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Article: Thermophysical Study of Pyridinium-Based Ionic Liquids Sharing Ions.

Reinado, Christian / Pelegrina, Adrián / Sánchez-Rubio, Miguel / Artigas, Héctor / Lafuente, Carlos

Journal of chemical and engineering data

2022  Volume 67, Issue 3, Page(s) 636–643

Abstract: The thermophysical properties of three pyridinium-based ionic liquids sharing ions were measured at several temperatures (278.15-338.15) K and at atmospheric pressure (0.1 MPa). Three ionic liquids were studied: 1-butylpyridinium bis(trifluoromethyl- ... ...

Abstract The thermophysical properties of three pyridinium-based ionic liquids sharing ions were measured at several temperatures (278.15-338.15) K and at atmospheric pressure (0.1 MPa). Three ionic liquids were studied: 1-butylpyridinium bis(trifluoromethyl-sulfonyl)imide, 1-hexylpyridinium bis(trifluoromethylsulfonyl)imide, and 1-hexylpyridinium tetrafluoroborate. The following thermophysical properties were measured: density, speed of sound, refractive index, surface tension, isobaric molar heat capacity, kinematic viscosity, and electrical conductivity. The thermophysical properties at atmospheric pressure were correlated with temperature, noting that the starting temperature for the speed of sound measurements depended on the ionic liquid. From these experimental results, some derived properties (isentropic compressibility, molar refraction, and dynamic viscosity) are calculated. These results together with those published previously for 1-butylpyridinium tetrafluoroborate are discussed.
Language English
Publishing date 2022-02-10
Publishing country United States
Document type Journal Article
ZDB-ID 1491128-0
ISSN 1520-5134 ; 0021-9568
ISSN (online) 1520-5134
ISSN 0021-9568
DOI 10.1021/acs.jced.1c00925
Database MEDical Literature Analysis and Retrieval System OnLINE

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