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  1. Article ; Online: Continuous and near real-time measurements of gaseous elemental mercury (GEM) from an Unmanned Aerial Vehicle: A new approach to investigate the 3D distribution of GEM in the lower atmosphere.

    Cabassi, J / Lazzaroni, M / Giannini, L / Mariottini, D / Nisi, B / Rappuoli, D / Vaselli, O

    Chemosphere

    2021  Volume 288, Issue Pt 2, Page(s) 132547

    Abstract: We present the first real attempt to directly and continuously measure GEM through a Lumex RA-915 M, designed for real-time detection of mercury vapor, mounted on an UAV (Unmanned Aerial Vehicle, namely a heavy-lift octocopter), inside and outside the ... ...

    Abstract We present the first real attempt to directly and continuously measure GEM through a Lumex RA-915 M, designed for real-time detection of mercury vapor, mounted on an UAV (Unmanned Aerial Vehicle, namely a heavy-lift octocopter), inside and outside the former Hg-mining area of Abbadia San Salvatore (Mt. Amiata, Italy), known as a GEM source. We tested the effectiveness of the UAV-Lumex combination at different heights in selected sites pertaining to both mining facilities and surrounding urban zones, shedding light on the GEM spatial distribution and concentration variability. The Lumex great sensitivity and the octocopter optimal versatility and maneuverability, both horizontally and vertically, allowed to depict the GEM distribution in the atmosphere up to 60 m above the ground. The acquisition system was further optimized by: i) synchronizing Lumex and UAV GPS data by means of a stand-alone GPS that was previously synchronized with Lumex; ii) using a vertical sampling tube (1.20 m high) connected to the Lumex inlet to overcome the rotors strong airflows and turbulence that would have affected GEM measurements; iii) supplying the octocopter with batteries for power supply to avoid the release of exhaust gases; iv) taking the advantage of the UAV ability to land in small spaces and stop at selected altitudes. The resulting dot-map graphical representations, providing a realistic 3D picture of GEM vertical profiling during the flights in near real-time, were useful to verify whether the guideline concentrations indicated by competent authorities were exceeded. The results showed that the GEM concentrations in the urban area, located a few hundred meters from the mining structures, and close to already reclaimed areas remained at relatively low values. Contrarily, GEM contents showed significant variations and the highest concentrations above the facilities containing the old furnaces, where increasing GEM concentrations were recorded at decreasing heights or downwind.
    MeSH term(s) Atmosphere ; Italy ; Mercury ; Unmanned Aerial Devices
    Chemical Substances Mercury (FXS1BY2PGL)
    Language English
    Publishing date 2021-10-12
    Publishing country England
    Document type Journal Article
    ZDB-ID 120089-6
    ISSN 1879-1298 ; 0045-6535 ; 0366-7111
    ISSN (online) 1879-1298
    ISSN 0045-6535 ; 0366-7111
    DOI 10.1016/j.chemosphere.2021.132547
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article: Continuous and near real-time measurements of gaseous elemental mercury (GEM) from an Unmanned Aerial Vehicle: A new approach to investigate the 3D distribution of GEM in the lower atmosphere

    Cabassi, J. / Lazzaroni, M. / Giannini, L. / Mariottini, D. / Nisi, B. / Rappuoli, D. / Vaselli, O.

    Chemosphere. 2022 Feb., v. 288

    2022  

    Abstract: We present the first real attempt to directly and continuously measure GEM through a Lumex RA-915 M, designed for real-time detection of mercury vapor, mounted on an UAV (Unmanned Aerial Vehicle, namely a heavy-lift octocopter), inside and outside the ... ...

