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Article ; Online: Acoustic monitoring of laser-induced phase transitions in minerals: implication for Mars exploration with SuperCam.

Chide, Baptiste / Beyssac, Olivier / Gauthier, Michel / Benzerara, Karim / Estève, Imène / Boulliard, Jean-Claude / Maurice, Sylvestre / Wiens, Roger C

Scientific reports

2021 Volume 11, Issue 1, Page(s) 24019

Abstract: The SuperCam instrument suite onboard the Mars 2020 Perseverance rover uses the laser-induced breakdown spectroscopy (LIBS) technique to determine the elemental composition of rocks and soils of the Mars surface. It is associated with a microphone to ... ...

Abstract	The SuperCam instrument suite onboard the Mars 2020 Perseverance rover uses the laser-induced breakdown spectroscopy (LIBS) technique to determine the elemental composition of rocks and soils of the Mars surface. It is associated with a microphone to retrieve the physical properties of the ablated targets when listening to the laser-induced acoustic signal. In this study, we report the monitoring of laser-induced mineral phase transitions in acoustic data. Sound data recorded during the laser ablation of hematite, goethite and diamond showed a sharp increase of the acoustic signal amplitude over the first laser shots. Analyses of the laser-induced craters with Raman spectroscopy and scanning electron microscopy indicate that both hematite and goethite have been transformed into magnetite and that diamond has been transformed into amorphous-like carbon over the first laser shots. It is shown that these transitions are the root cause of the increase in acoustic signal, likely due to a change in target's physical properties as the material is transformed. These results give insights into the influence of the target's optical and thermal properties over the acoustic signal. But most importantly, in the context of the Mars surface exploration with SuperCam, as this behavior occurs only for specific phases, it demonstrates that the microphone data may help discriminating mineral phases whereas LIBS data only have limited capabilities.
Language	English
Publishing date	2021-12-15
Publishing country	England
Document type	Journal Article
ZDB-ID	2615211-3
ISSN	2045-2322 ; 2045-2322
ISSN (online)	2045-2322
ISSN	2045-2322
DOI	10.1038/s41598-021-03315-7
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Article: Long-Distance 3D Reconstructions Using Photogrammetry with Curiosity’s ChemCam Remote Micro-Imager in Gale Crater (Mars)

Caravaca, Gwénaël / Le Mouélic, Stéphane / Rapin, William / Dromart, Gilles / Gasnault, Olivier / Fau, Amaury / Newsom, Horton E. / Mangold, Nicolas / Le Deit, Laetitia / Maurice, Sylvestre / Wiens, Roger C. / Lanza, Nina L.

Remote Sensing. 2021 Oct. 12, v. 13, no. 20

2021

Abstract: The Mars Science Laboratory rover Curiosity landed in Gale crater (Mars) in August 2012. It has since been studying the lower part of the 5 km-high sedimentary pile that composes Gale’s central mound, Aeolis Mons. To assess the sedimentary record, the ... ...

Abstract	The Mars Science Laboratory rover Curiosity landed in Gale crater (Mars) in August 2012. It has since been studying the lower part of the 5 km-high sedimentary pile that composes Gale’s central mound, Aeolis Mons. To assess the sedimentary record, the MSL team mainly uses a suite of imagers onboard the rover, providing various pixel sizes and fields of view from close to long-range observations. For this latter, we notably use the Remote Micro Imager (RMI), a subsystem of the ChemCam instrument that acts as 700 mm-focal length telescope, providing the smallest angular pixel size of the set of cameras on the Remote Sensing Mast. The RMI allows observations of remote outcrops up to a few kilometers away from the rover. As retrieving 3D information is critical to characterize the structures of the sedimentary deposits, we describe in this work an experiment aiming at computing for the first time with RMI Digital Outcrop Models of these distant outcrops. We show that Structure-from-Motion photogrammetry can successfully be applied to suitable sets of individual RMI frames to reconstruct the 3D shape and relief of these distant outcrops. These results show that a dedicated set of observations can be envisaged to characterize the most interesting geological features surrounding the rover.
Keywords	cameras ; exhibitions ; land ; models ; photogrammetry ; remote sensing ; teams ; telescopes
Language	English
Dates of publication	2021-1012
Publishing place	Multidisciplinary Digital Publishing Institute
Document type	Article
ZDB-ID	2513863-7
ISSN	2072-4292
ISSN	2072-4292
DOI	10.3390/rs13204068
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: ChemCam's cost a drop in the Mars bucket.

Wiens, Roger C / Maurice, Sylvestre

Science (New York, N.Y.)

