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  1. Article ; Online: On the use of satellite observations to fill gaps in the Halley station total ozone record

    L. N. Zhang / S. Solomon / K. A. Stone / J. D. Shanklin / J. D. Eveson / S. Colwell / J. P. Burrows / M. Weber / P. F. Levelt / N. A. Kramarova / D. P. Haffner

    Atmospheric Chemistry and Physics, Vol 21, Pp 9829-

    2021  Volume 9838

    Abstract: Measurements by the Dobson ozone spectrophotometer at the British Antarctic Survey's (BAS) Halley research station form a record of Antarctic total column ozone that dates back to 1956. Due to its location, length, and completeness, the record has been, ... ...

    Abstract Measurements by the Dobson ozone spectrophotometer at the British Antarctic Survey's (BAS) Halley research station form a record of Antarctic total column ozone that dates back to 1956. Due to its location, length, and completeness, the record has been, and continues to be, uniquely important for studies of long-term changes in Antarctic ozone. However, a crack in the ice shelf on which it resides forced the station to abruptly close in February of 2017, leading to a gap of two ozone hole seasons in its historic record. We develop and test a method for filling in the record of Halley total ozone by combining and adjusting overpass data from a range of different satellite instruments. Comparisons to the Dobson suggest that our method reproduces monthly ground-based total ozone values with an average difference of 1.1 ± 6.2 DU for the satellites used to fill in the 2017–2018 gap. We show that our approach more closely reproduces the Dobson measurements than simply using the raw satellite average or data from a single satellite instrument. The method also provides a check on the consistency of the provisional data from the automated Dobson used at Halley after 2018 with earlier manual Dobson data and suggests that there were likely inconsistencies between the two. The filled Halley dataset provides further support that the Antarctic ozone hole is healing, not only during September but also in January.
    Keywords Physics ; QC1-999 ; Chemistry ; QD1-999
    Subject code 290
    Language English
    Publishing date 2021-06-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  2. Article ; Online: Air quality impacts of COVID-19 lockdown measures detected from space using high spatial resolution observations of multiple trace gases from Sentinel-5P/TROPOMI

    P. F. Levelt / D. C. Stein Zweers / I. Aben / M. Bauwens / T. Borsdorff / I. De Smedt / H. J. Eskes / C. Lerot / D. G. Loyola / F. Romahn / T. Stavrakou / N. Theys / M. Van Roozendael / J. P. Veefkind / T. Verhoelst

    Atmospheric Chemistry and Physics, Vol 22, Pp 10319-

    2022  Volume 10351

    Abstract: The aim of this paper is to highlight how TROPOspheric Monitoring Instrument (TROPOMI) trace gas data can best be used and interpreted to understand event-based impacts on air quality from regional to city scales around the globe. For this study, we ... ...

    Abstract The aim of this paper is to highlight how TROPOspheric Monitoring Instrument (TROPOMI) trace gas data can best be used and interpreted to understand event-based impacts on air quality from regional to city scales around the globe. For this study, we present the observed changes in the atmospheric column amounts of five trace gases (NO 2 , SO 2 , CO, HCHO, and CHOCHO) detected by the Sentinel-5P TROPOMI instrument and driven by reductions in anthropogenic emissions due to COVID-19 lockdown measures in 2020. We report clear COVID-19-related decreases in TROPOMI NO 2 column amounts on all continents. For megacities, reductions in column amounts of tropospheric NO 2 range between 14 % and 63 %. For China and India, supported by NO 2 observations, where the primary source of anthropogenic SO 2 is coal-fired power generation, we were able to detect sector-specific emission changes using the SO 2 data. For HCHO and CHOCHO, we consistently observe anthropogenic changes in 2-week-averaged column amounts over China and India during the early phases of the lockdown periods. That these variations over such a short timescale are detectable from space is due to the high resolution and improved sensitivity of the TROPOMI instrument. For CO, we observe a small reduction over China, which is in concert with the other trace gas reductions observed during lockdown; however, large interannual differences prevent firm conclusions from being drawn. The joint analysis of COVID-19-lockdown-driven reductions in satellite-observed trace gas column amounts using the latest operational and scientific retrieval techniques for five species concomitantly is unprecedented. However, the meteorologically and seasonally driven variability of the five trace gases does not allow for drawing fully quantitative conclusions on the reduction in anthropogenic emissions based on TROPOMI observations alone. We anticipate that in future the combined use of inverse modeling techniques with the high spatial resolution data from S5P/TROPOMI for all observed ...
    Keywords Physics ; QC1-999 ; Chemistry ; QD1-999
    Subject code 550 ; 520
    Language English
    Publishing date 2022-08-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  3. Article ; Online: Simultaneous assimilation of ozone profiles from multiple UV-VIS satellite instruments