    Abstract We present the first real attempt to directly and continuously measure GEM through a Lumex RA-915 M, designed for real-time detection of mercury vapor, mounted on an UAV (Unmanned Aerial Vehicle, namely a heavy-lift octocopter), inside and outside the former Hg-mining area of Abbadia San Salvatore (Mt. Amiata, Italy), known as a GEM source. We tested the effectiveness of the UAV-Lumex combination at different heights in selected sites pertaining to both mining facilities and surrounding urban zones, shedding light on the GEM spatial distribution and concentration variability. The Lumex great sensitivity and the octocopter optimal versatility and maneuverability, both horizontally and vertically, allowed to depict the GEM distribution in the atmosphere up to 60 m above the ground. The acquisition system was further optimized by: i) synchronizing Lumex and UAV GPS data by means of a stand-alone GPS that was previously synchronized with Lumex; ii) using a vertical sampling tube (1.20 m high) connected to the Lumex inlet to overcome the rotors strong airflows and turbulence that would have affected GEM measurements; iii) supplying the octocopter with batteries for power supply to avoid the release of exhaust gases; iv) taking the advantage of the UAV ability to land in small spaces and stop at selected altitudes. The resulting dot-map graphical representations, providing a realistic 3D picture of GEM vertical profiling during the flights in near real-time, were useful to verify whether the guideline concentrations indicated by competent authorities were exceeded. The results showed that the GEM concentrations in the urban area, located a few hundred meters from the mining structures, and close to already reclaimed areas remained at relatively low values. Contrarily, GEM contents showed significant variations and the highest concentrations above the facilities containing the old furnaces, where increasing GEM concentrations were recorded at decreasing heights or downwind.
    Keywords guidelines ; maneuverability ; mercury ; turbulent flow ; unmanned aerial vehicles ; urban areas ; vapors ; Italy
    Language English
    Dates of publication 2022-02
    Publishing place Elsevier Ltd
    Document type Article
    ZDB-ID 120089-6
    ISSN 1879-1298 ; 0045-6535 ; 0366-7111
    ISSN (online) 1879-1298
    ISSN 0045-6535 ; 0366-7111
    DOI 10.1016/j.chemosphere.2021.132547
    Database NAL-Catalogue (AGRICOLA)

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  3. Article: Mercury distribution in plants and soils from the former mining area of Abbadia San Salvatore (Tuscany, central Italy).

    Meloni, Federica / Farieri, Alessandro / Higueras, Pablo L / Esbrí, José M / Nisi, Barbara / Cabassi, Jacopo / Rappuoli, Daniele / Vaselli, Orlando

    Research square

    2023  

    Abstract: The distribution of heavy metals in plants growing in soils from active and abandoned mining areas is of scientific significance as it allows one to recognize their ability to survive in a hostile environment and to provide useful indications for ... ...

    Abstract The distribution of heavy metals in plants growing in soils from active and abandoned mining areas is of scientific significance as it allows one to recognize their ability to survive in a hostile environment and to provide useful indications for phytoremediation operations. In this work, soils developed in the former Hg-mining area of Abbadia San Salvatore (Tuscany, Central Italy) were analyzed for total, leached Hg, % of organic- and inorganic-related Hg. The dehydrogenase enzyme activity (DHA) was also measured with the aim to evaluate the status of the soil, being characterized by high Hg content. Eventually, the concentration of Hg in the different parts of the plants growing on these soils was analyzed. The soils showed Hg content up to 1068 mg kg
    Language English
    Publishing date 2023-04-19
    Publishing country United States
    Document type Preprint
    DOI 10.21203/rs.3.rs-2823040/v1
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Mercury distribution in plants and soils from the former mining area of Abbadia San Salvatore (Tuscany, Central Italy).

    Meloni, Federica / Farieri, Alessandro / Higueras, Pablo L / Esbrí, José M / Nisi, Barbara / Cabassi, Jacopo / Rappuoli, Daniele / Vaselli, Orlando

    Environmental geochemistry and health

    2023  Volume 45, Issue 11, Page(s) 8523–8538

    Abstract: The distribution of heavy metals in plants (Castanea sativa, Sambucus nigra, Verbascum thapsus, Popolus spp., Salix spp., Acer pseudoplatanus, Robinia pseudoacacia) growing in soils from active and abandoned mining areas is of scientific significance as ... ...

