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  1. Article: Simple multi-residue analysis of persistent organic pollutants and molecular tracers in atmospheric samples.

    Iakovides, Minas / Sciare, Jean / Mihalopoulos, Nikos

    MethodsX

    2023  Volume 10, Page(s) 102224

    Abstract: We present a simple, selective and sensitive analytical method to quantitatively determine a wide range of halogenated persistent organic pollutants and molecular tracers in atmospheric samples. Identification and quantification was carried out by high- ... ...

    Abstract We present a simple, selective and sensitive analytical method to quantitatively determine a wide range of halogenated persistent organic pollutants and molecular tracers in atmospheric samples. Identification and quantification was carried out by high-resolution gas chromatography, hyphenated with low-resolution mass spectrometry operating in electron impact (EI) and electron capture negative ionization (ECNI) mode. Optimization on a number of instrumental parameters was conducted to obtain ultra-trace detection limits, in the range of few fg/m
    Language English
    Publishing date 2023-05-17
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 2830212-6
    ISSN 2215-0161
    ISSN 2215-0161
    DOI 10.1016/j.mex.2023.102224
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: A direct method to quantify methanol-soluble organic carbon for brown carbon absorption studies.

    Paraskevopoulou, D / Bikkina, S / Grivas, G / Kaskaoutis, D G / Tsagkaraki, M / Tavernaraki, K / Mihalopoulos, N

    MethodsX

    2023  Volume 11, Page(s) 102313

    Abstract: The current research provides a newly developed method to quantify methanol-soluble organic carbon (MeS_OC) in aerosol samples. This analytical procedure allows an accurate separation of MeS-OC component, which is critical for the calculation of mass ... ...

    Abstract The current research provides a newly developed method to quantify methanol-soluble organic carbon (MeS_OC) in aerosol samples. This analytical procedure allows an accurate separation of MeS-OC component, which is critical for the calculation of mass absorption efficiency (MAE) of ambient Brown Carbon (BrC) and consequently its climate relevant potential. The method includes extraction, filtering and condensation stages, leading to the preparation of a highly concentrated product in which MeS-OC can be precisely quantified by a Sunset Carbon Analyzer in a single analysis step. This method can be applied on aerosol collected using either high or low volume samplers, since a relatively small filter area is required for the determination. Furthermore, it eliminates any misestimation of the MeS-OC mass that may appear in other reported techniques that don't seem to include the precise separation of methanol-soluble fraction in their quantification process.•The mass quantification of methanol-soluble organic carbon is essential, contributing up to 50% to the absorptivity of organic aerosol (BrC) at shorter wavelengths.•The method provides a direct measurement of methanol-soluble aerosol components, resolving any potential uncertainties of previously applied methods.•The adoption of this direct quantification approach leads to a rationalization of past MAE estimates for BrC with implications for radiative transfer models.
    Language English
    Publishing date 2023-08-04
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 2830212-6
    ISSN 2215-0161
    ISSN 2215-0161
    DOI 10.1016/j.mex.2023.102313
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Cooking as an organic aerosol source leading to urban air quality degradation.

    Stavroulas, I / Bougiatioti, A / Grivas, G / Liakakou, E / Petrinoli, K / Kourtidis, K / Gerasopoulos, E / Mihalopoulos, N

    The Science of the total environment

    2023  Volume 908, Page(s) 168031

    Abstract: Air quality degradation events in the urban environment are often attributed to anthropogenic aerosol sources related to combustion of liquid or solid fuels in various activities. The effects of massive cooking emissions during Greek nationwide ... ...

