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  1. Article ; Online: The problem of polyethylene waste – recent attempts for its mitigation

    Tiago, Gonçalo A.O. / Mariquito, António / Martins-Dias, Susete / Marques, Ana C.

    Science of the Total Environment. 2023 Sept., v. 892 p.164629-

    2023  

    Abstract: For the past two decades, with the increase in plastic consumption came a rise in plastic waste, with the bulk of it ending up in landfills, incinerated, recycled or leaking into the environment, especially in aquatic ecosystems. Plastic waste poses a ... ...

    Abstract For the past two decades, with the increase in plastic consumption came a rise in plastic waste, with the bulk of it ending up in landfills, incinerated, recycled or leaking into the environment, especially in aquatic ecosystems. Plastic waste poses a significant environmental threat and a wealth issue due to its non-biodegradability and recalcitrant nature. Polyethylene (PE) remains one of the major utilized polymers in different applications amid all the other types because of its low production costs, simplistic nature prone to be modified and historically predominant researched material. Since the common methods for plastic disposal are troubled by limitations, there is a growing need for more appropriate and environment friendly methods alternatives. This study highlights several ways that can be used to assist PE (bio)degradation and mitigate its waste impact. Biodegradation (microbiological activity driven) and photodegradation (radiation driven) are the most promising for PE waste control. The shape of the material (powder, film, particles, etc.), the composition of medium, additives and pH, temperature and incubation or exposure times contribute to plastic degradation efficiency. Moreover, radiation pretreatment can enhance the biodegradability of PE, providing a promising approach to fighting plastic pollution. This paper relates the most significant results regarding PE degradation studies followed by weight loss analysis, surface morphology changes, oxidation degree (for photodegradation) and mechanical properties assessment. All combined strategies are very promising to minimize the polyethylene impact. However, there is still a long way to go through. The degradation kinetics is still low for the currently available biotic or abiotic processes, and complete mineralization is thoroughly unseen.
    Keywords biodegradability ; biodegradation ; environment ; mineralization ; oxidation ; pH ; photolysis ; pollution ; polyethylene ; temperature ; wastes ; weight loss ; Photodegradation ; Photocatalysis ; Photo-pretreatment
    Language English
    Dates of publication 2023-09
    Publishing place Elsevier B.V.
    Document type Article ; Online
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2023.164629
    Database NAL-Catalogue (AGRICOLA)

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  2. Article ; Online: Biodegradable Microcapsules of Poly(Butylene Adipate-

    Aguiar, António / Mariquito, António / Gonçalves, Diogo / Pinho, Isabel / Marques, Ana C

    Polymers

    2023  Volume 15, Issue 3

    Abstract: Poly(butylene adipate- ...

    Abstract Poly(butylene adipate-
    Language English
    Publishing date 2023-01-28
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2527146-5
    ISSN 2073-4360 ; 2073-4360
    ISSN (online) 2073-4360
    ISSN 2073-4360
    DOI 10.3390/polym15030665
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Emulsion Stabilization Strategies for Tailored Isocyanate Microcapsules.

    Loureiro, Mónica V / Mariquito, António / Vale, Mário / Bordado, João C / Pinho, Isabel / Marques, Ana C

    Polymers

    2023  Volume 15, Issue 2

    Abstract: We report on the stabilization of an oil-in-water (O/W) emulsion to, combined with interfacial polymerization, produce core-shell polyurea microcapsules (MCs) containing isophorone diisocyanate (IPDI). These will act as crosslinkers for mono-component ... ...

    Abstract We report on the stabilization of an oil-in-water (O/W) emulsion to, combined with interfacial polymerization, produce core-shell polyurea microcapsules (MCs) containing isophorone diisocyanate (IPDI). These will act as crosslinkers for mono-component adhesives. The emulsion stabilization was evaluated using three types of stabilizers, a polysaccharide (gum arabic) emulsifier, a silicone surfactant (Dabco
    Language English
    Publishing date 2023-01-12
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2527146-5
    ISSN 2073-4360 ; 2073-4360
    ISSN (online) 2073-4360
    ISSN 2073-4360
    DOI 10.3390/polym15020403
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Multicomponent oxide microspheres with designed macroporosity (MICROSCAFS®): a customized platform for chemicals immobilization.