    Abstract The distribution of heavy metals in plants (Castanea sativa, Sambucus nigra, Verbascum thapsus, Popolus spp., Salix spp., Acer pseudoplatanus, Robinia pseudoacacia) growing in soils from active and abandoned mining areas is of scientific significance as it allows to recognize their ability to survive in a hostile environment and provide useful indications for phytoremediation operations. In this work, soils from the former Hg-mining area of Abbadia San Salvatore (Tuscany, Central Italy) were analyzed for total, leached Hg, % of organic and inorganic-related Hg. The dehydrogenase enzyme activity (DHA) was also measured with the aim to evaluate the status of the soil, being characterized by high Hg contents (up to 1068 mg kg
    MeSH term(s) Mercury/analysis ; Environmental Monitoring ; Soil ; Soil Pollutants/analysis ; Italy ; Plants
    Chemical Substances Mercury (FXS1BY2PGL) ; Soil ; Soil Pollutants
    Language English
    Publishing date 2023-08-30
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 52039-1
    ISSN 1573-2983 ; 0142-7245 ; 0269-4042
    ISSN (online) 1573-2983
    ISSN 0142-7245 ; 0269-4042
    DOI 10.1007/s10653-023-01739-w
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  5. Article ; Online: Contamination Assessment and Temporal Evolution of Nitrates in the Shallow Aquifer of the Metauro River Plain (Adriatic Sea, Italy) after Remediation Actions.

    Taussi, Marco / Gozzi, Caterina / Vaselli, Orlando / Cabassi, Jacopo / Menichini, Matia / Doveri, Marco / Romei, Marco / Ferretti, Alfredo / Gambioli, Alma / Nisi, Barbara

    International journal of environmental research and public health

    2022  Volume 19, Issue 19

    Abstract: Over the last decades, groundwater resources at global level have suffered a significant deterioration due to nitrate pollution, mainly related to the input of agricultural fertilizers, manure, sewage, and untreated urban and industrial effluents. The ... ...

    Abstract Over the last decades, groundwater resources at global level have suffered a significant deterioration due to nitrate pollution, mainly related to the input of agricultural fertilizers, manure, sewage, and untreated urban and industrial effluents. The most impacted waters are those forming surface and shallow reservoirs, which usually play a key role in supplying waters to civil, agricultural, and industrial activities. The terminal portion of the Metauro River plain, located in central Italy along the Adriatic Sea coastline, hosts a strategic phreatic aquifer that, along with the surface water of the Metauro River, supplies water to the local population (i.e., about 60,000 people). This shallow coastal aquifer experiences a long-lasting story of nitrate contamination since the 1970s when the increase in the use of agricultural fertilizers contributed to very high levels of pollution (NO
    MeSH term(s) Environmental Monitoring ; Fertilizers/analysis ; Groundwater/analysis ; Humans ; Manure/analysis ; Nitrates/analysis ; Nitrogen Oxides/analysis ; Rivers ; Sewage/analysis ; Water/analysis ; Water Pollutants, Chemical/analysis
    Chemical Substances Fertilizers ; Manure ; Nitrates ; Nitrogen Oxides ; Sewage ; Water Pollutants, Chemical ; Water (059QF0KO0R)
    Language English
    Publishing date 2022-09-27
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2175195-X
    ISSN 1660-4601 ; 1661-7827
    ISSN (online) 1660-4601
    ISSN 1661-7827
    DOI 10.3390/ijerph191912231
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  6. Article ; Online: Mercury and Arsenic Discharge from Circumneutral Waters Associated with the Former Mining Area of Abbadia San Salvatore (Tuscany, Central Italy).

    Lazzaroni, Marta / Vetuschi Zuccolini, Marino / Nisi, Barbara / Cabassi, Jacopo / Caliro, Stefano / Rappuoli, Daniele / Vaselli, Orlando

    International journal of environmental research and public health

    2022  Volume 19, Issue 9

    Abstract: Dissolved and suspended toxic elements in water discharged from abandoned and active mining areas pose several critical issues, since they represent a threat to the environment. In this work, we investigated the water, suspended particulates, and stream ... ...

