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  1. Article: Identification of Natural and Anthropogenic Geochemical Processes Determining the Groundwater Quality in Port del Comte High Mountain Karst Aquifer (SE, Pyrenees)

    Herms, Ignasi / Jódar, Jorge / Soler, Albert / Lambán, Luís Javier / Custodio, Emilio / Núñez, Joan Agustí / Arnó, Georgina / Parcerisa, David / Jorge-Sánchez, Joan

    Water. 2021 Oct. 15, v. 13, no. 20

    2021  

    Abstract: The Port del Comte Massif (SE, Pyrenees) contains one of the most important vulnerable and strategic karst aquifers for supplying freshwater to the city of Barcelona (Spain). It is a fragile system, whose possible environmental impact is highly ... ...

    Abstract The Port del Comte Massif (SE, Pyrenees) contains one of the most important vulnerable and strategic karst aquifers for supplying freshwater to the city of Barcelona (Spain). It is a fragile system, whose possible environmental impact is highly conditioned by land use. To improve the hydrogeological knowledge of the system, between September 2013 and October 2015, a detailed fieldwork was carried out for the revision of the geological model, the inventory of water points, and the in situ physico-chemical characterization on major elements and isotopes of up to a total of 43 springs, as well as precipitation water. This paper focuses on the characterization of the geochemical processes that allow explanation of the observed chemical variability of groundwater drained by the pristine aquifer system to determine the origin of salinity. The results show that the main process is the dissolution of calcite and dolomite, followed by gypsum and halite, and a minor cation exchange-like process. Sulfur and oxygen isotopes from dissolved sulfate in the studied springs point out a geogenic origin related to the dissolution of gypsum from Triassic and Tertiary materials, and that the contribution from anthropogenic sources, like fertilizers, is lower. Nitrate in groundwater is not an important issue, with a few localized cases related with agricultural activities. The multidisciplinary approach has allowed the development of a consistent hydrogeological conceptual model of the functioning of the aquifer system, which can be replicated in other places to understand the geogenic character of the hydrogeochemistry.
    Keywords Triassic period ; aquifers ; calcite ; cations ; dissolved sulfates ; dolomite ; environmental impact ; freshwater ; groundwater ; gypsum ; hydrogeochemistry ; inventories ; karsts ; land use ; models ; nitrates ; oxygen ; salinity ; sulfur ; water quality ; Spain
    Language English
    Dates of publication 2021-1015
    Publishing place Multidisciplinary Digital Publishing Institute
    Document type Article
    ZDB-ID 2521238-2
    ISSN 2073-4441
    ISSN 2073-4441
    DOI 10.3390/w13202891
    Database NAL-Catalogue (AGRICOLA)

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  2. Article ; Online: Groundwater discharge in high-mountain watersheds: A valuable resource for downstream semi-arid zones. The case of the Bérchules River in Sierra Nevada (Southern Spain).

    Jódar, Jorge / Cabrera, José Antonio / Martos-Rosillo, Sergio / Ruiz-Constán, Ana / González-Ramón, Antonio / Lambán, Luis Javier / Herrera, Christian / Custodio, Emilio

    The Science of the total environment

    2017  Volume 593-594, Page(s) 760–772

    Abstract: Aquifers in permeable formations developed in high-mountain watersheds slow down the transfer of snowmelt to rivers, modifying rivers' flow pattern. To gain insight into the processes that control the hydrologic response of such systems the role played ... ...

    Abstract Aquifers in permeable formations developed in high-mountain watersheds slow down the transfer of snowmelt to rivers, modifying rivers' flow pattern. To gain insight into the processes that control the hydrologic response of such systems the role played by groundwater in an alpine basin located at the southeastern part of the Iberian Peninsula is investigated. As data in these environments is generally scarce and its variability is high, simple lumped parameter hydrological models that consider the groundwater component and snow accumulation and melting are needed. Instead of using existing models that use many parameters, the Témez lumped hydrological model of common use in Spain and Ibero-American countries is selected and modified to consider snow to get a simplified tool to separate hydrograph components. The result is the TDD model (Témez-Degree Day) which is applied in a high mountain watershed with seasonal snow cover in Southern Spain to help in quantifying groundwater recharge and determining the groundwater contribution to the outflow. Average groundwater recharge is about 23% of the precipitation, and groundwater contribution to total outflow ranges between 70 and 97%. Direct surface runoff is 1% of precipitation. These values depend on the existence of snow. Results are consistent with those obtained with chloride atmospheric deposition mass balances by other authors. They highlight the important role of groundwater in high mountain areas, which is enhanced by seasonal snow cover. Results compare well with other areas. This effect is often neglected in water planning, but can be easily taken into account just by extending the water balance tool in use, or any other, following the procedure that has being developed.
    Language English
    Publishing date 2017-09-01
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2017.03.190
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Vertical variation in the amplitude of the seasonal isotopic content of rainfall as a tool to jointly estimate the groundwater recharge zone and transit times in the Ordesa and Monte Perdido National Park aquifer system, north-eastern Spain.