    Abstract Air quality degradation events in the urban environment are often attributed to anthropogenic aerosol sources related to combustion of liquid or solid fuels in various activities. The effects of massive cooking emissions during Greek nationwide traditional festivities were investigated by a combined characterization of particulate matter (PM) levels and organic aerosol (OA) sources. Focus was centered on periods around two major festivities, namely "Fat Thursday" and Easter Sunday along six different years. OA sources were apportioned through Positive Matrix Factorization (PMF) on Aerosol Chemical Speciation Monitor (ACSM) mass spectra, while the spatial characteristics of the episodes were assessed through a low-cost, sensor-based PM
    MeSH term(s) Air Pollutants/analysis ; Environmental Monitoring ; Respiratory Aerosols and Droplets ; Air Pollution/analysis ; Particulate Matter/analysis ; Aerosols/analysis ; Cooking
    Chemical Substances Air Pollutants ; Particulate Matter ; Aerosols
    Language English
    Publishing date 2023-10-25
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2023.168031
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Evidence of stockpile contamination for legacy polychlorinated biphenyls and organochlorine pesticides in the urban environment of Cyprus (Eastern Mediterranean): Influence of meteorology on air level variability and gas/particle partitioning based on equilibrium and steady-state models.

    Iakovides, Minas / Oikonomou, Konstantina / Sciare, Jean / Mihalopoulos, Nikos

    Journal of hazardous materials

    2022  Volume 439, Page(s) 129544

    Abstract: The present study investigated comprehensively the atmospheric occurrence and fate of an extensive range of polychlorinated biphenyls (PCBs; forty-two congeners), organochlorine pesticides (OCPs; twenty-seven emerging and legacy agrochemicals) and ... ...

    Abstract The present study investigated comprehensively the atmospheric occurrence and fate of an extensive range of polychlorinated biphenyls (PCBs; forty-two congeners), organochlorine pesticides (OCPs; twenty-seven emerging and legacy agrochemicals) and polycyclic aromatic hydrocarbons (PAHs; fifty parent and alkylated members, including the non USEPA-16 listed toxic ones), in both gas and particulate phase of the scarcely monitored atmosphere over Cyprus for the first time. Parent-metabolite concentration ratios suggested fresh application for dichlorodiphenyl-trichloroethanes (DDTs), dicofol, hexachlorocyclohexanes, endosulfan and chlorothalonil, particularly during spring (April-May). Regressions of logarithms of partial pressure against ambient temperature revealed that secondary recycling from contaminated terrestrial surfaces regulates the atmospheric level variability of PCBs, DDTs, aldrin, chlordane, dicofol, heptachlor and endosulfan. Enthalpies of surface-air exchange (∆H
    MeSH term(s) Air Pollutants/analysis ; Cyprus ; Dicofol/analysis ; Endosulfan ; Environmental Monitoring/methods ; Humans ; Hydrocarbons, Chlorinated/analysis ; Meteorology ; Pesticides/analysis ; Polychlorinated Biphenyls/analysis ; Polycyclic Aromatic Hydrocarbons/analysis
    Chemical Substances Air Pollutants ; Hydrocarbons, Chlorinated ; Pesticides ; Polycyclic Aromatic Hydrocarbons ; Polychlorinated Biphenyls (DFC2HB4I0K) ; Endosulfan (OKA6A6ZD4K) ; Dicofol (W4WMM0WS91)
    Language English
    Publishing date 2022-07-08
    Publishing country Netherlands
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 1491302-1
    ISSN 1873-3336 ; 0304-3894
    ISSN (online) 1873-3336
    ISSN 0304-3894
    DOI 10.1016/j.jhazmat.2022.129544
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Identification of key aerosol types and mixing states in the central Indian Himalayas during the GVAX campaign: the role of particle size in aerosol classification.

    Dumka, U C / Kaskaoutis, D G / Mihalopoulos, N / Sheoran, Rahul

    The Science of the total environment

    2020  Volume 761, Page(s) 143188

    Abstract: Studies in aerosol properties, types and sources in the Himalayas are important for atmospheric and climatic issues due to high aerosol loading in the neighboring plains. This study uses in situ measurements of aerosol optical and microphysical ... ...

    Abstract Studies in aerosol properties, types and sources in the Himalayas are important for atmospheric and climatic issues due to high aerosol loading in the neighboring plains. This study uses in situ measurements of aerosol optical and microphysical properties obtained during the Ganges Valley Aerosol eXperiment (GVAX) at Nainital, India over the period June 2011-March 2012, aiming to identify key aerosol types and mixing states for two particle sizes (PM
    Language English
    Publishing date 2020-10-23
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2020.143188
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Human health risk assessment for toxic elements in the extreme ambient dust conditions observed in Sistan, Iran.