    Abstract Dissolved and suspended toxic elements in water discharged from abandoned and active mining areas pose several critical issues, since they represent a threat to the environment. In this work, we investigated the water, suspended particulates, and stream sediments of a 2.1 km long creek (Fosso della Chiusa) that is fed by waters draining the galleries of the abandoned Hg mining area of Abbadia San Salvatore (Mt. Amiata, Tuscany, central Italy). The geochemical results show evidence that the studied matrices are characterized by relatively high concentrations of Hg and As, whereas those of Sb are generally close to or below the instrumental detection limit. Independent of the matrices, the concentration of As decreases from the emergence point to the confluence with the Pagliola creek. In contrast, Hg concentrations display more complex behavior, as water and sediment are mainly characterized by concentrations that significantly increase along the water course. According to the geoaccumulation index (I
    MeSH term(s) Arsenic/analysis ; Environmental Monitoring/methods ; Geologic Sediments/chemistry ; Mercury/analysis ; Mining ; Rivers/chemistry ; Water ; Water Pollutants, Chemical/analysis
    Chemical Substances Water Pollutants, Chemical ; Water (059QF0KO0R) ; Mercury (FXS1BY2PGL) ; Arsenic (N712M78A8G)
    Language English
    Publishing date 2022-04-23
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2175195-X
    ISSN 1660-4601 ; 1661-7827
    ISSN (online) 1660-4601
    ISSN 1661-7827
    DOI 10.3390/ijerph19095131
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  7. Article: Hydrogeochemical surveys of shallow coastal aquifers: A conceptual model to set-up a monitoring network and increase the resilience of a strategic groundwater system to climate change and anthropogenic pressure

    Nisi, Barbara / Vaselli, Orlando / Taussi, Marco / Doveri, Marco / Menichini, Matia / Cabassi, Jacopo / Raco, Brunella / Botteghi, Serena / Mussi, Mario / Masetti, Giulio

    Applied geochemistry. 2022 July, v. 142

    2022  

    Abstract: Salinization is a main concern for coastal aquifers due to climate change and incremental anthropogenic pressure. The Mediterranean area is particularly sensitive to this process, being several coastal aquifers already affected by seawater intrusion. The ...

    Abstract Salinization is a main concern for coastal aquifers due to climate change and incremental anthropogenic pressure. The Mediterranean area is particularly sensitive to this process, being several coastal aquifers already affected by seawater intrusion. The Fano coastal aquifer, located in the northern part of the Adriatic Sea (Italy), has a regional importance since it supplies drinkable water to the local communities and may be subjected to salinization given its intrinsic vulnerability and the awaited human and climate pressure. In this work, for the first time a detailed hydrogeochemical and isotopic study on the Fano shallow aquifer is presented to highlight the quality of this groundwater system. The hydrological, geochemical and isotopic data indicate a strong nitrate contamination in the central part of the basin, forcing the local water management company to inject low-NO₃ waters from the main river course (Metauro River) to reduce the impact due to the N-bearing species. Differently from other coastal aquifers located along the Adriatic Sea where the seawater wedge is deteriorating most groundwater systems, our results and geochemical modeling suggest that the shallow aquifer of Fano is not apparently affected by salinization. This achievement makes this aquifer suitable for assessing whether the groundwater system might be evolving toward a seawater-contaminated aquifer. According to the proposed hydrogeochemical conceptual model, a monitor network should be deployed by the local authorities and the water management company to take appropriate measures to minimize the risk of seawater intrusion, should the hydrogeochemical and isotopic parameters indicate an incipient ingression of seawater.
    Keywords anthropogenic activities ; aquifers ; basins ; climate ; climate change ; drinking water ; groundwater ; humans ; hydrogeochemistry ; models ; nitrates ; risk ; rivers ; saltwater intrusion ; seawater ; water management ; Adriatic Sea ; Italy ; Mediterranean region
    Language English
    Dates of publication 2022-07
    Publishing place Elsevier Ltd
    Document type Article
    ZDB-ID 1499242-5
    ISSN 0883-2927
    ISSN 0883-2927
    DOI 10.1016/j.apgeochem.2022.105350
    Database NAL-Catalogue (AGRICOLA)

