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Article: Selective emitter with core–shell nanosphere structure for thermophotovoltaic systems

Meng, Caifeng / Liu, Yunpeng / Xu, Zhiheng / Wang, Hongyu / Tang, Xiaobin

Energy. 2022 Jan. 15, v. 239

2022

Abstract: For thermophotovoltaic (TPV) systems, traditional thermal emitters waste considerable energy due to the mismatch between the thermal radiation power spectrum and the bandgap of the photovoltaic (PV) cells. Here, a core–shell nanosphere (CSN) structured ... ...

Abstract	For thermophotovoltaic (TPV) systems, traditional thermal emitters waste considerable energy due to the mismatch between the thermal radiation power spectrum and the bandgap of the photovoltaic (PV) cells. Here, a core–shell nanosphere (CSN) structured selective emitter was designed and optimized on the basis of numerical calculation. By iteratively optimizing the geometric parameters of the CSN emitter, the average emissivity of the CSN emitter exceeds 0.93 within the bandgap and is suppressed to 0.13 outside the bandgap. The mechanism of selective emission characteristics is elucidated in detail. Additionally, the simulation results demonstrate that the CSN emitter exhibits emissivity insensitivity to polarization and incident angle. For the TPV system with the InGaAs cells, an output power density of 0.594 W/cm² and a system efficiency of 12.83% are achieved at a CSN emitter temperature of 1338 K. The obtained output power density is relatively high, i.e., 3.2 times that of the previously reported record (0.184 W/cm²). And ultimately, the core–shell structural nanoparticles were synthesized by solution–processed and their performance was tested. This research improves the performance of the selective emitter and paves the way for a more efficient design of TPV systems.
Keywords	angle of incidence ; energy ; geometry ; nanospheres ; temperature ; thermal radiation
Language	English
Dates of publication	2022-0115
Publishing place	Elsevier Ltd
Document type	Article
ZDB-ID	2019804-8
ISSN	0360-5442 ; 0360-5442
ISSN (online)	0360-5442
ISSN	0360-5442
DOI	10.1016/j.energy.2021.121884
Database	NAL-Catalogue (AGRICOLA)

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Article: High-temperature and radiation-resistant spinel-type ferrite coating for thermo-optical conversion in radioisotope thermophotovoltaic generators

Wang, Hongyu / Xu, Zhiheng / Yuan, Zicheng / Liu, Kai / Meng, Caifeng / Tang, Xiaobin

Energy. 2022 Jan. 15, v. 239

2022

Abstract: High-temperature radioisotope heat source surface coated with excellent performance of thermo-optical conversion coating can greatly improve thermophotovoltaic energy utilization. However, long-term high-temperature and radiation resistance of the thermo- ...

Abstract	High-temperature radioisotope heat source surface coated with excellent performance of thermo-optical conversion coating can greatly improve thermophotovoltaic energy utilization. However, long-term high-temperature and radiation resistance of the thermo-optical conversion pose a great challenge. In this work, spinel-type ferrite thermo-optical conversion coating was proposed to improve the heat and irradiation stability and output power of a radioisotope thermophotovoltaic (RTPV) prototype. Under the continuous irradiation of 32.64 kGy for 24 h at 1400 K, the emissivity of the spinel-type ferrite thermo-optical conversion coating could maintain more than 90%. In addition, the surface morphology of the coating was changed under high temperature, which enhanced its surface emissivity. Spinel-type ferrite thermo-optical conversion coating was applied to the RTPV prototype, which achieved a maximum output power of 144.23 mW. Compared with the RTPV prototype without coating, the overall output increased to 181.51%. Spinel-type ferrite thermo-optical conversion coating showed great application potential in the fields of thermo-optical conversion and high-efficiency utilization of thermal energy.
Keywords	ferrimagnetic materials ; heat ; irradiation ; prototypes ; radiation resistance ; radionuclides ; temperature ; thermal energy
Language	English
Dates of publication	2022-0115
Publishing place	Elsevier Ltd
Document type	Article
ZDB-ID	2019804-8
ISSN	0360-5442 ; 0360-5442
ISSN (online)	0360-5442
ISSN	0360-5442
DOI	10.1016/j.energy.2021.122255
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Article: Metabolites study on 5‐O‐methylvisammioside in vivo and in vitro by ultra high performance liquid chromatography coupled to quadrupole time‐of‐flight mass spectrometry

