2 A g
    Language English
    Publishing date 2021-02-14
    Publishing country United States
    Document type Journal Article
    ISSN 1944-8252
    ISSN (online) 1944-8252
    DOI 10.1021/acsami.1c00867
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Solution-processed two-dimensional materials for next-generation photovoltaics.

    Bellani, Sebastiano / Bartolotta, Antonino / Agresti, Antonio / Calogero, Giuseppe / Grancini, Giulia / Di Carlo, Aldo / Kymakis, Emmanuel / Bonaccorso, Francesco

    Chemical Society reviews

    2021  Volume 50, Issue 21, Page(s) 11870–11965

    Abstract: In the ever-increasing energy demand scenario, the development of novel photovoltaic (PV) technologies is considered to be one of the key solutions to fulfil the energy request. In this context, graphene and related two-dimensional (2D) materials (GRMs), ...

    Abstract In the ever-increasing energy demand scenario, the development of novel photovoltaic (PV) technologies is considered to be one of the key solutions to fulfil the energy request. In this context, graphene and related two-dimensional (2D) materials (GRMs), including nonlayered 2D materials and 2D perovskites, as well as their hybrid systems, are emerging as promising candidates to drive innovation in PV technologies. The mechanical, thermal, and optoelectronic properties of GRMs can be exploited in different active components of solar cells to design next-generation devices. These components include front (transparent) and back conductive electrodes, charge transporting layers, and interconnecting/recombination layers, as well as photoactive layers. The production and processing of GRMs in the liquid phase, coupled with the ability to "on-demand" tune their optoelectronic properties exploiting wet-chemical functionalization, enable their effective integration in advanced PV devices through scalable, reliable, and inexpensive printing/coating processes. Herein, we review the progresses in the use of solution-processed 2D materials in organic solar cells, dye-sensitized solar cells, perovskite solar cells, quantum dot solar cells, and organic-inorganic hybrid solar cells, as well as in tandem systems. We first provide a brief introduction on the properties of 2D materials and their production methods by solution-processing routes. Then, we discuss the functionality of 2D materials for electrodes, photoactive layer components/additives, charge transporting layers, and interconnecting layers through figures of merit, which allow the performance of solar cells to be determined and compared with the state-of-the-art values. We finally outline the roadmap for the further exploitation of solution-processed 2D materials to boost the performance of PV devices.
    Language English
    Publishing date 2021-11-01
    Publishing country England
    Document type Journal Article ; Review
    ZDB-ID 1472875-8
    ISSN 1460-4744 ; 0306-0012
    ISSN (online) 1460-4744
    ISSN 0306-0012
    DOI 10.1039/d1cs00106j
    Database MEDical Literature Analysis and Retrieval System OnLINE

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