2008 Volume 322, Issue 5907, Page(s) 1464

Language	English
Publishing date	2008-12-05
Publishing country	United States
Document type	Comment ; Letter
ZDB-ID	128410-1
ISSN	1095-9203 ; 0036-8075
ISSN (online)	1095-9203
ISSN	0036-8075
DOI	10.1126/science.322.5907.1464a
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Article ; Online: OrganiCam: a lightweight time-resolved laser-induced luminescence imager and Raman spectrometer for planetary organic material characterization.

Gasda, Patrick J / Wiens, Roger C / Reyes-Newell, Adriana / Ganguly, Kumkum / Newell, Raymond T / Peterson, Charles / Sandoval, Benigno / Ott, Logan / Adikari, Samantha / Voit, Seychelles / Clegg, Samuel M / Misra, Anupam K / Acosta-Maeda, Tayro E / Quinn, Heather / Sharma, Shiv K / Dale, Magdalena / Love, Steven P / Maurice, Sylvestre

Applied optics

2021 Volume 60, Issue 13, Page(s) 3753–3763

Abstract: OrganiCam is a laser-induced luminescence imager and spectrometer designed for standoff organic and biosignature detection on planetary bodies. OrganiCam uses a diffused laser beam (12° cone) to cover a large area at several meters distance and records ... ...

Abstract	OrganiCam is a laser-induced luminescence imager and spectrometer designed for standoff organic and biosignature detection on planetary bodies. OrganiCam uses a diffused laser beam (12° cone) to cover a large area at several meters distance and records luminescence on half of its intensified detector. The diffuser can be removed to record Raman and fluorescence spectra from a small spot from 2 m standoff distance. OrganiCam's small size and light weight makes it ideal for surveying organics on planetary surfaces. We have designed and built a brassboard version of the OrganiCam instrument and performed initial tests of the system.
Language	English
Publishing date	2021-05-13
Publishing country	United States
Document type	Journal Article
ISSN	1539-4522
ISSN (online)	1539-4522
DOI	10.1364/AO.421291
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Article: Origin and composition of three heterolithic boulder- and cobble-bearing deposits overlying the Murray and Stimson formations, Gale Crater, Mars.

Icarus

2020 Volume 350, Page(s) 113897

Abstract: Heterolithic, boulder-containing, pebble-strewn surfaces occur along the lower slopes of Aeolis Mons ("Mt. Sharp") in Gale crater, Mars. They were observed in HiRISE images acquired from orbit prior to the landing of the Curiosity rover. The rover was ... ...

Abstract	Heterolithic, boulder-containing, pebble-strewn surfaces occur along the lower slopes of Aeolis Mons ("Mt. Sharp") in Gale crater, Mars. They were observed in HiRISE images acquired from orbit prior to the landing of the Curiosity rover. The rover was used to investigate three of these units named Blackfoot, Brandberg, and Bimbe between sols 1099 and 1410. These unconsolidated units overlie the lower Murray formation that forms the base of Mt. Sharp, and consist of pebbles, cobbles and boulders. Blackfoot also overlies portions of the Stimson formation, which consists of eolian sandstone that is understood to significantly postdate the dominantly lacustrine deposition of the Murray formation. Blackfoot is elliptical in shape (62 × 26 m), while Brandberg is nearly circular (50 × 55 m), and Bimbe is irregular in shape, covering about ten times the area of the other two. The largest boulders are 1.5-2.5 m in size and are interpreted to be sandstones. As seen from orbit, some boulders are light-toned and others are dark-toned. Rover-based observations show that both have the same gray appearance from the ground and their apparently different albedos in orbital observations result from relatively flat sky-facing surfaces. Chemical observations show that two clasts of fine sandstone at Bimbe have similar compositions and morphologies to nine ChemCam targets observed early in the mission, near Yellowknife Bay, including the Bathurst Inlet outcrop, and to at least one target (Pyramid Hills, Sol 692) and possibly a cap rock unit just north of Hidden Valley, locations that are several kilometers apart in distance and tens of meters in elevation. These findings may suggest the earlier existence of draping strata, like the Stimson formation, that would have overlain the current surface from Bimbe to Yellowknife Bay. Compositionally these extinct strata could be related to the Siccar Point group to which the Stimson formation belongs. Dark, massive sandstone blocks at Bimbe are chemically distinct from blocks of similar morphology at Bradbury Rise, except for a single float block, Oscar (Sol 516). Conglomerates observed along a low, sinuous ridge at Bimbe consist of matrix and clasts with compositions similar to the Stimson formation, suggesting that stream beds likely existed nearly contemporaneously with the dunes that eventually formed the Stimson formation, or that they had the same source material. In either case, they represent a later pulse of fluvial activity relative to the lakes associated with the Murray formation. These three units may be local remnants of infilled impact craters (especially circular-shaped Brandberg), decayed buttes, patches of unconsolidated fluvial deposits, or residual mass-movement debris. Their incorporation of Stimson and Murray rocks, the lack of lithification, and appearance of being erosional remnants suggest that they record erosion and deposition events that post-date the exposure of the Stimson formation.
Language	English
Publishing date	2020-06-06
Publishing country	United States
Document type	Journal Article
ISSN	0019-1035
ISSN	0019-1035
DOI	10.1016/j.icarus.2020.113897
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Article ; Online: Planetary geochemical investigations using Raman and laser-induced breakdown spectroscopy.