Fan, Xueyan / Liu, Xiaochen / Meng, Caifeng / Liu, Ruina / Zhang, Zijian / Wang, Chunying

Journal of separation science. 2019 June, v. 42, no. 12

2019

Abstract: 5‐O‐Methylvisammioside is one of major chromones of Radix Saposhnikoviae possessing definite pharmacological activities, but there are few reports with respect to the metabolism of 5‐O‐methylvisammioside. In this work, metabolites in vivo were explored ... ...

Abstract	5‐O‐Methylvisammioside is one of major chromones of Radix Saposhnikoviae possessing definite pharmacological activities, but there are few reports with respect to the metabolism of 5‐O‐methylvisammioside. In this work, metabolites in vivo were explored in male Sprague‐Dawley rats and in vitro investigated on rat intestinal bacteria incubation model and were identified by using ultra high performance liquid chromatography/quadrupole time‐of‐flight mass spectrometry. An online data acquisition method based on a multiple mass defect filter and dynamic background subtraction was developed to trace all probable metabolites. As a result, 26 metabolites in vivo (including 18, 15, 10, and 10 in rat urine, faece, bile, and blood) and 7 metabolites in vitro were characterized, respectively. Additionally, the main metabolic pathways in vivo and in vitro, including deglycosylation, deglycosylation + demethylation, deglycosylation + oxidation, N‐acetylation, and sulfate conjugation, were summarized by calculating the relative content of each metabolite. The obtained results significantly enriched our knowledge about 5‐O‐methylvisammioside metabolism and will lead to a better understanding of its safety and efficacy.
Keywords	bile ; biochemical pathways ; blood ; data collection ; demethylation ; intestinal microorganisms ; laboratory animals ; males ; mass spectrometry ; medicinal properties ; metabolites ; models ; oxidation ; rats ; sulfates ; ultra-performance liquid chromatography ; urine
Language	English
Dates of publication	2019-06
Size	p. 2107-2114.
Publishing place	John Wiley & Sons, Ltd
Document type	Article
Note	JOURNAL ARTICLE
ZDB-ID	2047990-6
ISSN	1615-9314 ; 1615-9306
ISSN (online)	1615-9314
ISSN	1615-9306
DOI	10.1002/jssc.201900001
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Article: Metabolic profiling comparison of isovitexin in normal and kidney stone model rats by ultra‐high‐performance liquid chromatography coupled to quadrupole time‐of‐flight mass spectrometry

Meng, Caifeng / Liu, Ruina / Wang, Wei / Guo, Wei / Ma, Hongyun / Xie, Shuang / Liu, Yimeng / Wang, Chunying

Journal of separation science. 2020 June, v. 43, no. 12

2020

Abstract: Isovitexin, a bioactive flavonoid constituent isolated from Desmodii Styracifolii, is considered an adjuvant for antiurolithiasis diseases. In this study, an ultra‐high‐performance liquid chromatography coupled with hybrid triple quadruple time‐of‐flight ...

Abstract	Isovitexin, a bioactive flavonoid constituent isolated from Desmodii Styracifolii, is considered an adjuvant for antiurolithiasis diseases. In this study, an ultra‐high‐performance liquid chromatography coupled with hybrid triple quadruple time‐of‐flight mass spectrometry method was developed to characterize and compare the metabolic profiling of isovitexin experimented on normal and kidney stone model rats. The comparative research indicated that 28 metabolites (18 phase I and 10 phase II) in normal rats and 33 metabolites (20 phase I and 13 phase II) in kidney stone model rats were initially identified. The results of relative quantitative determination reflected that the contents of metabolites produced by deglycosylation, reduction, and isomerization in kidney stone model rats were greater than those in healthy rats. Instead, the levels of oxidative and dehydrogenated metabolites in normal groups were higher than those in kidney stone model groups. The results of this study are valuable and important for understanding the metabolic process of isovitexin in clinical application, and especially the metabolism study in kidney stone model rats could provide a beneficial reference for the further search of effective substances associated with the treatment of kidney stones.
Keywords	adjuvants ; flavonoids ; isomerization ; kidneys ; mass spectrometry ; metabolism ; metabolites ; quantitative analysis ; renal calculi ; separation ; ultra-performance liquid chromatography
Language	English
Dates of publication	2020-06
Size	p. 2363-2379.
Publishing place	John Wiley & Sons, Ltd
Document type	Article
Note	NAL-AP-2-clean ; JOURNAL ARTICLE
ZDB-ID	2047990-6
ISSN	1615-9314 ; 1615-9306
ISSN (online)	1615-9314
ISSN	1615-9306
DOI	10.1002/jssc.201901169
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Article: Comparative metabolism of schaftoside in healthy and calcium oxalate kidney stone rats by UHPLC-Q-TOF-MS/MS method

