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  1. Article ; Online: Welcoming Neighbour or Inhospitable Host? Selective Second Metal Binding in 5- and 6-Phospha-Substituted Bpy Ligands.

    Platts, James A / Kariuki, Benson M / Newman, Paul D

    Molecules (Basel, Switzerland)

    2024  Volume 29, Issue 5

    Abstract: The controlled formation of mixed-metal bimetallics was realised through use of ... ...

    Abstract The controlled formation of mixed-metal bimetallics was realised through use of a
    Language English
    Publishing date 2024-03-05
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 1413402-0
    ISSN 1420-3049 ; 1431-5165 ; 1420-3049
    ISSN (online) 1420-3049
    ISSN 1431-5165 ; 1420-3049
    DOI 10.3390/molecules29051150
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Cologne/Königswinter

    Zs.MO 81: Show issues

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  2. Article ; Online: A hybrid bipy-NHC ligand for the construction of group 11 mixed-metal bimetallic complexes.

    Kariuki, Benson M / Platts, James A / Newman, Paul D

    RSC advances

    2021  Volume 11, Issue 54, Page(s) 34170–34173

    Abstract: An asymmetric bipy/NHC ligand L has been used to construct Au/Au, Au/Ag and Au/Cu bimetallic complexes through prior coordination of the NHC to Au(i) and subsequent introduction of the second group 11 metal ion at the bipy donor of the hybrid ligand. The ...

    Abstract An asymmetric bipy/NHC ligand L has been used to construct Au/Au, Au/Ag and Au/Cu bimetallic complexes through prior coordination of the NHC to Au(i) and subsequent introduction of the second group 11 metal ion at the bipy donor of the hybrid ligand. The complex [Au(κ
    Language English
    Publishing date 2021-10-21
    Publishing country England
    Document type Journal Article
    ISSN 2046-2069
    ISSN (online) 2046-2069
    DOI 10.1039/d1ra06581e
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: A review of quantum chemical studies of Frustrated Lewis Pairs.

    Sharma, Gitanjali / Newman, Paul D / Platts, James A

    Journal of molecular graphics & modelling

    2021  Volume 105, Page(s) 107846

    Abstract: This review endeavours to explore the power of quantum chemistry, especially density functional theory (DFT) to unravel mechanisms underlying the fascinating field of FLP chemistry. Apart from the fundamental mechanism of hydrogen activation by FLPs, ... ...

    Abstract This review endeavours to explore the power of quantum chemistry, especially density functional theory (DFT) to unravel mechanisms underlying the fascinating field of FLP chemistry. Apart from the fundamental mechanism of hydrogen activation by FLPs, borylation, silylation, polymerization, formation of heterocycles, reaction with small gaseous molecules, alkenes, terminal alkynes have also been reviewed. The role of DFT in understanding regio-selectivity, steric effects, London dispersion and covalent Interactions in FLPs are also discussed.
    MeSH term(s) Alkenes ; Alkynes ; Hydrogen ; Polymerization
    Chemical Substances Alkenes ; Alkynes ; Hydrogen (7YNJ3PO35Z)
    Language English
    Publishing date 2021-01-25
    Publishing country United States
    Document type Journal Article ; Review
    ZDB-ID 1396450-1
    ISSN 1873-4243 ; 1093-3263
    ISSN (online) 1873-4243
    ISSN 1093-3263
    DOI 10.1016/j.jmgm.2021.107846
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Cologne/Königswinter

    Zs.A 3491: Show issues Location:
    Je nach Verfügbarkeit (siehe Angabe bei Bestand)
    bis Jg. 1994: Bestellungen von Artikeln über das Online-Bestellformular
    Jg. 1995 - 2021: Lesesall (2.OG)
    ab Jg. 2022: Lesesaal (EG)

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  4. Article ; Online: Asymmetric Cationic Phosphines: Synthesis, Coordination Chemistry, and Reactivity.

    Kariuki, Benson M / Newman, Paul D

    Inorganic chemistry

    2018  Volume 57, Issue 15, Page(s) 9554–9563

    Abstract: A single enantiomer of a cationic phosphine, [α-CgPAmHMe] ... ...

    Abstract A single enantiomer of a cationic phosphine, [α-CgPAmHMe]BF
    Language English
    Publishing date 2018-08-06
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.8b01657
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Reactions promoted by hypervalent iodine reagents and boron Lewis acids.

    Dasgupta, Ayan / Thiehoff, Christian / Newman, Paul D / Wirth, Thomas / Melen, Rebecca L

    Organic & biomolecular chemistry

    2022  Volume 19, Issue 22, Page(s) 4852–4865

    Abstract: Understanding the role of boranes in hypervalent iodine chemistry will open up new reactivities which can be utilised in organic synthesis. Due to similar reactivities, λ3-iodanes have presented themselves as viable alternatives for many transformations ... ...