    J. C. A. van Peet / R. J. van der A / H. M. Kelder / P. F. Levelt

    Atmospheric Chemistry and Physics, Vol 18, Pp 1685-

    2018  Volume 1704

    Abstract: A three-dimensional global ozone distribution has been derived from assimilation of ozone profiles that were observed by satellites. By simultaneous assimilation of ozone profiles retrieved from the nadir looking satellite instruments Global Ozone ... ...

    Abstract A three-dimensional global ozone distribution has been derived from assimilation of ozone profiles that were observed by satellites. By simultaneous assimilation of ozone profiles retrieved from the nadir looking satellite instruments Global Ozone Monitoring Experiment 2 (GOME-2) and Ozone Monitoring Instrument (OMI), which measure the atmosphere at different times of the day, the quality of the derived atmospheric ozone field has been improved. The assimilation is using an extended Kalman filter in which chemical transport model TM5 has been used for the forecast. The combined assimilation of both GOME-2 and OMI improves upon the assimilation results of a single sensor. The new assimilation system has been demonstrated by processing 4 years of data from 2008 to 2011. Validation of the assimilation output by comparison with sondes shows that biases vary between −5 and +10 % between the surface and 100 hPa. The biases for the combined assimilation vary between −3 and +3 % in the region between 100 and 10 hPa where GOME-2 and OMI are most sensitive. This is a strong improvement compared to direct retrievals of ozone profiles from satellite observations.
    Keywords Physics ; QC1-999 ; Chemistry ; QD1-999
    Subject code 290
    Language English
    Publishing date 2018-02-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  4. Article ; Online: NO x emission estimates during the 2014 Youth Olympic Games in Nanjing

    J. Ding / R. J. van der A / B. Mijling / P. F. Levelt / N. Hao

    Atmospheric Chemistry and Physics Discussions, Vol 15, Iss 5, Pp 6337-

    2015  Volume 6372

    Abstract: The Nanjing Government has taken temporary environmental regulations to guarantee good air quality during the Youth Olympic Games (YOG) in 2014. We study the effect of those regulations by applying the emission estimate algorithm DECSO (Daily Emission ... ...

    Abstract The Nanjing Government has taken temporary environmental regulations to guarantee good air quality during the Youth Olympic Games (YOG) in 2014. We study the effect of those regulations by applying the emission estimate algorithm DECSO (Daily Emission estimates Constrained by Satellite Observations) to measurements of the Ozone Monitoring Instrument (OMI). We improved DECSO by updating the chemical transport model CHIMERE from v2006 to v2013 and by adding an Observation minus Forecast (OmF) criterion to filter outlying satellite retrievals due to high aerosol concentrations. The comparison of model results with both ground and satellite observations indicates that CHIMERE v2013 is better performing than CHIMERE v2006. After filtering the satellite observations with high aerosol loads that were leading to large OmF values, unrealistic jumps in the emission estimates are removed. Despite the cloudy conditions during the YOG we could still see a decrease of tropospheric NO 2 column concentrations of about 32% in the OMI observations as compared to the average NO 2 concentrations from 2005 to 2012. The results of the improved DECSO algorithm for NO x emissions show a reduction of at least 25% during the YOG period. This indicates that air quality regulations taken by the local government were successful. The algorithm is also able to detect an emission reduction of 10% during the Chinese Spring Festival. This study demonstrates the capacity of the DECSO algorithm to capture the change of NO x emissions on a monthly scale. We also show that the observed concentrations and the derived emissions show different patterns that provide complimentary information. For example, the Nanjing smog episode in December 2013 led to a strong increase in NO 2 concentrations without an increase in NO x emissions. Furthermore, DECSO gives us important information of the non-trivial seasonal relation between NO x emissions and NO 2 concentrations on a local scale.
    Keywords Environmental sciences ; GE1-350 ; Geography. Anthropology. Recreation ; G ; Geophysics. Cosmic physics ; QC801-809
    Subject code 290
    Language English
    Publishing date 2015-03-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  5. Article ; Online: NO x emission estimates during the 2014 Youth Olympic Games in Nanjing

