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  1. Article: Non-collinear magnetism in the post-perovskite thiocyanate frameworks CsM(NCS)

    Geers, Madeleine / Lee, Jie Yie / Ling, Sanliang / Fabelo, Oscar / Cañadillas-Delgado, Laura / Cliffe, Matthew J

    Chemical science

    2023  Volume 14, Issue 13, Page(s) 3531–3540

    Abstract: ... ...

    Abstract AMX
    Language English
    Publishing date 2023-02-21
    Publishing country England
    Document type Journal Article
    ZDB-ID 2559110-1
    ISSN 2041-6539 ; 2041-6520
    ISSN (online) 2041-6539
    ISSN 2041-6520
    DOI 10.1039/d2sc06861c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Book ; Online: Non-collinear magnetism in the post-perovskite thiocyanate frameworks CsM(NCS)$_3$

    Geers, Madeleine / Lee, Jie Yie / Ling, Sanliang / Fabelo, Oscar / Cañadillas-Delgado, Laura / Cliffe, Matthew J.

    2023  

    Abstract: AMX$_3$ compounds are structurally diverse, a notable example being the post-perovskite structure which adopts a two-dimensional framework with corner- and edge-sharing octahedra. Few molecular post-perovskites are known and of these, none have reported ... ...

    Abstract AMX$_3$ compounds are structurally diverse, a notable example being the post-perovskite structure which adopts a two-dimensional framework with corner- and edge-sharing octahedra. Few molecular post-perovskites are known and of these, none have reported magnetic structures. Here we report the synthesis, structure and magnetic properties of molecular post-perovskites: CsNi(NCS)$_3$, a thiocyanate framework, and two new isostructural analogues CsCo(NCS)$_3$ and CsMn(NCS)$_3$. Magnetisation measurements show that all three compounds undergo magnetic order. CsNi(NCS)$_3$ (Curie temperature, $T_\mathrm{C} = 8.5(1)\;$K) and CsCo(NCS)$_3$ ($T_\mathrm{C} = 6.7(1)\;$K) order as weak ferromagnets. On the other hand, CsMn(NCS)$_3$ orders as an antiferromagnet (N\'eel temperature, $T_\mathrm{N}=16.8(8)\;$K). Neutron diffraction data of CsNi(NCS)$_3$ and CsMn(NCS)$_3$, show that both are non-collinear magnets. These results suggest molecular frameworks are fruitful ground for realising the spin textures required for the next generation of information technology.

    Comment: 9 pages, 5 figures
    Keywords Condensed Matter - Strongly Correlated Electrons ; Condensed Matter - Materials Science
    Subject code 530
    Publishing date 2023-01-10
    Publishing country us
    Document type Book ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  3. Article ; Online: Self-Assembled Surfactant-Polyoxovanadate Soft Materials as Tuneable Vanadium Oxide Cathode Precursors for Lithium-Ion Batteries.

    McNulty, Rory C / Penston, Keir / Amin, Sharad S / Stal, Sandro / Lee, Jie Yie / Samperi, Mario / Pérez-García, Lluïsa / Cameron, Jamie M / Johnson, Lee R / Amabilino, David B / Newton, Graham N

    Angewandte Chemie (International ed. in English)

    2023  Volume 62, Issue 12, Page(s) e202216066

    Abstract: The mixing of [ ... ...

    Abstract The mixing of [V
    Language English
    Publishing date 2023-02-09
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.202216066
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: Controlling multiple orderings in metal thiocyanate molecular perovskites A

    Lee, Jie Yie / Ling, Sanliang / Argent, Stephen P / Senn, Mark S / Cañadillas-Delgado, Laura / Cliffe, Matthew J

    Chemical science

    2021  Volume 12, Issue 10, Page(s) 3516–3525

    Abstract: We report four new A-site vacancy ordered thiocyanate double double perovskites, , A = ... ...

    Abstract We report four new A-site vacancy ordered thiocyanate double double perovskites, , A = K
    Language English
    Publishing date 2021-01-15
    Publishing country England
    Document type Journal Article
    ZDB-ID 2559110-1
    ISSN 2041-6539 ; 2041-6520
    ISSN (online) 2041-6539
    ISSN 2041-6520
    DOI 10.1039/d0sc06619b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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