Clegg, Samuel M / Wiens, Roger / Misra, Anupam K / Sharma, Shiv K / Lambert, James / Bender, Steven / Newell, Raymond / Nowak-Lovato, Kristy / Smrekar, Sue / Dyar, M Darby / Maurice, Sylvestre

Applied spectroscopy

2014 Volume 68, Issue 9, Page(s) 925–936

Abstract: An integrated Raman spectroscopy and laser-induced breakdown spectroscopy (LIBS) instrument is a valuable geoanalytical tool for future planetary missions to Mars, Venus, and elsewhere. The ChemCam instrument operating on the Mars Curiosity rover ... ...

Abstract	An integrated Raman spectroscopy and laser-induced breakdown spectroscopy (LIBS) instrument is a valuable geoanalytical tool for future planetary missions to Mars, Venus, and elsewhere. The ChemCam instrument operating on the Mars Curiosity rover includes a remote LIBS instrument. An integrated Raman-LIBS spectrometer (RLS) based on the ChemCam architecture could be used as a reconnaissance tool for other contact instruments as well as a primary science instrument capable of quantitative mineralogical and geochemical analyses. Replacing one of the ChemCam spectrometers with a miniature transmission spectrometer enables a Raman spectroscopy mineralogical analysis to be performed, complementing the LIBS chemical analysis while retaining an overall architecture resembling ChemCam. A prototype transmission spectrometer was used to record Raman spectra under both Martian and Venus conditions. Two different high-pressure and high-temperature cells were used to collect the Raman and LIBS spectra to simulate surface conditions on Venus. The resulting LIBS spectra were used to generate a limited partial least squares Venus calibration model for the major elements. These experiments demonstrate the utility and feasibility of a combined RLS instrument.
Language	English
Publishing date	2014
Publishing country	United States
Document type	Journal Article
ISSN	1943-3530
ISSN (online)	1943-3530
DOI	10.1366/13-07386
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Article ; Online: The dynamic atmospheric and aeolian environment of Jezero crater, Mars.

Newman, Claire E / Hueso, Ricardo / Lemmon, Mark T / Munguira, Asier / Vicente-Retortillo, Álvaro / Apestigue, Víctor / Martínez, Germán M / Toledo, Daniel / Sullivan, Rob / Herkenhoff, Ken E / de la Torre Juárez, Manuel / Richardson, Mark I / Stott, Alexander E / Murdoch, Naomi / Sanchez-Lavega, Agustín / Wolff, Michael J / Arruego, Ignacio / Sebastián, Eduardo / Navarro, Sara /

Gómez-Elvira, Javier / Tamppari, Leslie / Viúdez-Moreiras, Daniel / Harri, Ari-Matti / Genzer, Maria / Hieta, Maria / Lorenz, Ralph D / Conrad, Pan / Gómez, Felipe / McConnochie, Timothy H / Mimoun, David / Tate, Christian / Bertrand, Tanguy / Bell, James F / Maki, Justin N / Rodriguez-Manfredi, Jose Antonio / Wiens, Roger C / Chide, Baptiste / Maurice, Sylvestre / Zorzano, Maria-Paz / Mora, Luis / Baker, Mariah M / Banfield, Don / Pla-Garcia, Jorge / Beyssac, Olivier / Brown, Adrian / Clark, Ben / Lepinette, Alain / Montmessin, Franck / Fischer, Erik / Patel, Priyaben / Del Río-Gaztelurrutia, Teresa / Fouchet, Thierry / Francis, Raymond / Guzewich, Scott D

Science advances

2022 Volume 8, Issue 21, Page(s) eabn3783

Abstract: Despite the importance of sand and dust to Mars geomorphology, weather, and exploration, the processes that move sand and that raise dust to maintain Mars' ubiquitous dust haze and to produce dust storms have not been well quantified in situ, with ... ...