Liu, Ruina / Meng, Caifeng / Zhang, Zijian / Ma, Hongyun / Lv, Tao / Xie, Shuang / Liu, Yimeng / Wang, Chunying

Analytical biochemistry. 2020 May 15, v. 597

2020

Abstract: Schaftoside is a flavone-C-glycoside isolated from Herba Desmodii Styracifolii with valuable anti-kidney stones efficacies. In this study, a six-step strategy was first developed to detect and identify the metabolites in plasma, urine, bile, feces and ... ...

Abstract	Schaftoside is a flavone-C-glycoside isolated from Herba Desmodii Styracifolii with valuable anti-kidney stones efficacies. In this study, a six-step strategy was first developed to detect and identify the metabolites in plasma, urine, bile, feces and rat intestinal bacteria samples of healthy and model rats administrated with schaftoside using ultra-high-performance liquid chromatography coupled to quadrupole time-of-flight mass spectrometry (UHPLC-Q-TOF-MS/MS). The number and the relative peak area of metabolites in healthy rats and model rats were compared, and it was noticed that metabolites in bio-samples of healthy and model rats both had obvious differences. A total of 28 metabolites of schaftoside in healthy rats and 30 metabolites in model rats were initially indentified. The relative peak area of the parent drug and every metabolite in model rat plasma samples were larger than those in healthy rat plasma. Those metabolites with high blood concentrations might be beneficial for the treatment of calcium oxalate stones in the kidney. The results are valuable and important for understanding the metabolic process of schaftoside in clinical application, and especially the metabolism study in calcium oxalate kidney stone model rats could provide a beneficial reference for the further search of effective substances associated with the treatment of kidney stones.
Keywords	bile ; blood ; calcium oxalate ; drugs ; feces ; high performance liquid chromatography ; intestinal microorganisms ; kidneys ; metabolism ; metabolites ; models ; rats ; renal calculi ; tandem mass spectrometry ; ultra-performance liquid chromatography ; urine
Language	English
Dates of publication	2020-0515
Publishing place	Elsevier Inc.
Document type	Article
ZDB-ID	1110-1
ISSN	1096-0309 ; 0003-2697
ISSN (online)	1096-0309
ISSN	0003-2697
DOI	10.1016/j.ab.2020.113673
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Metabolites study on 5-O-methylvisammioside in vivo and in vitro by ultra high performance liquid chromatography coupled to quadrupole time-of-flight mass spectrometry.

Fan, Xueyan / Liu, Xiaochen / Meng, Caifeng / Liu, Ruina / Zhang, Zijian / Wang, Chunying

Journal of separation science

2019 Volume 42, Issue 12, Page(s) 2107–2114

Abstract: 5-O-Methylvisammioside is one of major chromones of Radix Saposhnikoviae possessing definite pharmacological activities, but there are few reports with respect to the metabolism of 5-O-methylvisammioside. In this work, metabolites in vivo were explored ... ...

