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  1. Article ; Online: Structural basis for different ω-agatoxin IVA sensitivities of the P-type and Q-type Ca

    Li, Zhangqiang / Cong, Ye / Wu, Tong / Wang, Tongtong / Lou, Xinyao / Yang, Xinyu / Yan, Nieng

    Cell research

    2024  

    Language English
    Publishing date 2024-03-05
    Publishing country England
    Document type Letter
    ZDB-ID 1319303-x
    ISSN 1748-7838 ; 1001-0602
    ISSN (online) 1748-7838
    ISSN 1001-0602
    DOI 10.1038/s41422-024-00940-5
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Regioselective Approach to β-Peroxyl Alcohols and Ethers from Alkenes

    Xu, Huan / Lou, Xinyao / Xie, Junrang / Qin, Ze / He, Huan / Gao, Xiaofang

    Journal of organic chemistry. 2022 July 13, v. 87, no. 15

    2022  

    Abstract: A different regioselective three-component reaction of alkenes, oxygen sources, and hydroperoxides mediated by ammonium iodine to α-oxyperoxidates has been developed. Mechanistic studies demonstrated that regioselective radical addition and subsequent ... ...

    Abstract A different regioselective three-component reaction of alkenes, oxygen sources, and hydroperoxides mediated by ammonium iodine to α-oxyperoxidates has been developed. Mechanistic studies demonstrated that regioselective radical addition and subsequent SN2 nucleophilic substitution were possible for the formation of products. In addition to the traditional pathway of SN2 reaction, that is, where nucleophiles attack the α-C atoms at the back side, an additional unusual transition configuration with the H₂O molecule attacking the α-C atom at the front side was obtained.
    Keywords Lewis bases ; alkenes ; ammonium ; hydroperoxides ; iodine ; organic chemistry ; oxygen ; regioselectivity
    Language English
    Dates of publication 2022-0713
    Size p. 9957-9968.
    Publishing place American Chemical Society
    Document type Article
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.2c00954
    Database NAL-Catalogue (AGRICOLA)

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  3. Article ; Online: Regioselective Approach to β-Peroxyl Alcohols and Ethers from Alkenes.

    Xu, Huan / Lou, Xinyao / Xie, Junrang / Qin, Ze / He, Huan / Gao, Xiaofang

    The Journal of organic chemistry

    2022  Volume 87, Issue 15, Page(s) 9957–9968

    Abstract: A different regioselective three-component reaction of alkenes, oxygen sources, and hydroperoxides mediated by ammonium iodine to α-oxyperoxidates has been developed. Mechanistic studies demonstrated that regioselective radical addition and subsequent ... ...

    Abstract A different regioselective three-component reaction of alkenes, oxygen sources, and hydroperoxides mediated by ammonium iodine to α-oxyperoxidates has been developed. Mechanistic studies demonstrated that regioselective radical addition and subsequent S
    Language English
    Publishing date 2022-07-13
    Publishing country United States
    Document type Journal Article
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.2c00954
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: Iodine-Initiated Dioxygenation of Aryl Alkenes Using tert-Butylhydroperoxides and Water: A Route to Vicinal Diols and Bisperoxides

    Gao, Xiaofang / Lin, Jiani / Zhang, Li / Lou, Xinyao / Guo, Guanghui / Peng, Na / Xu, Huan / Liu, Yi

    Journal of organic chemistry. 2021 Oct. 28, v. 86, no. 21

    2021  

    Abstract: An environment-friendly and efficient dioxygenation of aryl alkenes for the construction of vicinal diols has been developed in water with iodine as the catalyst and tert-butylhydroperoxides (TBHPs) as the oxidant. The protocol was efficient, sustainable, ...

    Abstract An environment-friendly and efficient dioxygenation of aryl alkenes for the construction of vicinal diols has been developed in water with iodine as the catalyst and tert-butylhydroperoxides (TBHPs) as the oxidant. The protocol was efficient, sustainable, and operationally simple. Detailed mechanistic studies indicated that one of the hydroxyl groups is derived from water and the other one is derived from TBHP. Additionally, the bisperoxides could be obtained in good yields with iodine as the catalyst, Na₂CO₃ as the additive, and propylene carbonate as the solvent, instead.
    Keywords catalysts ; glycols ; iodine ; organic chemistry ; oxidants ; propylene ; solvents
    Language English
    Dates of publication 2021-1028
    Size p. 15469-15480.
    Publishing place American Chemical Society
    Document type Article
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.1c01968
    Database NAL-Catalogue (AGRICOLA)

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  5. Article ; Online: Iodine-Initiated Dioxygenation of Aryl Alkenes Using

    Gao, Xiaofang / Lin, Jiani / Zhang, Li / Lou, Xinyao / Guo, Guanghui / Peng, Na / Xu, Huan / Liu, Yi

    The Journal of organic chemistry

    2021  Volume 86, Issue 21, Page(s) 15469–15480

    Abstract: An environment-friendly and efficient dioxygenation of aryl alkenes for the construction of vicinal diols has been developed in water with iodine as the catalyst ... ...

    Abstract An environment-friendly and efficient dioxygenation of aryl alkenes for the construction of vicinal diols has been developed in water with iodine as the catalyst and
    Language English
    Publishing date 2021-10-27
    Publishing country United States
    Document type Journal Article
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.1c01968
    Database MEDical Literature Analysis and Retrieval System OnLINE

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