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  1. AU="Nicola, Coppede"
  2. AU="Dewitt, John M"
  3. AU="Sorin M. Dudea"
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  1. Article ; Online: Classification and Forecasting of Water Stress in Tomato Plants Using Bioristor Data

    Manuele Bettelli / Filippo Vurro / Riccardo Pecori / Michela Janni / Nicola Coppede / Andrea Zappettini / Daniele Tessera

    IEEE Access, Vol 11, Pp 34795-

    2023  Volume 34807

    Abstract: Water stress and in particular drought are some of the most significant factors affecting plant growth, food production, and thus food security. Furthermore, the possibility to predict and shape irrigation on real plant demands is priceless. The ... ...

    Abstract Water stress and in particular drought are some of the most significant factors affecting plant growth, food production, and thus food security. Furthermore, the possibility to predict and shape irrigation on real plant demands is priceless. The objective of this study is to characterize, classify, and forecast water stress in tomato plants by means of in vivo real time data obtained through a novel sensor, named bioristor, and of different artificial intelligence models. First of all, we have applied classification models, namely Decision Trees and Random Forest, to try to distinguish four different stress statuses of tomato plants. Then, we have predicted, through the help of recurrent neural networks, the future status of a plant when considering both a binary (water stressed and not water stressed) and a four-status scenario. The obtained results are very good in terms of accuracy, precision, recall, F-measure, and of the resulting confusion matrices, and they suggest that the considered novel data and features coming from the bioristor, together with the used machine and deep learning models, can be successfully applied to real-world on-the-field smart irrigation scenarios in the future.
    Keywords AI modeling and forecasting ; bioristor ; precision agriculture ; recurrent neural network ; tomato plants ; tree-based classifiers ; Electrical engineering. Electronics. Nuclear engineering ; TK1-9971
    Subject code 580
    Language English
    Publishing date 2023-01-01T00:00:00Z
    Publisher IEEE
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  2. Article ; Online: Towards In Vivo Monitoring of Ions Accumulation in Trees

    Davide Amato / Giuseppe Montanaro / Filippo Vurro / Nicola Coppedé / Nunzio Briglia / Angelo Petrozza / Michela Janni / Andrea Zappettini / Francesco Cellini / Vitale Nuzzo

    Applied Sciences, Vol 11, Iss 4729, p

    Response of an in Planta Organic Electrochemical Transistor Based Sensor to Water Flux Density, Light and Vapor Pressure Deficit Variation

    2021  Volume 4729

    Abstract: Research on organic electrochemical transistor (OECT) based sensors to monitor in vivo plant traits such as xylem sap concentration is attracting attention for their potential application in precision agriculture. Fabrication and electronic aspects of ... ...

    Abstract Research on organic electrochemical transistor (OECT) based sensors to monitor in vivo plant traits such as xylem sap concentration is attracting attention for their potential application in precision agriculture. Fabrication and electronic aspects of OECT have been the subject of extensive research while its characterization within the plant water relation context deserves further efforts. This study tested the hypothesis that the response (R) of an OECT (bioristor) implanted in the trunk of olive trees is inversely proportional to the water flux density flowing through the plant (Jw). This study also examined the influence on R of vapor pressure deficit ( VPD ) as coupled/uncoupled with light. R was hourly recorded in potted olive trees for a 10-day period concomitantly with Jw (weight loss method). A subgroup of trees was bagged in order to reduce VPD and in turn Jw, and other trees were located in a walk-in chamber where VPD and light were independently managed. R was tightly sensitive to diurnal oscillation of Jw and at negligible values of Jw (late afternoon and night) R increased. The bioristor was not sensitive to the VPD per se unless a light source was coupled to trigger Jw. This study preliminarily examined the suitability of bioristor to estimate the mean daily nutrients accumulation rate (Ca, K) in leaves comparing chemical and sensor-based procedures showing a good agreement between them opening new perspective towards the application of OECT sensor in precision agricultural cropping systems.
    Keywords bioristor ; mineral nutrition ; OECT ; precision agriculture ; PEDOT ; sap concentration ; Technology ; T ; Engineering (General). Civil engineering (General) ; TA1-2040 ; Biology (General) ; QH301-705.5 ; Physics ; QC1-999 ; Chemistry ; QD1-999
    Subject code 580
    Language English
    Publishing date 2021-05-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  3. Article ; Online: Real-time monitoring of Arundo donax response to saline stress through the application of in vivo sensing technology.

