Article: Structural, optical and conductivity properties in tetragonal BaTi₁₋ₓCoₓO₃ (0≤ x ≤0.1)
RSC advances. 2022 May 30, v. 12, no. 25
2022
Abstract: This work investigates the structure, optical and electrical conductivity properties of BaTi₁₋ₓCoₓO₃ (0≤ x ≤0.1) ceramics prepared by the hydrothermal method. The X-ray diffraction and Raman scattering analysis demonstrates that the prepared samples have ...
Abstract | This work investigates the structure, optical and electrical conductivity properties of BaTi₁₋ₓCoₓO₃ (0≤ x ≤0.1) ceramics prepared by the hydrothermal method. The X-ray diffraction and Raman scattering analysis demonstrates that the prepared samples have a single-phase tetragonal structure with P4mm symmetry. The UV-vis diffuse reflectance spectrum confirms the influence of Co concentration on the direct optical band gap of BaTi₁₋ₓCoₓO₃ ceramics. The optical band gap shifts from 3.14 eV to 3.44 eV as the Co concentration increases from 0 to 0.1. The dielectric constant increases with the depletion of frequency according to the Maxwell–Wagner and Koops model. The AC conductivity versus frequency curve indicates that the conduction mechanism is determined by using the correlated barrier hopping (CBH) model. The Cole–Cole plot of the complex impedance was investigated for the prepared samples. The compounds showed dielectric relaxation of the non-Debye type. |
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Keywords | X-ray diffraction ; dielectric properties ; electrical conductivity ; hot water treatment ; models ; reflectance spectroscopy |
Language | English |
Dates of publication | 2022-0530 |
Size | p. 16119-16130. |
Publishing place | The Royal Society of Chemistry |
Document type | Article |
ISSN | 2046-2069 |
DOI | 10.1039/d2ra01411d |
Database | NAL-Catalogue (AGRICOLA) |
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