Article ; Online: Charge regulation in redox active monolayers embedded in proton exchanger surfaces.
Physical chemistry chemical physics : PCCP
2012 Volume 14, Issue 28, Page(s) 9988–9995
Abstract: Experimental evidence of the variation in redox potential of osmium pyridine complexes tethered to a Au surface by thiol or diazonium chemistry at different ionic concentration and electrolyte pH is described. The interplay between the charged redox and ... ...
Abstract | Experimental evidence of the variation in redox potential of osmium pyridine complexes tethered to a Au surface by thiol or diazonium chemistry at different ionic concentration and electrolyte pH is described. The interplay between the charged redox and acid groups is described by a charge regulation model based on PM-IRRAS spectroscopic evidence on the different degrees of surface protonation. |
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Language | English |
Publishing date | 2012-07-28 |
Publishing country | England |
Document type | Journal Article |
ZDB-ID | 1476244-4 |
ISSN | 1463-9084 ; 1463-9076 |
ISSN (online) | 1463-9084 |
ISSN | 1463-9076 |
DOI | 10.1039/c2cp40695k |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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