    Dahmardeh Behrooz, Reza / Kaskaoutis, D G / Grivas, G / Mihalopoulos, N

    Chemosphere

    2020  Volume 262, Page(s) 127835

    Abstract: This study evaluates the bioaccessibility and health risks related to heavy metals (Cd, Cr, Co, Cu, Mn, Ni, Pb, Zn and metalloid As) in airborne dust samples (TSP and ... ...

    Abstract This study evaluates the bioaccessibility and health risks related to heavy metals (Cd, Cr, Co, Cu, Mn, Ni, Pb, Zn and metalloid As) in airborne dust samples (TSP and PM
    MeSH term(s) Adult ; Air Pollution/statistics & numerical data ; Carcinogens/analysis ; Child ; Dust/analysis ; Environmental Exposure/statistics & numerical data ; Environmental Monitoring ; Hazardous Substances/analysis ; Humans ; Iran ; Metals, Heavy/analysis ; Risk Assessment ; Seasons
    Chemical Substances Carcinogens ; Dust ; Hazardous Substances ; Metals, Heavy
    Language English
    Publishing date 2020-08-01
    Publishing country England
    Document type Journal Article
    ZDB-ID 120089-6
    ISSN 1879-1298 ; 0045-6535 ; 0366-7111
    ISSN (online) 1879-1298
    ISSN 0045-6535 ; 0366-7111
    DOI 10.1016/j.chemosphere.2020.127835
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Source apportionment of fine and ultrafine particle number concentrations in a major city of the Eastern Mediterranean.

    Kalkavouras, Panayiotis / Grivas, Georgios / Stavroulas, Iasonas / Petrinoli, Kalliopi / Bougiatioti, Aikaterini / Liakakou, Eleni / Gerasopoulos, Evangelos / Mihalopoulos, Nikolaos

    The Science of the total environment

    2024  Volume 915, Page(s) 170042

    Abstract: Ultrafine particles (UFP) are recognized as an emerging pollutant able to induce serious health effects. However, quantitative information regarding the contributions of UFP sources is generally limited. This study evaluates statistical (k-means ... ...

    Abstract Ultrafine particles (UFP) are recognized as an emerging pollutant able to induce serious health effects. However, quantitative information regarding the contributions of UFP sources is generally limited. This study evaluates statistical (k-means clustering) and receptor models (Positive Matrix Factorization - PMF) using particle number size distributions (PNSD), along with chemical speciation data, measured at an urban background supersite in Athens, Greece, aiming to characterize their sources. PNSD measurements (10-487 nm) were performed during three distinct periods (warm, cold, and lockdown cold). Traffic and residential biomass burning (BB) produced high UFP number concentrations (N
    Language English
    Publishing date 2024-01-15
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2024.170042
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Fine aerosol sources at an urban background site in the Eastern Mediterranean (Nicosia; Cyprus): Insights from offline versus online source apportionment comparison for carbonaceous aerosols.

    Bimenyimana, Elie / Pikridas, Michael / Oikonomou, Konstantina / Iakovides, Minas / Christodoulou, Aliki / Sciare, Jean / Mihalopoulos, Nikos

    The Science of the total environment

    2023  Volume 893, Page(s) 164741

    Abstract: A total of 348 daily ... ...

    Abstract A total of 348 daily PM
    Language English
    Publishing date 2023-06-08
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2023.164741
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: A direct method to quantify methanol-soluble organic carbon for Brown Carbon absorption studies

    Paraskevopoulou, D. / Bikkina, S. / Grivas, G. / Kaskaoutis, D.G. / Tsagkaraki, M. / Tavernaraki, K. / Mihalopoulos, N.

    MethodsX. 2023 Aug. 04, p.102313-

    2023  , Page(s) 102313–

    Abstract: The current research provides a newly developed method to quantify methanol-soluble organic carbon (MeS_OC) in aerosol samples. This analytical procedure allows an accurate separation of MeS-OC component, which is critical for the calculation of mass ... ...