Abstract	5-O-Methylvisammioside is one of major chromones of Radix Saposhnikoviae possessing definite pharmacological activities, but there are few reports with respect to the metabolism of 5-O-methylvisammioside. In this work, metabolites in vivo were explored in male Sprague-Dawley rats and in vitro investigated on rat intestinal bacteria incubation model and were identified by using ultra high performance liquid chromatography/quadrupole time-of-flight mass spectrometry. An online data acquisition method based on a multiple mass defect filter and dynamic background subtraction was developed to trace all probable metabolites. As a result, 26 metabolites in vivo (including 18, 15, 10, and 10 in rat urine, faece, bile, and blood) and 7 metabolites in vitro were characterized, respectively. Additionally, the main metabolic pathways in vivo and in vitro, including deglycosylation, deglycosylation + demethylation, deglycosylation + oxidation, N-acetylation, and sulfate conjugation, were summarized by calculating the relative content of each metabolite. The obtained results significantly enriched our knowledge about 5-O-methylvisammioside metabolism and will lead to a better understanding of its safety and efficacy.
MeSH term(s)	Animals ; Chromatography, High Pressure Liquid ; Drugs, Chinese Herbal/analysis ; Drugs, Chinese Herbal/metabolism ; Male ; Molecular Structure ; Rats ; Rats, Sprague-Dawley ; Tandem Mass Spectrometry ; Time Factors
Chemical Substances	5-O-methylvisammisoide ; Drugs, Chinese Herbal
Language	English
Publishing date	2019-04-29
Publishing country	Germany
Document type	Journal Article
ZDB-ID	2047990-6
ISSN	1615-9314 ; 1615-9306
ISSN (online)	1615-9314
ISSN	1615-9306
DOI	10.1002/jssc.201900001
Database	MEDical Literature Analysis and Retrieval System OnLINE

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Article ; Online: Structural characterization and screening of chemical markers of flavonoids in Lysimachiae Herba and Desmodii Styracifolii Herba by ultra high-performance liquid chromatography quadrupole time-of-flight tandem mass spectrometry based metabolomics approach.

Liu, Xiaochen / Fan, Xueyan / Wang, Xin / Liu, Ruina / Meng, Caifeng / Wang, Chunying

Journal of pharmaceutical and biomedical analysis

2019 Volume 171, Page(s) 52–64

Abstract: In traditional Chinese medicine, Lysimachiae Herba (LH) and Desmodii Styracifolii Herba (DSH) have been widely used for the treatment of calculi, but there is a certain focus in clinical application. Flavonoids as their pharmacologically active ... ...

Abstract	In traditional Chinese medicine, Lysimachiae Herba (LH) and Desmodii Styracifolii Herba (DSH) have been widely used for the treatment of calculi, but there is a certain focus in clinical application. Flavonoids as their pharmacologically active substances were focusly studied to make clear of their chemical compositions and reveal the similarities and differences between LH and DHS by analysis of characteristic marker components at the molecular level. An ultra high performance liquid chromatography quadrupole time-of-flight tandem mass spectrometry (UPLC-QTOF-MS/MS) approach based on metabolite profiling was established. The high-resolution data was acquired through data dependent acquisition (DDA) mode. Based on the targeted and untargeted analytical strategies, a total of 113 compounds were identified, of which 80 compounds existed in LH and 61 in DSH. Then multivariate statistical analysis was applied to further find the characteristic marker components, and a total number of 21 variables were screened as the valuable variables for discrimination. By matching with identified flavonoids, these 21 variables were corresponding to 15 flavonoids (including 6 from LH and 9 from DSH) which were firstly identified as the marker compounds. These results indicated that the UPLC-QTOF-MS/MS method with analysis strategy was a powerful tool for rapidly identification and screening of marker compounds of flavonoids between LH and DSH, and the 15 screened marker compounds provide a chemical basis for the further researches on the mechanisms of LH and DSH in the treatment of cholelithiasis and nephrolithiasis respectively.
MeSH term(s)	Biomarkers/chemistry ; Chromatography, High Pressure Liquid/methods ; Fabaceae/chemistry ; Flavonoids/isolation & purification ; Medicine, Chinese Traditional ; Metabolomics/methods ; Multivariate Analysis ; Plant Extracts/chemistry ; Primulaceae/chemistry ; Tandem Mass Spectrometry/methods
Chemical Substances	Biomarkers ; Flavonoids ; Plant Extracts
Language	English
Publishing date	2019-04-03
Publishing country	England
Document type	Journal Article
ZDB-ID	604917-5
ISSN	1873-264X ; 0731-7085
ISSN (online)	1873-264X
ISSN	0731-7085
DOI	10.1016/j.jpba.2019.04.003
Database	MEDical Literature Analysis and Retrieval System OnLINE

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Article ; Online: The Epidemiology of Tinea Capitis in Guangxi Province, China.