    J. Ding / R. J. van der A / B. Mijling / P. F. Levelt / N. Hao

    Atmospheric Chemistry and Physics, Vol 15, Iss 16, Pp 9399-

    2015  Volume 9412

    Abstract: The Nanjing Government applied temporary environmental regulations to guarantee good air quality during the Youth Olympic Games (YOG) in 2014. We study the effect of those regulations by applying the emission estimate algorithm DECSO (Daily Emission ... ...

    Abstract The Nanjing Government applied temporary environmental regulations to guarantee good air quality during the Youth Olympic Games (YOG) in 2014. We study the effect of those regulations by applying the emission estimate algorithm DECSO (Daily Emission estimates Constrained by Satellite Observations) to measurements of the Ozone Monitoring Instrument (OMI). We improved DECSO by updating the chemical transport model CHIMERE from v2006 to v2013 and by adding an Observation minus Forecast (OmF) criterion to filter outlying satellite retrievals due to high aerosol concentrations. The comparison of model results with both ground and satellite observations indicates that CHIMERE v2013 is better performing than CHIMERE v2006. After filtering the satellite observations with high aerosol loads that were leading to large OmF values, unrealistic jumps in the emission estimates are removed. Despite the cloudy conditions during the YOG we could still see a decrease of tropospheric NO 2 column concentrations of about 32 % in the OMI observations when compared to the average NO 2 columns from 2005 to 2012. The results of the improved DECSO algorithm for NO x emissions show a reduction of at least 25 % during the YOG period and afterwards. This indicates that air quality regulations taken by the local government have an effect in reducing NO x emissions. The algorithm is also able to detect an emission reduction of 10 % during the Chinese Spring Festival. This study demonstrates the capacity of the DECSO algorithm to capture the change of NO x emissions on a monthly scale. We also show that the observed NO 2 columns and the derived emissions show different patterns that provide complimentary information. For example, the Nanjing smog episode in December 2013 led to a strong increase in NO 2 concentrations without an increase in NO x emissions. Furthermore, DECSO gives us important information on the non-trivial seasonal relation between NO x emissions and NO 2 concentrations on a local scale.
    Keywords Physics ; QC1-999 ; Chemistry ; QD1-999
    Subject code 290
    Language English
    Publishing date 2015-08-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  6. Article: Evaluation of broadband surface solar irradiance derived from the Ozone Monitoring Instrument

    Wang, P / J.P. Veefkind / M. Sneep / P. Stammes / P.F. Levelt

    Remote sensing of environment. 2014 June, v. 149

    2014  

    Abstract: Surface solar irradiance (SSI) data are important for planning and estimating the production of solar power plants. Long-term high quality surface solar radiation data are needed for monitoring climate change. This paper presents a new surface solar ... ...

