Article ; Online: Straightforward Synthesis of Pentagon-Embedded Expanded [11]Helicenes for Radiative Cooling Property.
Chemistry (Weinheim an der Bergstrasse, Germany)
2023 Volume 30, Issue 3, Page(s) e202302893
Abstract: Two new pentagon-embedded carbo[11]helicenes have been designed and synthesized in a three-step process, which are the first example of carbo[11]helicenes through the post-functionalization of twistacene. TD-DFT analyses indicate that both of them ... ...
| Abstract | Two new pentagon-embedded carbo[11]helicenes have been designed and synthesized in a three-step process, which are the first example of carbo[11]helicenes through the post-functionalization of twistacene. TD-DFT analyses indicate that both of them possess high enantiomerization barriers of 42.29 kcal/mol and 40.76 kcal/mol, respectively. They emit strong red fluorescence and can be chemically oxidized into stable cationic radicals upon addition of AgSbF |
|---|---|
| Language | English |
| Publishing date | 2023-11-20 |
| Publishing country | Germany |
| Document type | Journal Article |
| ZDB-ID | 1478547-X |
| ISSN | 1521-3765 ; 0947-6539 |
| ISSN (online) | 1521-3765 |
| ISSN | 0947-6539 |
| DOI | 10.1002/chem.202302893 |
| Database | MEDical Literature Analysis and Retrieval System OnLINE |
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