Zheng, Dongyan / Liang, Tianwei / Wu, Weixuan / Al-Odaini, Najwa / Pan, Kaisu / Huang, Lan / Huang, Guomei / Tang, Lulu / Li, Xinlei / He, Shao / Jian, Huahui / Wei, Nibo / Wei, Li Juan / Pan, Yanbin / Tang, Ping / Meng, Caifeng / Qin, Jinglin / Wan, Zhe / Chen, Xiaoqing /

Cao, Cunwei

Mycopathologia

2023 Volume 188, Issue 5, Page(s) 489–496

Abstract: The aim of this study was to analyze the epidemiological characteristics and pathogen spectrum of tinea capitis in Guangxi, southern China. A multicenter prospective descriptive study was conducted in 8 hospitals across Guangxi. From January 2019 to July ...

Abstract	The aim of this study was to analyze the epidemiological characteristics and pathogen spectrum of tinea capitis in Guangxi, southern China. A multicenter prospective descriptive study was conducted in 8 hospitals across Guangxi. From January 2019 to July 2022, one hundred seventy-one (171) patients diagnosed with tinea capitis were included. Demographic data, risk factors, and fungal data were collected. If necessary, species were further identified by morphological or molecular sequencing in the central laboratory. Of the 171 cases of tinea capitis, 74.3% occurred in patients aged 2-8 years. Children with tinea capitis were mainly boys (59.6%) and were more likely than adults to have a history of animal contact (44.2% vs. 33.3%) and zoophilic dermatophyte infection (76.9% vs. 46.7%, P = 0.008). The adults were mainly female (53%) and were more likely than children to have a history of infection with anthropophilic organisms (53.3% vs. 18.9%). The causative agents of tinea capitis in Guangxi were diverse, and the most common pathogen was Microsporum canis (M. cani, n = 98, 62%), followed by Trichophyton mentagrophytes (T. mentagrophytes n = 18, 11.4%) and Trichophyton tonsurans (T. tonsurans n = 12, 7.6%). In addition, tinea capitis caused by Nannizzia incurvata (N. incurvata) and Trichophyton verrucosum (T. verrucosum) was detected in the study. Notably, the proportion of patients with kerion in the study was 41.5% (n = 71), and most of those patients were children (n = 68), especially neglected children living in the rural mountainous areas of Guangxi, where they were unable to receive timely diagnosis and appropriate treatment. In conclusion, the causative agents of tinea capitis in Guangxi, South China, are diverse, and the incidence of kerion is high, indicating that diagnosis and treatment modalities in the region remain grossly inadequate. Clinicians and policy-makers should collaborate to adopt public health strategies to control the disease.
MeSH term(s)	Child ; Male ; Adult ; Animals ; Humans ; Female ; China/epidemiology ; Tinea Capitis/epidemiology ; Tinea Capitis/microbiology ; Microsporum ; Risk Factors ; Hospitals ; Incidence ; Trichophyton
Language	English
Publishing date	2023-06-25
Publishing country	Netherlands
Document type	Multicenter Study ; Journal Article
ZDB-ID	391081-7
ISSN	1573-0832 ; 0369-299X ; 0301-486X ; 0027-5530
ISSN (online)	1573-0832
ISSN	0369-299X ; 0301-486X ; 0027-5530
DOI	10.1007/s11046-023-00762-w
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Article ; Online: Metabolic profiling comparison of isovitexin in normal and kidney stone model rats by ultra-high-performance liquid chromatography coupled to quadrupole time-of-flight mass spectrometry.

Meng, Caifeng / Liu, Ruina / Wang, Wei / Guo, Wei / Ma, Hongyun / Xie, Shuang / Liu, Yimeng / Wang, Chunying

Journal of separation science

2020 Volume 43, Issue 12, Page(s) 2363–2379

Abstract: Isovitexin, a bioactive flavonoid constituent isolated from Desmodii Styracifolii, is considered an adjuvant for antiurolithiasis diseases. In this study, an ultra-high-performance liquid chromatography coupled with hybrid triple quadruple time-of-flight ...

