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  1. Article ; Online: Iron-catalyzed coupling of three reactants.

    Lefèvre, Guillaume

    Science (New York, N.Y.)

    2021  Volume 374, Issue 6566, Page(s) 396–397

    Abstract: Vinyl boronates couple under mild conditions to two partners through carbon-carbon bonds. ...

    Abstract Vinyl boronates couple under mild conditions to two partners through carbon-carbon bonds.
    MeSH term(s) Catalysis ; Iron
    Chemical Substances Iron (E1UOL152H7)
    Language English
    Publishing date 2021-10-21
    Publishing country United States
    Document type Journal Article ; Comment
    ZDB-ID 128410-1
    ISSN 1095-9203 ; 0036-8075
    ISSN (online) 1095-9203
    ISSN 0036-8075
    DOI 10.1126/science.abl4762
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  2. Article ; Online: Reply to Musher.

    Stabler, Sarah / Lefèvre, Guillaume

    Clinical infectious diseases : an official publication of the Infectious Diseases Society of America

    2023  Volume 77, Issue 6, Page(s) 933–934

    Language English
    Publishing date 2023-06-22
    Publishing country United States
    Document type Letter ; Comment
    ZDB-ID 1099781-7
    ISSN 1537-6591 ; 1058-4838
    ISSN (online) 1537-6591
    ISSN 1058-4838
    DOI 10.1093/cid/ciad353
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: The crucial and multifaceted roles of main-group cations and their salts in iron-mediated cross-couplings.

    Wowk, Vincent / Lefèvre, Guillaume

    Dalton transactions (Cambridge, England : 2003)

    2022  Volume 51, Issue 28, Page(s) 10674–10680

    Abstract: While a broad variety of iron-catalyzed cross-couplings involve the use of main-group organometallics R-[M] as nucleophiles, the role of the [M] ...

    Abstract While a broad variety of iron-catalyzed cross-couplings involve the use of main-group organometallics R-[M] as nucleophiles, the role of the [M]
    MeSH term(s) Cations/chemistry ; Iron/chemistry ; Oxidation-Reduction ; Salts/chemistry
    Chemical Substances Cations ; Salts ; Iron (E1UOL152H7)
    Language English
    Publishing date 2022-07-19
    Publishing country England
    Document type Journal Article ; Review
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d2dt00871h
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  4. Article: Successful Introduction of Benralizumab for Eosinophilic Ascites.

    Belfeki, Nabil / Ghriss, Nouha / Zayet, Souheil / El Hedhili, Faten / Moini, Cyrus / Lefevre, Guillaume

    Biomedicines

    2024  Volume 12, Issue 1

    Abstract: Eosinophilic ascites is a rare disorder, reported in both adult and pediatric patients, characterized by high eosinophil counts in the peritoneal fluid. Eosinophilic ascites appears as a manifestation of various diseases such as parasitic and fungal ... ...

    Abstract Eosinophilic ascites is a rare disorder, reported in both adult and pediatric patients, characterized by high eosinophil counts in the peritoneal fluid. Eosinophilic ascites appears as a manifestation of various diseases such as parasitic and fungal infections, malignancy, and hypereosinophilic syndrome. It also represents an uncommon manifestation of eosinophilic gastroenteritis, usually treated with corticosteroids. We present the case of a 16-year-old woman with abdominal distention related to abundant ascites. Further work-up concluded that it was eosinophilic gastroenteritis complicated with eosinophilic ascites. The patient was on oral steroids for three weeks, but various abdominal relapses were observed, leading to the introduction of benralizumab, as a steroid-sparing therapy with a favorable outcome.
    Language English
    Publishing date 2024-01-06
    Publishing country Switzerland
    Document type Case Reports
    ZDB-ID 2720867-9
    ISSN 2227-9059
    ISSN 2227-9059
    DOI 10.3390/biomedicines12010117
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  5. Article ; Online: Divergent Fe-Mediated C-H Activation Paths Driven by Alkali Cations.

    Wowk, Vincent / Bauer, Alexis K / Radovic, Aleksa / Chamoreau, Lise-Marie / Neidig, Michael L / Lefèvre, Guillaume

    JACS Au

    2024  Volume 4, Issue 2, Page(s) 512–524

    Abstract: The association of the ferrous complex ... ...

    Abstract The association of the ferrous complex Fe
    Language English
    Publishing date 2024-01-19
    Publishing country United States
    Document type Journal Article
    ISSN 2691-3704
    ISSN (online) 2691-3704
    DOI 10.1021/jacsau.3c00649
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  6. Article ; Online: A Versatile, Functional Group-Tolerant, and Bench-Stable Iron Precatalyst for Building Arene and Triazine Rings by [2+2+2] Cycloadditions.