    Abstract Surface solar irradiance (SSI) data are important for planning and estimating the production of solar power plants. Long-term high quality surface solar radiation data are needed for monitoring climate change. This paper presents a new surface solar irradiance dataset, the broadband (0.2–4μm) surface solar irradiance product derived from the Ozone Monitoring Instrument (OMI). The OMI SSI algorithm is based on the Heliosat method and uses the OMI O2–O2 cloud product as main input. The OMI SSI data are validated against the globally distributed Baseline Surface Radiation Network (BSRN) measurements at 19 stations for the year 2008. Furthermore, the monthly mean OMI SSI data are compared to independent surface solar irradiance products from International Satellite Cloud Climatology Project Flux Data (ISCCP-FD) and Clouds and the Earth's Radiant Energy System (CERES) data for the year 2005. The mean difference between OMI SSI and BSRN global (direct+diffuse) irradiances is −1.2Wm−2 (−0.2%), the root mean square error is 100.1Wm−2 (18.1%), and the mean absolute error is 67.8Wm−2 (12.2%). The differences between OMI SSI and BSRN global irradiances are smaller over continental and coastal sites and larger over deserts and islands. OMI SSI has a good agreement with the CERES shortwave (SW) model B surface downward flux (SDF) product. The correlation coefficient and index of agreement between monthly mean 1-degree gridded OMI SSI and CERES SW SDF are >0.99. OMI SSI is lower than CERES SW SDF which is partly due to the solar zenith angle. On average, OMI SSI is 13.5Wm−2 (2.5%) lower than the ISCCP-FD SW surface downward flux and the correlation coefficient and index of agreement are >0.98 for every month.
    Keywords algorithms ; climate change ; climatology ; correlation ; data collection ; deserts ; energy ; islands ; monitoring ; ozone ; planning ; power plants ; remote sensing ; satellites ; solar energy ; solar radiation
    Language English
    Dates of publication 2014-06
    Size p. 88-99.
    Publishing place Elsevier Inc.
    Document type Article
    ZDB-ID 431483-9
    ISSN 0034-4257
    ISSN 0034-4257
    DOI 10.1016/j.rse.2014.03.036
    Database NAL-Catalogue (AGRICOLA)

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  7. Article ; Online: MAX-DOAS tropospheric nitrogen dioxide column measurements compared with the Lotos-Euros air quality model

    T. Vlemmix / H. J. Eskes / A. J. M. Piters / M. Schaap / F. J. Sauter / H. Kelder / P. F. Levelt

    Atmospheric Chemistry and Physics, Vol 15, Iss 3, Pp 1313-

    2015  Volume 1330

    Abstract: A 14-month data set of MAX-DOAS (Multi-Axis Differential Optical Absorption Spectroscopy) tropospheric NO 2 column observations in De Bilt, the Netherlands, has been compared with the regional air quality model Lotos-Euros. The model was run on a 7×7 km ... ...

    Abstract A 14-month data set of MAX-DOAS (Multi-Axis Differential Optical Absorption Spectroscopy) tropospheric NO 2 column observations in De Bilt, the Netherlands, has been compared with the regional air quality model Lotos-Euros. The model was run on a 7×7 km 2 grid, the same resolution as the emission inventory used. A study was performed to assess the effect of clouds on the retrieval accuracy of the MAX-DOAS observations. Good agreement was found between modeled and measured tropospheric NO 2 columns, with an average difference of less than 1% of the average tropospheric column (14.5 · 10 15 molec cm −2 ). The comparisons show little cloud cover dependence after cloud corrections for which ceilometer data were used. Hourly differences between observations and model show a Gaussian behavior with a standard deviation (σ) of 5.5 · 10 15 molec cm −2 . For daily averages of tropospheric NO 2 columns, a correlation of 0.72 was found for all observations, and 0.79 for cloud free conditions. The measured and modeled tropospheric NO 2 columns have an almost identical distribution over the wind direction. A significant difference between model and measurements was found for the average weekly cycle, which shows a much stronger decrease during the weekend for the observations; for the diurnal cycle, the observed range is about twice as large as the modeled range. The results of the comparison demonstrate that averaged over a long time period, the tropospheric NO 2 column observations are representative for a large spatial area despite the fact that they were obtained in an urban region. This makes the MAX-DOAS technique especially suitable for validation of satellite observations and air quality models in urban regions.
    Keywords Physics ; QC1-999 ; Chemistry ; QD1-999
    Subject code 333
    Language English
    Publishing date 2015-02-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  8. Article ; Online: MAX-DOAS tropospheric nitrogen dioxide column measurements compared with the Lotos-Euros air quality model

