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Article: Torrefied agro-industrial residue as filler in natural rubber compounds

Torres, Lennard Farrales / Mccaffrey, Zachariah / Washington, Wisdom / Williams, Tina G. / Wood, Delilah F. / Orts, William J. / Mcmahan, Colleen M.

Journal of applied polymer science. 2021 July 20, v. 138, no. 28

2021  

Abstract: This study explored the feasibility of using torrefied biomass as a reinforcing filler in natural rubber compounds. Carbon black was then replaced with the torrefied biomass in elastomer formulations for concentration varying from 0 to 100 percent (60 ... ...

Abstract This study explored the feasibility of using torrefied biomass as a reinforcing filler in natural rubber compounds. Carbon black was then replaced with the torrefied biomass in elastomer formulations for concentration varying from 0 to 100 percent (60 phr total). Their influence on the curing process, dynamic properties, and mechanical properties was investigated. Results were compared with the properties of vulcanizates containing solely carbon black fillers. Time to cure (t90) for compounds with torrefied biomass fillers increased, while filler-filler interactions (delta G') decreased, compared to carbon black controls. At low strains, the tan d values of the torrefied fillers vulcanizates were similar to the controls. Incorporation of torrefied biomass into natural rubber decreased compound tensile strength and modulus but increased elongation. Replacement with torrefied fillers resulted in a weaker filler network in the matrix. Still, results showed that moderate substitution concentrations (~20 phr) could be feasible for some natural rubber applications.
Keywords biomass ; polymers ; rubber ; soot ; tensile strength
Language English
Dates of publication 2021-0720
Document type Article
ZDB-ID 1491105-X
ISSN 1097-4628 ; 0021-8995
ISSN (online) 1097-4628
ISSN 0021-8995
DOI 10.1002/app.50684
Database NAL-Catalogue (AGRICOLA)

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