    Parisot, William / Haddad, Mansour / Phansavath, Phannarath / Lefèvre, Guillaume / Ratovelomanana-Vidal, Virginie

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2024  Volume 30, Issue 22, Page(s) e202400096

    Abstract: We report an efficient iron-catalyzed cycloaddition procedure leading to the construction of (hetero)aromatic rings by alkyne [2+2+2] cycloisomerization. This method relies on the use of an air-stable (N,N)Fe(II) precursor easily prepared from a ... ...

    Abstract We report an efficient iron-catalyzed cycloaddition procedure leading to the construction of (hetero)aromatic rings by alkyne [2+2+2] cycloisomerization. This method relies on the use of an air-stable (N,N)Fe(II) precursor easily prepared from a commercially available ligand derived from 1,10-phenanthroline, reduced in situ into a catalytically active non-innocent (N,N ⋅
    Language English
    Publishing date 2024-02-28
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1478547-X
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.202400096
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  7. Article: Total synthesis of insect sex pheromones: recent improvements based on iron-mediated cross-coupling chemistry.

    Gayon, Eric / Lefèvre, Guillaume / Guerret, Olivier / Tintar, Adrien / Chourreu, Pablo

    Beilstein journal of organic chemistry

    2023  Volume 19, Page(s) 158–166

    Abstract: In the current ecological context, use of insect sex pheromones as an alternative to conventional pesticides is in constant growth. In this report, we discuss the recent contributions brought by our groups in the field of iron-catalyzed cross-couplings ... ...

    Abstract In the current ecological context, use of insect sex pheromones as an alternative to conventional pesticides is in constant growth. In this report, we discuss the recent contributions brought by our groups in the field of iron-catalyzed cross-couplings applied to the synthesis of insect pheromones. The pivotal question of the development of sustainable synthetic procedures involving cheap, non-toxic and efficient additives is also discussed, as well as the mechanistic features guiding the reactivity of such catalytic systems.
    Language English
    Publishing date 2023-02-14
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2192461-2
    ISSN 1860-5397
    ISSN 1860-5397
    DOI 10.3762/bjoc.19.15
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  8. Article ; Online: Iron-Catalyzed Cross-Coupling of Thioesters and Organomanganese Reagents.

    Geiger, Valentin Jacob / Lefèvre, Guillaume / Fleischer, Ivana

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2022  Volume 28, Issue 62, Page(s) e202202212

    Abstract: We report a Fukuyama-type coupling of thioesters with aliphatic organomanganese reagents utilizing a cheap and easily available iron(III) precatalyst. The reactions exhibit a wide tolerance of solvents and functional groups, allowing for the conversion ... ...

    Abstract We report a Fukuyama-type coupling of thioesters with aliphatic organomanganese reagents utilizing a cheap and easily available iron(III) precatalyst. The reactions exhibit a wide tolerance of solvents and functional groups, allowing for the conversion of thioesters derived from natural products and pharmaceutical compounds. A strong steric impact from each reaction component (carboxylic moiety, thiol substituent and manganese reagent) was displayed, which enabled regioselective transformation of dithioesters. Mechanistic investigations showed that the released thiolate does not act as a mere spectator ligand, but rather positively influences the stability of intermediate alkyl(II)ferrates.
    MeSH term(s) Indicators and Reagents ; Catalysis ; Ferric Compounds ; Iron ; Sulfhydryl Compounds
    Chemical Substances Indicators and Reagents ; Ferric Compounds ; Iron (E1UOL152H7) ; Sulfhydryl Compounds
    Language English
    Publishing date 2022-09-01
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1478547-X
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.202202212
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  9. Article ; Online: The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts.

    Bakas, Nikki J / Chourreu, Pablo / Gayon, Eric / Lefèvre, Guillaume / Neidig, Michael L

    Chemical communications (Cambridge, England)

    2023  Volume 59, Issue 10, Page(s) 1317–1320

    Abstract: The molecular-level role of alkoxide salts, used as alternative additive ... ...

    Abstract The molecular-level role of alkoxide salts, used as alternative additive to
    Language English
    Publishing date 2023-01-31
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc06257g
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  10. Article ; Online: Iron-Catalyzed Cross-Coupling of

    Rousseau, Lidie / Desaintjean, Alexandre / Knochel, Paul / Lefèvre, Guillaume

    Molecules (Basel, Switzerland)

    2020  Volume 25, Issue 3

    Abstract: ... Various ... ...

    Abstract Various substituted
    MeSH term(s) Catalysis ; Indicators and Reagents/chemistry ; Iron/chemistry ; Magnesium/chemistry ; Manganese/chemistry ; Organometallic Compounds/chemistry ; Proton Magnetic Resonance Spectroscopy/methods
    Chemical Substances Indicators and Reagents ; Organometallic Compounds ; Manganese (42Z2K6ZL8P) ; Iron (E1UOL152H7) ; Magnesium (I38ZP9992A)
    Language English
    Publishing date 2020-02-07
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 1413402-0
    ISSN 1420-3049 ; 1431-5165 ; 1420-3049
    ISSN (online) 1420-3049
    ISSN 1431-5165 ; 1420-3049
    DOI 10.3390/molecules25030723
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