    Michela, Janni / Claudia, Cocozza / Federico, Brilli / Sara, Pignattelli / Filippo, Vurro / Nicola, Coppede / Manuele, Bettelli / Davide, Calestani / Loreto, Francesco / Zappettini, Andrea

    Scientific reports

    2021  Volume 11, Issue 1, Page(s) 18598

    Abstract: One of the main impacts of climate change on agriculture production is the dramatic increase of saline ( ... ...

    Abstract One of the main impacts of climate change on agriculture production is the dramatic increase of saline (Na
    Language English
    Publishing date 2021-09-20
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2615211-3
    ISSN 2045-2322 ; 2045-2322
    ISSN (online) 2045-2322
    ISSN 2045-2322
    DOI 10.1038/s41598-021-97872-6
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Methylglyoxal Adducts Levels in Blood Measured on Dried Spot by Portable Near-Infrared Spectroscopy

    Giuseppe Bonapace / Francesco Gentile / Nicola Coppedé / Maria Laura Coluccio / Virginia Garo / Marco Flavio Michele Vismara / Patrizio Candeloro / Giuseppe Donato / Natalia Malara

    Nanomaterials, Vol 11, Iss 2432, p

    2021  Volume 2432

    Abstract: The altered glucose metabolism characterising cancer cells determines an increased amount of methylglyoxal in their secretome. Previous studies have demonstrated that the methylglyoxal, in turn, modifies the protonation state (PS) of soluble proteins ... ...

    Abstract The altered glucose metabolism characterising cancer cells determines an increased amount of methylglyoxal in their secretome. Previous studies have demonstrated that the methylglyoxal, in turn, modifies the protonation state (PS) of soluble proteins contained in the secretomes of cultivated circulating tumour cells (CTCs). In this study, we describe a method to assess the content of methylglyoxal adducts (MAs) in the secretome by near-infrared (NIR) portable handheld spectroscopy and the extreme learning machine (ELM) algorithm. By measuring the vibration absorption functional groups containing hydrogen, such as C-H, O-H and N-H, NIR generates specific spectra. These spectra reflect alterations of the energy frequency of a sample bringing information about its MAs concentration levels. The algorithm deciphers the information encoded in the spectra and yields a quantitative estimate of the concentration of MAs in the sample. This procedure was used for the comparative analysis of different biological fluids extracted from patients suspected of having cancer (secretome, plasma, serum, interstitial fluid and whole blood) measured directly on the solute left on a surface upon a sample-drop cast and evaporation, without any sample pretreatment. Qualitative and quantitative regression models were built and tested to characterise the different levels of MAs by ELM. The final model we selected was able to automatically segregate tumour from non-tumour patients. The method is simple, rapid and repeatable; moreover, it can be integrated in portable electronic devices for point-of-care and remote testing of patients.
    Keywords methylglyoxal adducts ; near-infrared spectroscopy ; secretome ; early cancer detection ; point-of-care ; Chemistry ; QD1-999
    Subject code 610
    Language English
    Publishing date 2021-09-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  5. Article: In Vivo Phenotyping for the Early Detection of Drought Stress in Tomato

    Michela Janni / Nicola Coppede / Manuele Bettelli / Nunzio Briglia / Angelo Petrozza / Stephan Summerer / Filippo Vurro / Donatella Danzi / Francesco Cellini / Nelson Marmiroli / Domenico Pignone / Salvatore Iannotta / Andrea Zappettini

    Plant phenomics. 2019, v. 2019

    2019  

    Abstract: Drought stress imposes a major constraint over a crop yield and can be expected to grow in importance if the climate change predicted comes about. Improved methods are needed to facilitate crop management via the prompt detection of the onset of stress. ... ...

    Abstract Drought stress imposes a major constraint over a crop yield and can be expected to grow in importance if the climate change predicted comes about. Improved methods are needed to facilitate crop management via the prompt detection of the onset of stress. Here, we report the use of an in vivo OECT (organic electrochemical transistor) sensor, termed as bioristor, in the context of the drought response of the tomato plant. The device was integrated within the plant’s stem, thereby allowing for the continuous monitoring of the plant’s physiological status throughout its life cycle. Bioristor was able to detect changes of ion concentration in the sap upon drought, in particular, those dissolved and transported through the transpiration stream, thus efficiently detecting the occurrence of drought stress immediately after the priming of the defence responses. The bioristor’s acquired data were coupled with those obtained in a high-throughput phenotyping platform revealing the extreme complementarity of these methods to investigate the mechanisms triggered by the plant during the drought stress event.
    Keywords climate change ; crop management ; crop yield ; drought ; electrochemistry ; phenomics ; phenotype ; physiological state ; sap ; tomatoes ; transistors ; transpiration ; water stress
    Language English
    Publishing place American Association for the Advancement of Science (AAAS)
    Document type Article
    ISSN 2643-6515
    DOI 10.34133/2019/6168209
    Database NAL-Catalogue (AGRICOLA)