    Abstract Understanding the role of boranes in hypervalent iodine chemistry will open up new reactivities which can be utilised in organic synthesis. Due to similar reactivities, λ3-iodanes have presented themselves as viable alternatives for many transformations dominated by transition metals whilst mitigating some of the associated drawbacks of metal systems. As showcased by recent reports, boranes can adopt a dual role in hypervalent iodine chemistry that surpasses mere activation of the hypervalent iodine reagent. Increased efforts to harness this potential with diverse boranes will uncover exciting reactivity with high applicability across various disciplines including adoption in the pharmaceutical sciences. This review will be relevant to the wider synthetic community including organic, inorganic, materials, and medicinal chemists due to the versatility of hypervalent iodine chemistry especially in combination with borane activation or participation. We aim to highlight the development of hypervalent iodine compounds including their structure, bonding, synthesis and utility in metal-free organic synthesis in combination with Lewis acidic boranes.
    Language English
    Publishing date 2022-01-17
    Publishing country England
    Document type Journal Article ; Review ; Research Support, Non-U.S. Gov't
    ZDB-ID 2097583-1
    ISSN 1477-0539 ; 1477-0520
    ISSN (online) 1477-0539
    ISSN 1477-0520
    DOI 10.1039/d1ob00740h
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Remote control: stereoselective coordination of electron-deficient 2,2'-bipyridine ligands to Re(I) and Ir(III) cores.

    Jerwood, Kimberley / Lowy, Phoebe / Deeming, Laura / Kariuki, Benson M / Newman, Paul D

    Dalton transactions (Cambridge, England : 2003)

    2021  Volume 50, Issue 45, Page(s) 16459–16463

    Abstract: Highly diastereoselective coordination of unsymmetrical cationic 2,2'-bipyridine ligands bearing a chiral amidinium substituent to [Re(CO) ...

    Abstract Highly diastereoselective coordination of unsymmetrical cationic 2,2'-bipyridine ligands bearing a chiral amidinium substituent to [Re(CO)
    Language English
    Publishing date 2021-11-23
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d1dt02928b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands.

    Willcox, Darren / Carden, Jamie L / Ruddy, Adam J / Newman, Paul D / Melen, Rebecca L

    Dalton transactions (Cambridge, England : 2003)

    2020  Volume 49, Issue 8, Page(s) 2417–2420

    Abstract: The ability of alkali metal complexes featuring functionalized BINOL-derived ligands to catalyze ketone hydroboration reactions was explored. The reduced products were formed in excellent yields and with variable enantioselectivities dependent upon the ... ...

    Abstract The ability of alkali metal complexes featuring functionalized BINOL-derived ligands to catalyze ketone hydroboration reactions was explored. The reduced products were formed in excellent yields and with variable enantioselectivities dependent upon the nature of the ligand and the alkali metal cation.
    Language English
    Publishing date 2020-01-24
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d0dt00232a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Amidine functionalized phosphines: tuneable ligands for transition metals.

    Wilkins, Lewis C / Melen, Rebecca L / Platts, James A / Newman, Paul D

    Dalton transactions (Cambridge, England : 2003)

    2017  Volume 46, Issue 41, Page(s) 14234–14243

    Abstract: Attachment of racemic 1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1 ... ...

    Abstract Attachment of racemic 1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.1
    Language English
    Publishing date 2017-10-24
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c7dt03343e
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article: Ring-Expanded N-Heterocyclic Carbenes for Copper-Mediated Azide-Alkyne Click Cycloaddition Reactions.

    Sebest, Filip / Dunsford, Jay J / Adams, Matthew / Pivot, Jeremy / Newman, Paul D / Díez-González, Silvia

    ChemCatChem

    2018  Volume 10, Issue 9, Page(s) 2041–2045

    Abstract: A series of well-defined copper(I) complexes bearing ring-expanded N-heterocyclic carbene (NHC) ligands has been applied to the azide-alkyne cycloaddition reaction. The obtained results notably showed that the six-membered NHC ligands outperform well- ... ...

    Abstract A series of well-defined copper(I) complexes bearing ring-expanded N-heterocyclic carbene (NHC) ligands has been applied to the azide-alkyne cycloaddition reaction. The obtained results notably showed that the six-membered NHC ligands outperform well-established five-membered ones. [CuI(Mes-6)] displayed a remarkable catalytic activity while respecting the strict criteria for click reactions.
    Language English
    Publishing date 2018-03-07
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2501161-3
    ISSN 1867-3899 ; 1867-3880
    ISSN (online) 1867-3899
    ISSN 1867-3880
    DOI 10.1002/cctc.201701992
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Push and pull: the potential role of boron in N

    Ruddy, Adam J / Ould, Darren M C / Newman, Paul D / Melen, Rebecca L

    Dalton transactions (Cambridge, England : 2003)

    2018  Volume 47, Issue 31, Page(s) 10377–10381

    Abstract: Recent developments in main group chemistry towards the activation and conversion of ... ...

    Abstract Recent developments in main group chemistry towards the activation and conversion of N
    Language English
    Publishing date 2018-08-21
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c8dt01168k
    Database MEDical Literature Analysis and Retrieval System OnLINE

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