Artikel ; Online: Homonuclear Mixed-Valent Cobalt Imidazolate Framework for Oxygen-Evolution Electrocatalysis.
Chemistry (Weinheim an der Bergstrasse, Germany)
2016 Band 22, Heft 11, Seite(n) 3676–3680
Abstract: Herein, the synthesis and characterization of the first mixed-valent, purely cobalt-based zeolitic imidazolate framework, Co(II)3Co(III)2(C3H3N2)12 is presented. The material adopts the cubic garnet-type structure and combines high thermal stability of ... ...
| Abstract | Herein, the synthesis and characterization of the first mixed-valent, purely cobalt-based zeolitic imidazolate framework, Co(II)3Co(III)2(C3H3N2)12 is presented. The material adopts the cubic garnet-type structure and combines high thermal stability of up to 350 °C with excellent chemical stability. Electrochemical characterization showed that the cobalt centres are redox active and efficiently support oxygen evolution, thus rendering this framework a potential candidate for single-site heterogeneous catalysis based on earth-abundant elements. |
|---|---|
| Sprache | Englisch |
| Erscheinungsdatum | 2016-03-07 |
| Erscheinungsland | Germany |
| Dokumenttyp | Journal Article ; Research Support, Non-U.S. Gov't |
| ZDB-ID | 1478547-x |
| ISSN | 1521-3765 ; 0947-6539 |
| ISSN (online) | 1521-3765 |
| ISSN | 0947-6539 |
| DOI | 10.1002/chem.201504151 |
| Datenquelle | MEDical Literature Analysis and Retrieval System OnLINE |
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