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  1. Article: Mixed-Gas Selectivity Based on Pure Gas Permeation Measurements: An Approximate Model.

    Malakhov, Alexander O / Volkov, Vladimir V

    Membranes

    2021  Volume 11, Issue 11

    Abstract: An approximate model based on friction-coefficient formalism is developed to predict the mixed-gas permeability and selectivity of polymeric membranes. More specifically, the model is a modification of Kedem's approach to flux coupling. The crucial ... ...

    Abstract An approximate model based on friction-coefficient formalism is developed to predict the mixed-gas permeability and selectivity of polymeric membranes. More specifically, the model is a modification of Kedem's approach to flux coupling. The crucial assumption of the developed model is the division of the inverse local permeability of the mixture component into two terms: the inverse local permeability of the corresponding pure gas and the term proportional to the friction between penetrants. Analytical expressions for permeability and selectivity of polymeric membranes in mixed-gas conditions were obtained within the model. The input parameters for the model are ideal selectivity and solubility coefficients for pure gases. Calculations have shown that, depending on the input parameters and the value of the membrane Peclét number (the measure of coupling), there can be both a reduction and an enhancement of selectivity compared to the ideal selectivity. The deviation between real and ideal selectivity increases at higher Peclét numbers; in the limit of large Peclét numbers, the mixed-gas selectivity tends to the value of the ideal solubility selectivity. The model has been validated using literature data on mixed-gas separation of
    Language English
    Publishing date 2021-10-28
    Publishing country Switzerland
    Document type Journal Article
    ISSN 2077-0375
    ISSN 2077-0375
    DOI 10.3390/membranes11110833
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Temperature Dependence of Light Hydrocarbons Sorption and Transport in Dense Membranes Based on Tetradecyl Substituted Silicone Rubber.

    Malakhov, Alexander O / Sokolov, Stepan E / Grushevenko, Evgenia A / Volkov, Vladimir V

    Membranes

    2023  Volume 13, Issue 2

    Abstract: Solubility-selective polymer membranes are promising materials for ... ...

    Abstract Solubility-selective polymer membranes are promising materials for C
    Language English
    Publishing date 2023-01-18
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2614641-1
    ISSN 2077-0375
    ISSN 2077-0375
    DOI 10.3390/membranes13020124
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Mitigating of Thin-Film Composite PTMSP Membrane Aging by Introduction of Porous Rigid and Soft Branched Polymeric Additives.

    Bakhtin, Danila S / Malakhov, Alexander O / Volkov, Alexey V / Kulikov, Leonid A / Petrova, Inna V / Borisov, Ilya L / Bazhenov, Stepan D

    Membranes

    2022  Volume 13, Issue 1

    Abstract: This work was focused on the mitigation of physical aging in thin-film composite (TFC) membranes (selective layer ~1 μm) based on polymer intrinsic microporosity (PTMSP) by the introduction of both soft, branched polyethyleneimine (PEI), and rigid, ... ...

    Abstract This work was focused on the mitigation of physical aging in thin-film composite (TFC) membranes (selective layer ~1 μm) based on polymer intrinsic microporosity (PTMSP) by the introduction of both soft, branched polyethyleneimine (PEI), and rigid, porous aromatic framework PAF-11, polymer additives. Self-standing mixed-matrix membranes of thicknesses in the range of 20-30 μm were also prepared with the same polymer and fillers. Based on 450 days of monitoring, it was observed that the neat PTMSP composite membrane underwent a severe decline of its gas transport properties, and the resultant CO
    Language English
    Publishing date 2022-12-23
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2614641-1
    ISSN 2077-0375
    ISSN 2077-0375
    DOI 10.3390/membranes13010021
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article: Membranes Based on PTMSP/PVTMS Blends for Membrane Contactor Applications.

    Kalmykov, Denis / Balynin, Alexey / Yushkin, Alexey / Grushevenko, Evgenia / Sokolov, Stepan / Malakhov, Alexander / Volkov, Alexey / Bazhenov, Stepan

    Membranes

    2022  Volume 12, Issue 11

    Abstract: In this work, perspective polymeric materials were developed for membrane contactor applications, e.g., for the dissolved oxygen removal from amine ... ...

    Abstract In this work, perspective polymeric materials were developed for membrane contactor applications, e.g., for the dissolved oxygen removal from amine CO
    Language English
    Publishing date 2022-11-17
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2614641-1
    ISSN 2077-0375
    ISSN 2077-0375
    DOI 10.3390/membranes12111160
    Database MEDical Literature Analysis and Retrieval System OnLINE

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