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  8. Article: The Campo de Calatrava Volcanic Field (central Spain): Fluid geochemistry in a CO2-rich area

    Nisi, B / A. Delgado Huertas / E.L. Maletic / F. Tassi / J. Elio / L. Giannini / M. Guidi / O. Vaselli / S. Marchionni / T.H. Darrah

    Applied geochemistry. 2019 Mar., v. 102

    2019  

    Abstract: The Campo de Calatrava Volcanic Field (CCVF) located in central-southern Spain (along with Selva-Emporda in Catalonia, NE Spain) is regarded as one of the most important CO2 emitting zones in Peninsular Spain. Here, we report and evaluate new molecular ... ...

    Abstract The Campo de Calatrava Volcanic Field (CCVF) located in central-southern Spain (along with Selva-Emporda in Catalonia, NE Spain) is regarded as one of the most important CO2 emitting zones in Peninsular Spain. Here, we report and evaluate new molecular and isotopic geochemistry of thermal waters and CO2-rich gas discharges from the CCVF. Locally, these CO2-rich fluid emissions represent the remnants of the past volcanic activity that affected this area from the late Miocene through the Quaternary, with the most recent events occurring in the Holocene. The locations of discharging fluids and previous volcanic centers appear to be aligned along well-defined NW-SE and NNW-SSE lineaments, with subordinate trends in the ENE-WSW direction. The chemical and isotopic composition of the thermal waters suggests a meteoric origin, dominated by three distinct geochemical facies: 1) HCO3-Mg(Ca) type waters, associated with a relatively shallow aquifer and related to the interaction of meteoric waters with CO2-rich gases, alkaline volcanic products, and sedimentary formations, 2) SO4(Cl)-Ca(Mg) type waters, which stems from the two rivers (Guadiana and Jabalón) that drain Triassic evaporitic rocks before entering the study area, and 3) HCO3-Na type waters, hosted in deep geopressurized CO2-rich reservoirs within the Ordovician basement rocks.The 87Sr/86Sr isotopic compositions (ranging between 0.70415 and 0.71623) and δ34S-SO4 values (+10.7 to +18.3‰ vs. CDT) of CO2-rich fluids are consistent with interactions between water and either the Paleozoic basement, Triassic evaporites, Quaternary volcanic rocks, or a combination thereof. Dissolution of a CO2-rich gas phase into the aquifer produces low pH values (down to 5.4) and enhances water-rock interactions causing relatively high salinity (Total Ionic Salinity: up to ∼185 meq/L). Carbon dioxide is by far the most abundant gas constituent (up to 992 mmol/mol) and is dominated by mantle-derived sources as indicated by the combination of relatively high helium isotopic ratios (up to 2.7 R/Ra), high isotopic ratios of carbon in CO2 (ranging between −6.8 and −3.2‰ V-PDB), and the carbon isotopic signature of TDIC (from −6.8 to +2.2‰ vs. VPDB).In the last two decades, numerous (CO2-rich) gas blowouts have occurred in the area during well drillings, suggesting the presence of a geopressurized gas reservoir at relatively shallow depth.
    Keywords aquifers ; carbon ; carbon dioxide ; emissions ; gases ; geochemistry ; helium ; magnesium ; Miocene epoch ; Ordovician period ; pH ; rivers ; salinity ; Triassic period ; volcanic activity ; volcanic rocks ; Spain
    Language English
    Dates of publication 2019-03
    Size p. 153-170.
    Publishing place Elsevier Ltd
    Document type Article
    ZDB-ID 1499242-5
    ISSN 0883-2927
    ISSN 0883-2927
    DOI 10.1016/j.apgeochem.2019.01.011
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  9. Article ; Online: Volatile organic compounds (VOCs) from diffuse degassing areas: Interstitial soil gases as message bearers from deep hydrothermal reservoirs.

