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  1. Article ; Online: Atom-economic access to cationic magnesium complexes.

    Brouillet, Etienne V / Brown, Scott A / Kennedy, Alan R / Rae, Annabel / Walton, Heather P / Robertson, Stuart D

    Dalton transactions (Cambridge, England : 2003)

    2023  Volume 52, Issue 37, Page(s) 13332–13338

    Abstract: Cationic alkaline-earth complexes attract interest for their enhanced Lewis acidity and reactivity compared with their neutral counterparts. Synthetic protocols to these complexes generally utilize expensive specialized reagents in reactions generating ... ...

    Abstract Cationic alkaline-earth complexes attract interest for their enhanced Lewis acidity and reactivity compared with their neutral counterparts. Synthetic protocols to these complexes generally utilize expensive specialized reagents in reactions generating multiple by-products. We have studied a simple ligand transfer approach to these complexes using (NacNac)MgR and ER
    Language English
    Publishing date 2023-09-26
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt02669h
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Sigma/pi Bonding Preferences of Solvated Alkali-Metal Cations to Ditopic Arylmethyl Anions.

    Rae, Annabel / Byrne, Keelan M / Brown, Scott A / Kennedy, Alan R / Krämer, Tobias / Mulvey, Robert E / Robertson, Stuart D

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2022  Volume 28, Issue 18, Page(s) e202104260

    Abstract: Arylmethyl anions allow alkali-metals to bind in a σ-fashion to the lateral carbanionic centre or a π-fashion to the aryl ring or in between these extremities, with the trend towards π bonding increasing on descending group 1. Here we review known alkali ...

    Abstract Arylmethyl anions allow alkali-metals to bind in a σ-fashion to the lateral carbanionic centre or a π-fashion to the aryl ring or in between these extremities, with the trend towards π bonding increasing on descending group 1. Here we review known alkali metal structures of diphenylmethane, fluorene, 2-benzylpyridine and 4-benzylpyridine. Next, we synthesise Li, Na, K monomers of these diarylmethyls using polydentate donors PMDETA or Me
    MeSH term(s) Alkalies ; Anions/chemistry ; Cations/chemistry ; Metals, Alkali/chemistry ; Models, Molecular
    Chemical Substances Alkalies ; Anions ; Cations ; Metals, Alkali
    Language English
    Publishing date 2022-03-08
    Publishing country Germany
    Document type Journal Article ; Review
    ZDB-ID 1478547-X
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.202104260
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Atom-efficient synthesis of a benchmark electrolyte for magnesium battery applications.

    Brown, Scott A / Cussen, Serena A / Kennard, Rhiannon / Marchesini, Sofia / Pryke, Jethro J / Rae, Annabel / Robertson, Stuart D / Samajdar, Rudra N / Wain, Andrew J

    Chemical communications (Cambridge, England)

    2022  Volume 58, Issue 86, Page(s) 12070–12073

    Abstract: The benchmark magnesium electrolyte, [ ... ...

    Abstract The benchmark magnesium electrolyte, [Mg
    Language English
    Publishing date 2022-10-27
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc03290b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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