Abstract	Despite the importance of sand and dust to Mars geomorphology, weather, and exploration, the processes that move sand and that raise dust to maintain Mars' ubiquitous dust haze and to produce dust storms have not been well quantified in situ, with missions lacking either the necessary sensors or a sufficiently active aeolian environment. Perseverance rover's novel environmental sensors and Jezero crater's dusty environment remedy this. In Perseverance's first 216 sols, four convective vortices raised dust locally, while, on average, four passed the rover daily, over 25% of which were significantly dusty ("dust devils"). More rarely, dust lifting by nonvortex wind gusts was produced by daytime convection cells advected over the crater by strong regional daytime upslope winds, which also control aeolian surface features. One such event covered 10 times more area than the largest dust devil, suggesting that dust devils and wind gusts could raise equal amounts of dust under nonstorm conditions.
Language	English
Publishing date	2022-05-25
Publishing country	United States
Document type	Journal Article
ZDB-ID	2810933-8
ISSN	2375-2548 ; 2375-2548
ISSN (online)	2375-2548
ISSN	2375-2548
DOI	10.1126/sciadv.abn3783
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Article: Analysis of water ice and water ice/soil mixtures using laser-induced breakdown spectroscopy: application to Mars polar exploration.

Arp, Zane A / Cremers, David A / Wiens, Roger C / Wayne, David M / Sallé, Béatrice / Maurice, Sylvestre

Applied spectroscopy

2004 Volume 58, Issue 8, Page(s) 897–909

Abstract: Recently, laser-induced breakdown spectroscopy (LIBS) has been developed for the elemental analysis of geological samples for application to space exploration. There is also interest in using the technique for the analysis of water ice and ice/dust ... ...

Abstract	Recently, laser-induced breakdown spectroscopy (LIBS) has been developed for the elemental analysis of geological samples for application to space exploration. There is also interest in using the technique for the analysis of water ice and ice/dust mixtures located at the Mars polar regions. The application is a compact instrument for a lander or rover to the Martian poles to interrogate stratified layers of ice and dusts that contain a record of past geologic history, believed to date back several million years. Here we present results of a study of the use of LIBS for the analysis of water ice and ice/dust mixtures in situ and at short stand-off distances (< 6.5 m) using experimental parameters appropriate for a compact instrument. Characteristics of LIBS spectra of water ice, ice/soil mixtures, element detection limits, and the ability to ablate through ice samples to monitor subsurface dust deposits are discussed.
MeSH term(s)	Extraterrestrial Environment/chemistry ; Geology/instrumentation ; Geology/methods ; Ice/analysis ; Lasers ; Mars ; Spectrum Analysis/instrumentation ; Spectrum Analysis/methods ; Water/analysis
Chemical Substances	Ice ; Water (059QF0KO0R)
Language	English
Publishing date	2004-08
Publishing country	United States
Document type	Journal Article ; Research Support, Non-U.S. Gov't ; Research Support, U.S. Gov't, Non-P.H.S.
ISSN	0003-7028
ISSN	0003-7028
DOI	10.1366/0003702041655377
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Article ; Online: Evidence for water ice near Mercury's north pole from MESSENGER Neutron Spectrometer measurements.

Lawrence, David J / Feldman, William C / Goldsten, John O / Maurice, Sylvestre / Peplowski, Patrick N / Anderson, Brian J / Bazell, David / McNutt, Ralph L / Nittler, Larry R / Prettyman, Thomas H / Rodgers, Douglas J / Solomon, Sean C / Weider, Shoshana Z

Science (New York, N.Y.)

2013 Volume 339, Issue 6117, Page(s) 292–296

Abstract: Measurements by the Neutron Spectrometer on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft show decreases in the flux of epithermal and fast neutrons from Mercury's north polar region that are consistent with the ...

Abstract	Measurements by the Neutron Spectrometer on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft show decreases in the flux of epithermal and fast neutrons from Mercury's north polar region that are consistent with the presence of water ice in permanently shadowed regions. The neutron data indicate that Mercury's radar-bright polar deposits contain, on average, a hydrogen-rich layer more than tens of centimeters thick beneath a surficial layer 10 to 30 cm thick that is less rich in hydrogen. Combined neutron and radar data are best matched if the buried layer consists of nearly pure water ice. The upper layer contains less than 25 weight % water-equivalent hydrogen. The total mass of water at Mercury's poles is inferred to be 2 × 10(16) to 10(18) grams and is consistent with delivery by comets or volatile-rich asteroids.
Language	English
Publishing date	2013-01-18
Publishing country	United States
Document type	Journal Article ; Research Support, U.S. Gov't, Non-P.H.S.
ZDB-ID	128410-1
ISSN	1095-9203 ; 0036-8075
ISSN (online)	1095-9203
ISSN	0036-8075
DOI	10.1126/science.1229953
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Article ; Online: Compositionally and density stratified igneous terrain in Jezero crater, Mars.