    T. Vlemmix / H. J. Eskes / A. J. M. Piters / H. Kelder / P. F. Levelt

    Atmospheric Chemistry and Physics Discussions, Vol 11, Iss 10, Pp 28895-

    2011  Volume 28944

    Abstract: A data set of ground based tropospheric NO 2 column observations from De Bilt, the Netherlands, has been compared with the regional air quality model Lotos-Euros. The size of the data set (355 days spread over 14 months, 2106 hourly averages) enables ... ...

    Abstract A data set of ground based tropospheric NO 2 column observations from De Bilt, the Netherlands, has been compared with the regional air quality model Lotos-Euros. The size of the data set (355 days spread over 14 months, 2106 hourly averages) enables statistically significant conclusions, despite a strong variability in both data sets, and allows to study the seasonal, weekly and diurnal variability and dependence on meteorological variables. The model was run on a 7×7 km grid, and based on an emission data base with the same resolution. With this resolution the model is able to resolve the major sources in the neighborhood of the measurement location. Since for the largest part the observations were performed under cloudy conditions, a retrieval study was done to assess the effect of clouds on the retrieval accuracy. It was found that the sensitivity to NO 2 in the boundary layer is almost unchanged by clouds, provided that the cloud bottom height is above the NO 2 and that a viewing elevation angle is used of 30° above the horizon. Partially cloudy conditions, even when above the NO 2 , may have a significant positive or negative impact on individual measurements, but when averaged over time do not cause a significant bias. In general a good agreement was found between modeled and measured tropospheric NO 2 columns, with an average difference of less than 1% of the average tropospheric column (14.5 · 10 15 molec cm −2 ). This holds for both the cloud covered and cloud free observations, and the comparisons show very little cloud cover dependence after the cloud corrections. Hourly differences between observations and model show a Gaussian behavior with a standard deviation σ = 5.5 · 10 15 molec cm −2 . For daily averages of tropospheric NO 2 columns, a correlation 0.72 was found for all observations, and 0.79 for cloud free conditions. The measured and modeled tropospheric NO 2 columns have an almost identical distribution over the wind directions, when averaged over 12 sectors of 30°. A significant difference between model and measurements was found for the average weekly cycle, which shows a much stronger decrease in the weekend for the observations, and for the diurnal cycle, for which the observed range is about twice as large as the modeled range. In addition the observations show a decrease with increasing temperature, whereas the model shows no dependency on the temperature for this data set which did not include summer months. The results of the comparison demonstrate that averaged over a long time period, the tropospheric NO 2 column observations are representative for a large spatial area despite the fact that they were obtained in an urban region. This makes the MAX-DOAS technique, more than in situ techniques, especially suitable for validation of satellite observations and air quality models in urban regions.
    Keywords Environmental sciences ; GE1-350 ; Geography. Anthropology. Recreation ; G ; DOAJ:Environmental Sciences ; DOAJ:Earth and Environmental Sciences ; Geophysics. Cosmic physics ; QC801-809
    Subject code 333
    Language English
    Publishing date 2011-10-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  9. Article ; Online: Intercomparison of NO x emission inventories over East Asia

    J. Ding / K. Miyazaki / R. J. van der A / B. Mijling / J.-I. Kurokawa / S. Cho / G. Janssens-Maenhout / Q. Zhang / F. Liu / P. F. Levelt

    Atmospheric Chemistry and Physics, Vol 17, Pp 10125-

    2017  Volume 10141

    Abstract: We compare nine emission inventories of nitrogen oxides including four satellite-derived NO x inventories and the following bottom-up inventories for East Asia: REAS (Regional Emission inventory in ASia), MEIC (Multi-resolution Emission Inventory for ... ...

