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  1. AU="Moulding, David J"
  2. AU=Ogawa Makio
  3. AU="Heisel, Curtis J"
  4. AU="Zakharchenko, Artem"
  5. AU="C.K.Cheong, "
  6. AU="Pierfrancesco Franco"
  7. AU="Barutcu, Sezgin"
  8. AU="Saha, Titas"
  9. AU="Lipina, Tatiana V"
  10. AU="Herman, Mariana"
  11. AU="Sicard, Delphine"
  12. AU="Guglielmi, Adele"
  13. AU="Hammond, Ester"
  14. AU="Li, Lanhui"
  15. AU="Hassett, Michael J"
  16. AU="Kyle K. Biggar"
  17. AU="Al-Garawi, Amal"
  18. AU="Freeman, Willard M"
  19. AU="Lussier, A M"
  20. AU="J.Castaneda, "
  21. AU="Izquierdo, Ledys"
  22. AU="Werner, F"
  23. AU="Boddington, Marie E"
  24. AU="N Siddaiah"

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  1. Artikel ; Online: Photoluminescence of Pentavalent Uranyl Amide Complexes.

    Ortu, Fabrizio / Randall, Simon / Moulding, David J / Woodward, Adam W / Kerridge, Andrew / Meyer, Karsten / La Pierre, Henry S / Natrajan, Louise S

    Journal of the American Chemical Society

    2021  Band 143, Heft 33, Seite(n) 13184–13194

    Abstract: Pentavalent uranyl species are crucial intermediates in transformations that play a key role for the nuclear industry and have recently been demonstrated to persist in reducing biotic and abiotic aqueous environments. However, due to the inherent ... ...

    Abstract Pentavalent uranyl species are crucial intermediates in transformations that play a key role for the nuclear industry and have recently been demonstrated to persist in reducing biotic and abiotic aqueous environments. However, due to the inherent instability of pentavalent uranyl, little is known about its electronic structure. Herein, we report the synthesis and characterization of a series of monomeric and dimeric, pentavalent uranyl amide complexes. These synthetic efforts enable the acquisition of emission spectra of well-defined pentavalent uranyl complexes using photoluminescence techniques, which establish a unique signature to characterize its electronic structure and, potentially, its role in biological and engineered environments via emission spectroscopy.
    Sprache Englisch
    Erscheinungsdatum 2021-08-13
    Erscheinungsland United States
    Dokumenttyp Journal Article ; Research Support, U.S. Gov't, Non-P.H.S. ; Research Support, Non-U.S. Gov't
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.1c05184
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  2. Artikel: Photoluminescence of Pentavalent Uranyl Amide Complexes

    Ortu, Fabrizio / Randall, Simon / Moulding, David J. / Woodward, Adam W. / Kerridge, Andrew / Meyer, Karsten / La Pierre, Henry S. / Natrajan, Louise S.

    Journal of the American Chemical Society. 2021 Aug. 13, v. 143, no. 33

    2021  

    Abstract: Pentavalent uranyl species are crucial intermediates in transformations that play a key role for the nuclear industry and have recently been demonstrated to persist in reducing biotic and abiotic aqueous environments. However, due to the inherent ... ...

    Abstract Pentavalent uranyl species are crucial intermediates in transformations that play a key role for the nuclear industry and have recently been demonstrated to persist in reducing biotic and abiotic aqueous environments. However, due to the inherent instability of pentavalent uranyl, little is known about its electronic structure. Herein, we report the synthesis and characterization of a series of monomeric and dimeric, pentavalent uranyl amide complexes. These synthetic efforts enable the acquisition of emission spectra of well-defined pentavalent uranyl complexes using photoluminescence techniques, which establish a unique signature to characterize its electronic structure and, potentially, its role in biological and engineered environments via emission spectroscopy.
    Schlagwörter industry ; photoluminescence ; spectroscopy ; uranyl ions
    Sprache Englisch
    Erscheinungsverlauf 2021-0813
    Umfang p. 13184-13194.
    Erscheinungsort American Chemical Society
    Dokumenttyp Artikel
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.1c05184
    Datenquelle NAL Katalog (AGRICOLA)

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  3. Artikel ; Online: Uranyl-tri- bis(silyl)amide Alkali Metal Contact and Separated Ion Pair Complexes.

    Cobb, Philip J / Moulding, David J / Ortu, Fabrizio / Randall, Simon / Wooles, Ashley J / Natrajan, Louise S / Liddle, Stephen T

    Inorganic chemistry

    2018  Band 57, Heft 11, Seite(n) 6571–6583

    Abstract: We report the preparation of a range of alkali metal uranyl(VI) tri- bis(silyl)amide complexes [{M(THF) ...

    Abstract We report the preparation of a range of alkali metal uranyl(VI) tri- bis(silyl)amide complexes [{M(THF)
    Sprache Englisch
    Erscheinungsdatum 2018-06-04
    Erscheinungsland United States
    Dokumenttyp Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.8b00715
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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  4. Artikel ; Online: Structural diversity of bimetallic rhodium and iridium half sandwich dithiolato complexes.

    Nejman, Phillip S / Morton-Fernandez, Brian / Moulding, David J / Athukorala Arachchige, Kasun S / Cordes, David B / Slawin, Alexandra M Z / Kilian, Petr / Woollins, J Derek

    Dalton transactions (Cambridge, England : 2003)

    2015  Band 44, Heft 38, Seite(n) 16758–16766

    Abstract: The synthesis of a range of rhodium(iii) and iridium(iii) half sandwich complexes with aryl dithiolato ligands of varying geometry and flexibility are reported. These include dinuclear [Cp*M(S-R-S)]2 complexes 3b and 4b, M = Rh, Ir; S-R-S = naphthalene-1, ...

    Abstract The synthesis of a range of rhodium(iii) and iridium(iii) half sandwich complexes with aryl dithiolato ligands of varying geometry and flexibility are reported. These include dinuclear [Cp*M(S-R-S)]2 complexes 3b and 4b, M = Rh, Ir; S-R-S = naphthalene-1,8-dithiolate (b) and four dinuclear complexes bearing bridging dithiolate ligands [(Cp*M)2(μ2-Cl)(μ2-S-R-S)]Cl 3c, 4c, 5b, 6b, M = Rh, Ir; S-R-S = naphthalene-1,8-dithiolate (b) or acenaphthene-5,6-dithiolate (c). The introduction of a less rigid biphenyl dithiolate backbone resulted in the tetranuclear dicationic complex [(Cp*Rh)4(S-R-S)3]Cl2 (3d), S-R-S = biphenyl-2,2'-dithiolate (d) with dithiolate ligands in two different bridging modes. All new complexes were fully characterised by multinuclear NMR, IR, Raman and MS spectroscopy and single crystal X-ray diffraction.
    Sprache Englisch
    Erscheinungsdatum 2015-10-14
    Erscheinungsland England
    Dokumenttyp Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c5dt02542g
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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