Wiens, Roger C / Udry, Arya / Beyssac, Olivier / Quantin-Nataf, Cathy / Mangold, Nicolas / Cousin, Agnès / Mandon, Lucia / Bosak, Tanja / Forni, Olivier / McLennan, Scott M / Sautter, Violaine / Brown, Adrian / Benzerara, Karim / Johnson, Jeffrey R / Mayhew, Lisa / Maurice, Sylvestre / Anderson, Ryan B / Clegg, Samuel M / Crumpler, Larry /

Gabriel, Travis S J / Gasda, Patrick / Hall, James / Horgan, Briony H N / Kah, Linda / Legett, Carey / Madariaga, Juan Manuel / Meslin, Pierre-Yves / Ollila, Ann M / Poulet, Francois / Royer, Clement / Sharma, Shiv K / Siljeström, Sandra / Simon, Justin I / Acosta-Maeda, Tayro E / Alvarez-Llamas, Cesar / Angel, S Michael / Arana, Gorka / Beck, Pierre / Bernard, Sylvain / Bertrand, Tanguy / Bousquet, Bruno / Castro, Kepa / Chide, Baptiste / Clavé, Elise / Cloutis, Ed / Connell, Stephanie / Dehouck, Erwin / Dromart, Gilles / Fischer, Woodward / Fouchet, Thierry / Francis, Raymond / Frydenvang, Jens / Gasnault, Olivier / Gibbons, Erin / Gupta, Sanjeev / Hausrath, Elisabeth M / Jacob, Xavier / Kalucha, Hemani / Kelly, Evan / Knutsen, Elise / Lanza, Nina / Laserna, Javier / Lasue, Jeremie / Le Mouélic, Stéphane / Leveille, Richard / Lopez Reyes, Guillermo / Lorenz, Ralph / Manrique, Jose Antonio / Martinez-Frias, Jesus / McConnochie, Tim / Melikechi, Noureddine / Mimoun, David / Montmessin, Franck / Moros, Javier / Murdoch, Naomi / Pilleri, Paolo / Pilorget, Cedric / Pinet, Patrick / Rapin, William / Rull, Fernando / Schröder, Susanne / Shuster, David L / Smith, Rebecca J / Stott, Alexander E / Tarnas, Jesse / Turenne, Nathalie / Veneranda, Marco / Vogt, David S / Weiss, Benjamin P / Willis, Peter / Stack, Kathryn M / Williford, Kenneth H / Farley, Kenneth A

Science advances

2022 Volume 8, Issue 34, Page(s) eabo3399

Abstract: Before Perseverance, Jezero crater's floor was variably hypothesized to have a lacustrine, lava, volcanic airfall, or aeolian origin. SuperCam observations in the first 286 Mars days on Mars revealed a volcanic and intrusive terrain with compositional ... ...

Abstract	Before Perseverance, Jezero crater's floor was variably hypothesized to have a lacustrine, lava, volcanic airfall, or aeolian origin. SuperCam observations in the first 286 Mars days on Mars revealed a volcanic and intrusive terrain with compositional and density stratification. The dominant lithology along the traverse is basaltic, with plagioclase enrichment in stratigraphically higher locations. Stratigraphically lower, layered rocks are richer in normative pyroxene. The lowest observed unit has the highest inferred density and is olivine-rich with coarse (1.5 millimeters) euhedral, relatively unweathered grains, suggesting a cumulate origin. This is the first martian cumulate and shows similarities to martian meteorites, which also express olivine disequilibrium. Alteration materials including carbonates, sulfates, perchlorates, hydrated silicates, and iron oxides are pervasive but low in abundance, suggesting relatively brief lacustrine conditions. Orbital observations link the Jezero floor lithology to the broader Nili-Syrtis region, suggesting that density-driven compositional stratification is a regional characteristic.
Language	English
Publishing date	2022-08-25
Publishing country	United States
Document type	Journal Article
ZDB-ID	2810933-8
ISSN	2375-2548 ; 2375-2548
ISSN (online)	2375-2548
ISSN	2375-2548
DOI	10.1126/sciadv.abo3399
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