    Jódar, Jorge / Custodio, Emilio / Lambán, Luis Javier / Martos-Rosillo, Sergio / Herrera-Lameli, Christian / Sapriza-Azuri, Gonzalo

    The Science of the total environment

    2016  Volume 573, Page(s) 505–517

    Abstract: The time series of stable water isotope composition relative to meteorological stations and springs located in the high mountainous zone of the Ordesa and Monte Perdido National Park are analyzed in order to study how the seasonal isotopic content of ... ...

    Abstract The time series of stable water isotope composition relative to meteorological stations and springs located in the high mountainous zone of the Ordesa and Monte Perdido National Park are analyzed in order to study how the seasonal isotopic content of precipitation propagates through the hydrogeological system in terms of the aquifer recharge zone elevation and transit time. The amplitude of the seasonal isotopic composition of precipitation and the mean isotopic content in rainfall vary along a vertical transect, with altitudinal slopes for δ
    Language English
    Publishing date 2016-12-15
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2016.08.117
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Groundwater flow in a closed basin with a saline shallow lake in a volcanic area: Laguna Tuyajto, northern Chilean Altiplano of the Andes.

    Herrera, Christian / Custodio, Emilio / Chong, Guillermo / Lambán, Luis Javier / Riquelme, Rodrigo / Wilke, Hans / Jódar, Jorge / Urrutia, Javier / Urqueta, Harry / Sarmiento, Alvaro / Gamboa, Carolina / Lictevout, Elisabeth

    The Science of the total environment

    2016  Volume 541, Page(s) 303–318

    Abstract: Laguna Tuyajto is a small, shallow saline water lake in the Andean Altiplano of northern Chile. In the eastern side it is fed by springs that discharge groundwater of the nearby volcanic aquifers. The area is arid: rainfall does not exceed 200mm/year in ... ...

    Abstract Laguna Tuyajto is a small, shallow saline water lake in the Andean Altiplano of northern Chile. In the eastern side it is fed by springs that discharge groundwater of the nearby volcanic aquifers. The area is arid: rainfall does not exceed 200mm/year in the rainiest parts. The stable isotopic content of spring water shows that the recharge is originated mainly from winter rain, snow melt, and to a lesser extent from some short and intense sporadic rainfall events. Most of the spring water outflowing in the northern side of Laguna Tuyajto is recharged in the Tuyajto volcano. Most of the spring water in the eastern side and groundwater are recharged at higher elevations, in the rims of the nearby endorheic basins of Pampa Colorada and Pampa Las Tecas to the East. The presence of tritium in some deep wells in Pampa Colorada and Pampa Las Tecas indicates recent recharge. Gas emission in recent volcanoes increase the sulfate content of atmospheric deposition and this is reflected in local groundwater. The chemical composition and concentration of spring waters are the result of meteoric water evapo-concentration, water-rock interaction, and mainly the dissolution of old and buried evaporitic deposits. Groundwater flow is mostly shallow due to a low permeability ignimbrite layer of regional extent, which also hinders brine spreading below and around the lake. High deep temperatures near the recent Tuyajto volcano explain the high dissolved silica contents and the δ(18)O shift to heavier values found in some of the spring waters. Laguna Tuyajto is a terminal lake where salts cumulate, mostly halite, but some brine transfer to the Salar de Aguas Calientes-3 cannot be excluded. The hydrogeological behavior of Laguna Tuyajto constitutes a model to understand the functioning of many other similar basins in other areas in the Andean Altiplano.
    Language English
    Publishing date 2016-01-15
    Publishing country Netherlands
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2015.09.060
    Database MEDical Literature Analysis and Retrieval System OnLINE

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