Abstract	Isovitexin, a bioactive flavonoid constituent isolated from Desmodii Styracifolii, is considered an adjuvant for antiurolithiasis diseases. In this study, an ultra-high-performance liquid chromatography coupled with hybrid triple quadruple time-of-flight mass spectrometry method was developed to characterize and compare the metabolic profiling of isovitexin experimented on normal and kidney stone model rats. The comparative research indicated that 28 metabolites (18 phase I and 10 phase II) in normal rats and 33 metabolites (20 phase I and 13 phase II) in kidney stone model rats were initially identified. The results of relative quantitative determination reflected that the contents of metabolites produced by deglycosylation, reduction, and isomerization in kidney stone model rats were greater than those in healthy rats. Instead, the levels of oxidative and dehydrogenated metabolites in normal groups were higher than those in kidney stone model groups. The results of this study are valuable and important for understanding the metabolic process of isovitexin in clinical application, and especially the metabolism study in kidney stone model rats could provide a beneficial reference for the further search of effective substances associated with the treatment of kidney stones.
MeSH term(s)	Animals ; Apigenin/analysis ; Apigenin/metabolism ; Chromatography, High Pressure Liquid ; Disease Models, Animal ; Kidney Calculi/chemistry ; Kidney Calculi/metabolism ; Male ; Mass Spectrometry ; Rats ; Rats, Sprague-Dawley ; Time Factors
Chemical Substances	Apigenin (7V515PI7F6) ; isovitexin (KTQ9R9MS0Q)
Language	English
Publishing date	2020-05-05
Publishing country	Germany
Document type	Comparative Study ; Journal Article
ZDB-ID	2047990-6
ISSN	1615-9314 ; 1615-9306
ISSN (online)	1615-9314
ISSN	1615-9306
DOI	10.1002/jssc.201901169
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Article ; Online: Comparative metabolism of schaftoside in healthy and calcium oxalate kidney stone rats by UHPLC-Q-TOF-MS/MS method.

Liu, Ruina / Meng, Caifeng / Zhang, Zijian / Ma, Hongyun / Lv, Tao / Xie, Shuang / Liu, Yimeng / Wang, Chunying

Analytical biochemistry

2020 Volume 597, Page(s) 113673

Abstract	Schaftoside is a flavone-C-glycoside isolated from Herba Desmodii Styracifolii with valuable anti-kidney stones efficacies. In this study, a six-step strategy was first developed to detect and identify the metabolites in plasma, urine, bile, feces and rat intestinal bacteria samples of healthy and model rats administrated with schaftoside using ultra-high-performance liquid chromatography coupled to quadrupole time-of-flight mass spectrometry (UHPLC-Q-TOF-MS/MS). The number and the relative peak area of metabolites in healthy rats and model rats were compared, and it was noticed that metabolites in bio-samples of healthy and model rats both had obvious differences. A total of 28 metabolites of schaftoside in healthy rats and 30 metabolites in model rats were initially indentified. The relative peak area of the parent drug and every metabolite in model rat plasma samples were larger than those in healthy rat plasma. Those metabolites with high blood concentrations might be beneficial for the treatment of calcium oxalate stones in the kidney. The results are valuable and important for understanding the metabolic process of schaftoside in clinical application, and especially the metabolism study in calcium oxalate kidney stone model rats could provide a beneficial reference for the further search of effective substances associated with the treatment of kidney stones.
MeSH term(s)	Animals ; Calcium Oxalate/blood ; Calcium Oxalate/metabolism ; Calcium Oxalate/urine ; Disease Models, Animal ; Glycosides/blood ; Glycosides/metabolism ; Glycosides/urine ; Kidney Calculi/blood ; Kidney Calculi/chemistry ; Kidney Calculi/urine ; Male ; Rats ; Rats, Sprague-Dawley
Chemical Substances	Glycosides ; schaftoside ; Calcium Oxalate (2612HC57YE)
Language	English
Publishing date	2020-03-04
Publishing country	United States
Document type	Comparative Study ; Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	1110-1
ISSN	1096-0309 ; 0003-2697
ISSN (online)	1096-0309
ISSN	0003-2697
DOI	10.1016/j.ab.2020.113673
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