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  1. Article: 3D Nanoporous FeAl-KIT-5 with a cage type pore structure: a highly efficient and stable catalyst for hydroarylation of styrene and arylacetylenes

    Varghese, Shaji / Nagarajan, Samuthira / Benzigar, Mercy R / Mano, Ajayan / ALOthman, Zeid A / Raj, George Allen Gnana / Vinu, Ajayan

    Tetrahedron letters. 2012 Mar. 21, v. 53, no. 12

    2012  

    Abstract: A novel bimetallic nanoporous FeAl-KIT-5 catalyst with a cage type porous structure and a high surface area has been prepared for the hydroarylation of styrene and arylacetylenes to afford 1,1-diarylalkanes and 1,1-diarylalkenes, respectively. The ... ...

    Abstract A novel bimetallic nanoporous FeAl-KIT-5 catalyst with a cage type porous structure and a high surface area has been prepared for the hydroarylation of styrene and arylacetylenes to afford 1,1-diarylalkanes and 1,1-diarylalkenes, respectively. The catalyst was found to be highly active, and selective, affording a high yield of substituted alkanes and alkenes. The catalyst also showed much higher activity as compared to those of other nanoporous catalysts such as AlSBA-15, AlKIT-5, and FeKIT-5, and can be reused several times without much loss of its activity.
    Keywords alkanes ; alkenes ; catalysts ; chemical reactions ; chemical structure ; styrene ; surface area
    Language English
    Dates of publication 2012-0321
    Size p. 1485-1489.
    Publishing place Elsevier Ltd
    Document type Article
    ZDB-ID 204287-3
    ISSN 1873-3581 ; 0040-4039
    ISSN (online) 1873-3581
    ISSN 0040-4039
    DOI 10.1016/j.tetlet.2012.01.040
    Database NAL-Catalogue (AGRICOLA)

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  2. Article: Mesoporous and hexagonally ordered CuAl-SBA-15-catalyzed tandem C–C and C–O bond formation between phenols and allylic alcohols

    Varghese, Shaji / Anand, Chokkalinkam / Dhawale, Dattatray / Mano, Ajayan / Balasubramanian, Veerappan V / Raj, George Allen Gnana / Nagarajan, Samuthira / Wahab, Mohammad A / Vinu, Ajayan

    Tetrahedron letters. 2012 Oct. 17, v. 53, no. 42

    2012  

    Abstract: A novel mesoporous catalyst, CuAl-SBA-15, with a hexagonally ordered porous structure prepared via a soft-templating approach in a highly acidic medium is used for tandem C–C and C–O bond formation between phenols and allylic alcohols to afford a variety ...

    Abstract A novel mesoporous catalyst, CuAl-SBA-15, with a hexagonally ordered porous structure prepared via a soft-templating approach in a highly acidic medium is used for tandem C–C and C–O bond formation between phenols and allylic alcohols to afford a variety of dihydrobenzopyrans in good yields. The catalyst is also found to be highly active for the synthesis of vitamin E and can be recycled several times without significant loss of its activity.
    Keywords catalysts ; chemical reactions ; chemical structure ; phenols ; vitamin E
    Language English
    Dates of publication 2012-1017
    Size p. 5656-5659.
    Publishing place Elsevier Ltd
    Document type Article
    ZDB-ID 204287-3
    ISSN 1873-3581 ; 0040-4039
    ISSN (online) 1873-3581
    ISSN 0040-4039
    DOI 10.1016/j.tetlet.2012.08.043
    Database NAL-Catalogue (AGRICOLA)

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