    Abstract The current research provides a newly developed method to quantify methanol-soluble organic carbon (MeS_OC) in aerosol samples. This analytical procedure allows an accurate separation of MeS-OC component, which is critical for the calculation of mass absorption efficiency (MAE) of ambient Brown Carbon (BrC) and consequently its climate relevant potential. The method includes extraction, filtering and condensation stages, leading to the preparation of a highly concentrated product in which MeS-OC can be precisely quantified by a Sunset Carbon Analyzer in a single analysis step. This method can be applied on aerosol collected using either high or low volume samplers, since a relatively small filter area is required for the determination. Furthermore, it eliminates any misestimation of the MeS-OC mass that may appear in other reported techniques that don't seem to include the precise separation of methanol-soluble fraction in their quantification process.• The mass quantification of methanol-soluble organic carbon is essential, contributing up to 50% to the absorptivity of organic aerosol (BrC) at shorter wavelengths.• The method provides a direct measurement of methanol-soluble aerosol components, resolving any potential uncertainties of previously applied methods.• The adoption of this direct quantification approach leads to a rationalization of past MAE estimates for BrC with implications for radiative transfer models.
    Keywords absorption ; absorptivity ; aerosols ; climate ; organic carbon ; radiative transfer ; BrC ; Methanol-soluble organic carbon ; Brown carbon absorption ; Mass absorption efficiency ; Particulate matter
    Language English
    Dates of publication 2023-0804
    Publishing place Elsevier B.V.
    Document type Article ; Online
    Note Pre-press version
    ZDB-ID 2830212-6
    ISSN 2215-0161
    ISSN 2215-0161
    DOI 10.1016/j.mex.2023.102313
    Database NAL-Catalogue (AGRICOLA)

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  10. Article: Determination of the background pollution in the Eastern Mediterranean applying a statistical clustering technique

    Rizos, K. / Meleti, C. / Kouvarakis, G. / Mihalopoulos, N. / Melas, D.

    Atmospheric environment. 2022 May 01, v. 276

    2022  

    Abstract: The knowledge of the background air pollution is essential in order to implement abatement strategies for improving air quality. In the present study, a statistical clustering algorithm based on Hidden Markov Models (HMMs) was used to determine the ... ...

    Abstract The knowledge of the background air pollution is essential in order to implement abatement strategies for improving air quality. In the present study, a statistical clustering algorithm based on Hidden Markov Models (HMMs) was used to determine the background concentrations of PM₁₀ and O₃ at a coastal monitoring site in the Eastern Mediterranean by analyzing an eight-year period of air quality data, from 2011 to 2018. Time series of the deseasonalized daily average concentrations of PM₁₀ and O₃ and their diurnal amplitudes were applied to the model to identify the unobserved patterns or hidden states that define the pollution states of the two mentioned air pollutants. The pollution state characterized by the lowest daily average concentration and diurnal amplitudes defined the background pollution level and had the main interest in the current work. The findings revealed that during the studied period, 59% of the total daily PM₁₀ values and 67% of the O₃ values corresponded to the background pollution state and the average background concentrations were 14.3 ± 5.2 μg/m³ for PM₁₀ and 48.4 ± 8.2 ppb for O₃ respectively. In the case of PM₁₀, anthropogenic activities and Saharan dust events, which define different pollution states, contribute in a decisive way to the PM₁₀ load in the region and play a significant role in the observed annual PM₁₀ levels. Additionally, in the case of O₃, anthropogenic activities and regional pollution affect the background levels of the region mainly during summer months. The proposed method is a flexible tool with great potential for estimating the background levels of air pollutants at various monitoring stations.
    Keywords air ; air pollution ; air quality ; algorithms ; dust ; environment ; summer ; time series analysis
    Language English
    Dates of publication 2022-0501
    Publishing place Elsevier Ltd
    Document type Article
    ZDB-ID 216368-8
    ISSN 0004-6981 ; 1352-2310
    ISSN 0004-6981 ; 1352-2310
    DOI 10.1016/j.atmosenv.2022.119067
    Database NAL-Catalogue (AGRICOLA)

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