    Abstract We compare nine emission inventories of nitrogen oxides including four satellite-derived NO x inventories and the following bottom-up inventories for East Asia: REAS (Regional Emission inventory in ASia), MEIC (Multi-resolution Emission Inventory for China), CAPSS (Clean Air Policy Support System) and EDGAR (Emissions Database for Global Atmospheric Research). Two of the satellite-derived inventories are estimated by using the DECSO (Daily Emission derived Constrained by Satellite Observations) algorithm, which is based on an extended Kalman filter applied to observations from OMI or from GOME-2. The other two are derived with the EnKF algorithm, which is based on an ensemble Kalman filter applied to observations of multiple species using either the chemical transport model CHASER and MIROC-chem. The temporal behaviour and spatial distribution of the inventories are compared on a national and regional scale. A distinction is also made between urban and rural areas. The intercomparison of all inventories shows good agreement in total NO x emissions over mainland China, especially for trends, with an average bias of about 20 % for yearly emissions. All the inventories show the typical emission reduction of 10 % during the Chinese New Year and a peak in December. Satellite-derived approaches using OMI show a summer peak due to strong emissions from soil and biomass burning in this season. Biases in NO x emissions and uncertainties in temporal variability increase quickly when the spatial scale decreases. The analyses of the differences show the importance of using observations from multiple instruments and a high spatial resolution model for the satellite-derived inventories, while for bottom-up inventories, accurate emission factors and activity information are required. The advantage of the satellite-derived approach is that the emissions are soon available after observation, while the strength of the bottom-up inventories is that they include detailed information of emissions for each source category.
    Keywords Physics ; QC1-999 ; Chemistry ; QD1-999
    Subject code 520
    Language English
    Publishing date 2017-08-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  10. Article ; Online: Simulation study of the aerosol information content in OMI spectral reflectance measurements

    B. Veihelmann / P. F. Levelt / P. Stammes / J. P. Veefkind

    Atmospheric Chemistry and Physics Discussions, Vol 7, Iss 1, Pp 1785-

    2007  Volume 1821

    Abstract: The Ozone Monitoring Instrument (OMI) is designed and used primarily to retrieve trace gases like O 3 and NO 2 from the measured Earth reflectance spectrum in the UV-visible (270–500 nm). However, also aerosols are an important science target of OMI. ... ...

    Abstract The Ozone Monitoring Instrument (OMI) is designed and used primarily to retrieve trace gases like O 3 and NO 2 from the measured Earth reflectance spectrum in the UV-visible (270–500 nm). However, also aerosols are an important science target of OMI. Therefore, a Principal Component Analysis (PCA) is performed to quantify the information content of OMI reflectance measurements on aerosols. This analysis is applied to synthetic reflectance measurements for desert dust, biomass burning aerosols, and weakly absorbing anthropogenic aerosol with a variety of aerosol optical thicknesses, aerosol layer altitudes, refractive indices and size distributions. The range of aerosol parameters considered covers the natural variability of tropospheric aerosols. This theoretical analysis is performed for a large number of scenarios with various geometries and surface albedo spectra for ocean, soil and vegetation. When the surface albedo spectrum is accurately known and clouds are absent, OMI reflectance measurements have 2 to 4 degrees of freedom that can be attributed to aerosol parameters. This information content depends on the observation geometry, the surface albedo spectrum, and on the aerosol parameters themselves. An additional wavelength band is evaluated, that comprises the O 2 -O 2 absorption band at a wavelength of 477 nm. It is found that this wavelength band adds significantly more information than any other individual band. The PCA is applied to assess the capability of the aerosol retrieval to discern various aerosol types as well as clouds.
    Keywords Environmental sciences ; GE1-350 ; Geography. Anthropology. Recreation ; G ; DOAJ:Environmental Sciences ; DOAJ:Earth and Environmental Sciences ; Geophysics. Cosmic physics ; QC801-809
    Language English
    Publishing date 2007-02-01T00:00:00Z
    Publisher Copernicus Publications
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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