    Venturi, Stefania / Randazzo, Antonio / Cabassi, Jacopo / Cinti, Daniele / Meloni, Federica / Procesi, Monia / Nisi, Barbara / Voltattorni, Nunzia / Capecchiacci, Francesco / Ricci, Tullio / Vaselli, Orlando / Tassi, Franco

    The Science of the total environment

    2023  Volume 912, Page(s) 169047

    Abstract: The chemical composition of volatile organic compounds (VOCs) in interstitial soil gases from hydrothermal areas is commonly shaped by both deep hydrothermal conditions (e.g., temperature, redox, sulfur fugacity) and shallow secondary processes occurring ...

    Abstract The chemical composition of volatile organic compounds (VOCs) in interstitial soil gases from hydrothermal areas is commonly shaped by both deep hydrothermal conditions (e.g., temperature, redox, sulfur fugacity) and shallow secondary processes occurring near the soil-atmosphere interface. Caldara di Manziana and Solfatara di Nepi, i.e., two hydrothermal systems characterized by diverse physicochemical conditions located in the Sabatini Volcanic District and Vicano-Cimino Volcanic District, respectively (Central Italy), were investigated to evaluate the capability of VOCs in soil gases to preserve information from the respective feeding deep fluid reservoirs. Hierarchical cluster analyses and robust principal component analyses allowed recognition of distinct groups of chemical parameters of soil gases collected from the two study areas. The compositional dissimilarities from the free-gas discharges were indeed reflected by the chemical features of soil gases collected from each site, despite the occurrence of shallow processes, e.g., air mixing and microbial degradation processes, affecting VOCs. Four distinct groups of VOCs were recognized suggesting similar sources and/or geochemical behaviors, as follows: (i) S-bearing compounds, whose abundance (in particular that of thiophenes) was strictly dependent on the sulfur fugacity in the feeding system; (ii) C
    Language English
    Publishing date 2023-12-05
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2023.169047
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  10. Article: Statistical methods for the geochemical characterisation of surface waters: The case study of the Tiber River basin (Central Italy)

    Gozzi, C / Buccianti, A / Filzmoser, P / Nisi, B / Vaselli, O

    Computers & geosciences. 2019 June 17,

    2019  

    Abstract: Studying the chemistry of surface waters and their resilience to compositional changes represents a global challenge to preserve them from human- and changing climate-induced modifications. River waters are sentinel parameters for all processes occurring ...

    Abstract Studying the chemistry of surface waters and their resilience to compositional changes represents a global challenge to preserve them from human- and changing climate-induced modifications. River waters are sentinel parameters for all processes occurring in a river basin. This is particularly true for regional watersheds, which can include both natural- and anthropogenic-sourced solutes such as those present in the Tiber River basin, the biggest one in Central Italy. In this work, innovative applications of statistical methods are proposed, in the perspective of Compositional Data Analysis theory, in order to consider the geochemical riverine system as a whole and detect compositional changes throughout the catchment. Robust compositional biplots highlighted different sources of variability linked to geological (low variability) and antrophogenic origin (high variability) of the main compounds, thus identifying a hierarchy in the variance of the riverine geochemical processes. On a different scale, the innovative use of the robust Mahalanobis distance in an iterative way monitored spatial compositional shifts for single cases. The effectiveness of this method consists in minimising the influence of an individual anomalous point on the compositional centre and the covariance structure of the data highlighting when along the river a significant compositional shift occurs. The study provides powerful compositional tools for detecting potential contamination events or climate-induced modifications both at catchment and river scale.
    Keywords case studies ; climatic factors ; computers ; covariance ; geochemistry ; humans ; river water ; rivers ; solutes ; surface water ; variance ; watersheds ; Italy
    Language English
    Dates of publication 2019-0617
    Publishing place Elsevier Ltd
    Document type Article
    Note Pre-press version
    ISSN 0098-3004
    DOI 10.1016/j.cageo.2019.06.011
    Database NAL-Catalogue (AGRICOLA)

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