Article ; Online: Pure shift edited NMR methodologies for the extraction of Homo- and heteronuclear couplings with ultra-high resolution.
Progress in nuclear magnetic resonance spectroscopy
2023 Volume 136-137, Page(s) 1–60
Abstract: The scalar couplings that result in the splitting of the signals in the NMR spectrum arise due to the interaction of the nuclear spins, whereby the spin polarization is transmitted through chemical bonds. The interaction strengths depend inter alia on ... ...
Abstract | The scalar couplings that result in the splitting of the signals in the NMR spectrum arise due to the interaction of the nuclear spins, whereby the spin polarization is transmitted through chemical bonds. The interaction strengths depend inter alia on the number of consecutive chemical bonds intervening between the two interacting spins and on the molecular conformation. The pairwise interaction of many spins in a molecule resulting in a complex spectrum poses a severe challenge to analyse the spectrum and hence the determination of magnitudes and signs of homo- and heteronuclear couplings. The problem is more severe in the analysis of |
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Language | English |
Publishing date | 2023-02-07 |
Publishing country | England |
Document type | Journal Article ; Review |
ZDB-ID | 209325-x |
ISSN | 1873-3301 ; 0079-6565 |
ISSN (online) | 1873-3301 |
ISSN | 0079-6565 |
DOI | 10.1016/j.pnmrs.2023.02.001 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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