    Vale, Mário / Orišková, Sofia / Mariquito, António / Reis, Luís / Pinto, Moisés / Marques, Ana C

    RSC advances

    2023  Volume 13, Issue 19, Page(s) 12951–12965

    Abstract: A novel versatile, easily recoverable, and recyclable material platform is herein presented, consisting of multicomponent oxide microspheres, of silica-titania and silica-titania-hafnia composition, with tailored interconnected macroporosity (MICROSCAFS®) ...

    Abstract A novel versatile, easily recoverable, and recyclable material platform is herein presented, consisting of multicomponent oxide microspheres, of silica-titania and silica-titania-hafnia composition, with tailored interconnected macroporosity (MICROSCAFS®). When functionalized or loaded with desired species, they are potential enablers of emerging applications in environmental remediation, among other fields. We combine emulsion templating for the spherical shape of the particles, with an adapted sol-gel technique involving polymerization-induced phase separation by spinodal decomposition. An advantage of our method regards the employed mix of precursors, which prevents the use of specific gelation additives and porogens and allows a high reproducibility of MICROSCAFS®. We present insight into their formation mechanism using cryo-scanning electron microscopy, and a systematic study of the effect of multiple synthesis parameters on the MICROSCAFS® size and porosity. The composition of the silicon precursors has the most significant effect on fine-tuning the pores size, ranging from the nanometer to the micron scale. Mechanical properties are correlated with morphological features. Larger macroporosity (68% open porosity, estimated by X-ray computed tomography) leads to less stiffness, higher elastic recovery, and compressibility values up to 42%. We believe this study creates a base for consistent custom MICROSCAFS® production, with a design for various future applications.
    Language English
    Publishing date 2023-04-25
    Publishing country England
    Document type Journal Article
    ISSN 2046-2069
    ISSN (online) 2046-2069
    DOI 10.1039/d3ra00895a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: The problem of polyethylene waste - recent attempts for its mitigation.

    Tiago, Gonçalo A O / Mariquito, António / Martins-Dias, Susete / Marques, Ana C

    The Science of the total environment

    2023  Volume 892, Page(s) 164629

    Abstract: For the past two decades, with the increase in plastic consumption came a rise in plastic waste, with the bulk of it ending up in landfills, incinerated, recycled or leaking into the environment, especially in aquatic ecosystems. Plastic waste poses a ... ...

    Abstract For the past two decades, with the increase in plastic consumption came a rise in plastic waste, with the bulk of it ending up in landfills, incinerated, recycled or leaking into the environment, especially in aquatic ecosystems. Plastic waste poses a significant environmental threat and a wealth issue due to its non-biodegradability and recalcitrant nature. Polyethylene (PE) remains one of the major utilized polymers in different applications amid all the other types because of its low production costs, simplistic nature prone to be modified and historically predominant researched material. Since the common methods for plastic disposal are troubled by limitations, there is a growing need for more appropriate and environment friendly methods alternatives. This study highlights several ways that can be used to assist PE (bio)degradation and mitigate its waste impact. Biodegradation (microbiological activity driven) and photodegradation (radiation driven) are the most promising for PE waste control. The shape of the material (powder, film, particles, etc.), the composition of medium, additives and pH, temperature and incubation or exposure times contribute to plastic degradation efficiency. Moreover, radiation pretreatment can enhance the biodegradability of PE, providing a promising approach to fighting plastic pollution. This paper relates the most significant results regarding PE degradation studies followed by weight loss analysis, surface morphology changes, oxidation degree (for photodegradation) and mechanical properties assessment. All combined strategies are very promising to minimize the polyethylene impact. However, there is still a long way to go through. The degradation kinetics is still low for the currently available biotic or abiotic processes, and complete mineralization is thoroughly unseen.
    MeSH term(s) Polyethylene/metabolism ; Ecosystem ; Plastics/chemistry ; Polymers ; Biodegradation, Environmental
    Chemical Substances Polyethylene (9002-88-4) ; Plastics ; Polymers
    Language English
    Publishing date 2023-06-05
    Publishing country Netherlands
    Document type Journal Article ; Review
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2023.164629
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article: A construção e reperação naval

    Mariquito, António

    Economia : questôes económicas e sociais ; Ec Vol. 42 , p. 22-32

    1983  Volume 42, Page(s) 22–32

    Author's details António Mariquito
    Keywords Schiffsbau ; EG-Staaten ; Portugal
    Publishing place Lisboa
    Document type Article
    ZDB-ID 730890-5
    Database ECONomics Information System

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