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  6. Article ; Online: Low Temperature Sensing Properties of a Nano Hybrid Material Based on ZnO Nanotetrapods and Titanyl Phthalocyanine

    Davide Calestani / Andrea Zappettini / Salvatore Iannotta / Roberto Mosca / Marco Villani / Nicola Coppedè

    Sensors, Vol 13, Iss 3, Pp 3445-

    2013  Volume 3453

    Abstract: ZnO nanotetrapods have recently been exploited for the realization of high-sensitivity gas sensors, but they are affected by the typical drawbacks of metal-oxides, i.e., poor selectivity and a relatively high working temperature. On the other hand, it ... ...

    Abstract ZnO nanotetrapods have recently been exploited for the realization of high-sensitivity gas sensors, but they are affected by the typical drawbacks of metal-oxides, i.e., poor selectivity and a relatively high working temperature. On the other hand, it has been also demonstrated that the combined use of nanostructured metal oxides and organic molecules can improve the gas sensing performance sensitivity or selectivity, even at lower temperatures. A gas sensor device, based on films of interconnected ZnO nanotetrapods properly functionalized by titanyl phthalocyanine (TiOPc), has been realized in order to combine the high surface to volume ratio and structural stability of the crystalline ZnO nanostructures with the enhanced sensitivity of the semiconducting TiOPc molecule, especially at low temperature. The electronic properties of the resulting nanohybrid material are different from those of each single component. The response of the hybrid nanostructure towards different gases has been compared with that of ZnO nanotetrapod without functionalization in order to highlight the peculiar properties of the hybrid interaction(s). The dynamic response in time has been studied for different gases and temperatures; in particular, an increase in the response to NO2 has been observed, even at room temperature. The formation of localized p-n heterojunctions and the possibility of exchanging charge carriers at the hybrid interface is shown to be crucial for the sensing mechanism.
    Keywords gas sensor ; ZnO nanostructures ; phthalocyanine ; NO2 ; room temperature ; Technology (General) ; T1-995 ; Technology ; T ; DOAJ:Technology (General) ; DOAJ:Technology and Engineering ; Analytical chemistry ; QD71-142 ; Chemistry ; QD1-999 ; Science ; Q ; DOAJ:Analytical Chemistry ; DOAJ:Chemistry
    Subject code 621
    Language English
    Publishing date 2013-03-01T00:00:00Z
    Publisher MDPI AG
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  7. Article ; Online: Microtexturing of the Conductive PEDOT:PSS Polymer for Superhydrophobic Organic Electrochemical Transistors

    Francesco Gentile / Nicola Coppedè / Giuseppe Tarabella / Marco Villani / Davide Calestani / Patrizio Candeloro / Salvatore Iannotta / Enzo Di Fabrizio

    BioMed Research International, Vol

    2014  Volume 2014

    Abstract: Superhydrophobic surfaces are bioinspired, nanotechnology artifacts, which feature a reduced friction coefficient, whereby they can be used for a number of very practical applications including, on the medical side, the manipulation of biological ... ...

    Abstract Superhydrophobic surfaces are bioinspired, nanotechnology artifacts, which feature a reduced friction coefficient, whereby they can be used for a number of very practical applications including, on the medical side, the manipulation of biological solutions. In this work, we integrated superhydrophobic patterns with the conducting polymer PEDOT:PSS, one of the most used polymers in organic electronics because highly sensitive to ionized species in solution. In doing so, we combined geometry and materials science to obtain an advanced device where, on account of the superhydrophobicity of the system, the solutions of interest can be manipulated and, on account of the conductive PEDOT:PSS polymer, the charged molecules dispersed inside can be quantitatively measured. This original substrate preparation allowed to perform electrochemical measurements on ionized species in solution with decreasing concentration down to 10−7 molar. Moreover, it was demonstrated the ability of the device of realizing specific, combined time and space resolved analysis of the sample. Collectively, these results demonstrate how a tight, interweaving integration of different disciplines can provide realistic tools for the detection of pathologies. The scheme here introduced offers breakthrough capabilities that are expected to radically improve both the pace and the productivity of biomedical research, creating an access revolution.
    Keywords Medicine ; R
    Language English
    Publishing date 2014-01-01T00:00:00Z
    Publisher Hindawi Limited
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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