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Article: Stereoselective synthesis of hernandulcin, peroxylippidulcine A, lippidulcines A, B and C and taste evaluation.

Rigamonti, Marco Giulio / Gatti, Francesco Gilberto

2015 Volume 11, Page(s) 2117–2124

Abstract: The first stereoselective synthesis of lippidulcines A, B and C has been accomplished starting from (+)-hernandulcin, which has been prepared on a multigram scale. The previously assigned absolute configurations have been confirmed. The key steps of this ...

Abstract	The first stereoselective synthesis of lippidulcines A, B and C has been accomplished starting from (+)-hernandulcin, which has been prepared on a multigram scale. The previously assigned absolute configurations have been confirmed. The key steps of this synthesis are based on a modified version of the Kornblum-DeLaMare rearrangement, and on a highly regioselective and stereoselective ketone reduction with the MeCBS reagent. The taste evaluations indicate that none of these sesquiterpenes are sweet, instead the lippidulcine A is a cooling agent with a mint after taste.
Language	English
Publishing date	2015-11-05
Publishing country	Germany
Document type	Journal Article
ZDB-ID	2192461-2
ISSN	1860-5397
ISSN	1860-5397
DOI	10.3762/bjoc.11.228
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Article: Ultrasonic Intensification To Produce Diester Biolubricants

Patience, Nicolas A / Boffito, Daria C / Galli, Federico / Rigamonti, Marco G / Schieppati, Dalma

Industrial & engineering chemistry process design and development. 2019 Apr. 11, v. 58, no. 19

2019

Abstract: Biolubricants synthesized from vegetable oils with oleic acid and 1,3-propanediol possess better cold flow properties and have a smaller environmental footprint than mineral-based lubricants. However, their synthesis is lengthy (>6 h) and requires ... ...

Abstract	Biolubricants synthesized from vegetable oils with oleic acid and 1,3-propanediol possess better cold flow properties and have a smaller environmental footprint than mineral-based lubricants. However, their synthesis is lengthy (>6 h) and requires temperatures above 120 °C. We applied ultrasound (US) to synthesize long-chain diesters (biolubricants): an ultrasonic horn delivered rated powers of 500 and 750 W at a frequency of 20 kHz to a solution of oleic acid and 1,3-propanediol. Amberlyst15-H esterified the acid to the diester biolubricant. US horns with powers of 750 and 500 W increased the reaction rate by factors of 2 and 1.2–1.5, respectively. A temperature of 100 °C is necessary to convert oleic acid to >50%. A partial factorial experimental design confirmed that temperature, US power, and initial molar ratio of reactants affect reaction rate and oleic acid conversion (p-value of <0.05). The 500 W horn is 17% less expensive than the 750 W horn.
Keywords	biolubricants ; ecological footprint ; esterification ; experimental design ; fluid mechanics ; oleic acid ; temperature ; ultrasonics ; vegetable oil
Language	English
Dates of publication	2019-0411
Size	p. 7957-7963.
Publishing place	American Chemical Society
Document type	Article
ZDB-ID	1484436-9
ISSN	1520-5045 ; 0888-5885
ISSN (online)	1520-5045
ISSN	0888-5885
DOI	10.1021/acs.iecr.9b00717
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Article ; Online: Influence of frequency and amplitude on the mucus viscoelasticity of the novel mechano-acoustic Frequencer™.

Schieppati, Dalma / Germon, Rémi / Galli, Federico / Rigamonti, Marco Giulio / Stucchi, Marta / Boffito, Daria Camilla

Respiratory medicine

2019 Volume 153, Page(s) 52–59

Abstract: Background: Cystic fibrosis affects 1/3200 Caucasians. This genetic disease disturbs the ion and water homeostasis across epithelia, thus rendering mucus more viscous and harder to expel. Conventional treatments rely on the clapping method coupled with ... ...

Abstract	Background: Cystic fibrosis affects 1/3200 Caucasians. This genetic disease disturbs the ion and water homeostasis across epithelia, thus rendering mucus more viscous and harder to expel. Conventional treatments rely on the clapping method coupled with postural drainage. Despite the effectiveness of these procedures, they are invasive and enervating. Methods: Here we study a new mechano-acoustic treatment device to help patients expectorate excess mucus, the Frequencer™. We test both normal and pathological synthetic mucin solutions (1 % and 4 % by weight) in vitro. We varied the frequency applied (from 20 Hz to 60 Hz) as well as the amplitude (from 50 % to 100 % intensity). Moreover, we assessed the effect of NaCl on mucus rehydration. Results: A frequency of 40 Hz coupled with a 0.5 gL Conclusions: Mechanical solicitation is fundamental to help patients affected by cystic fibrosis expectorate mucus. With an operating frequency of 20 Hz to 65 Hz, the Frequencer™ provides a gentler therapy than traditional methods (conventional chest physiotherapy). The Frequencer™ proved to be effective in the homogenization of synthetic mucin solutions in vitro in 20 min and elicited improved effectiveness in a mucin-rich environment.
MeSH term(s)	Acoustics/instrumentation ; Animals ; Cystic Fibrosis/epidemiology ; Cystic Fibrosis/physiopathology ; Cystic Fibrosis/therapy ; Drainage, Postural/instrumentation ; Humans ; Mechanical Phenomena ; Mucus/chemistry ; Mucus/drug effects ; Mucus/physiology ; Physical Therapy Modalities/standards ; Physical Therapy Modalities/statistics & numerical data ; Radio Waves/adverse effects ; Saline Solution/adverse effects ; Saline Solution/therapeutic use ; Swine ; Viscoelastic Substances/chemistry
Chemical Substances	Saline Solution ; Viscoelastic Substances
Language	English
Publishing date	2019-05-27
Publishing country	England
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	1003348-8
ISSN	1532-3064 ; 0954-6111
ISSN (online)	1532-3064
ISSN	0954-6111
DOI	10.1016/j.rmed.2019.04.011
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Article ; Online: Ultrasound assisted wet media milling synthesis of nanofiber-cage LiFePO

Li, He / Cabañas-Gac, Fernanda / Hadidi, Lida / Bilodeau-Calame, Michel / Abid, Ameni / Mameri, Kahina / Rigamonti, Marco Giulio / Rousselot, Steeve / Dollé, Mickaël / Patience, Gregory S

Ultrasonics sonochemistry

2020 Volume 68, Page(s) 105177

Abstract: To meet the objectives of the Intergovernmental Panel on Climate Change nations are adopting policies to encourage consumers to purchase electric vehicles. Electrification of the automobile industry reduces greenhouse gases but active metals for the ... ...

Abstract	To meet the objectives of the Intergovernmental Panel on Climate Change nations are adopting policies to encourage consumers to purchase electric vehicles. Electrification of the automobile industry reduces greenhouse gases but active metals for the cathode-LiCoO
Language	English
Publishing date	2020-05-27
Publishing country	Netherlands
Document type	Journal Article
ZDB-ID	1208333-1
ISSN	1873-2828 ; 1350-4177
ISSN (online)	1873-2828
ISSN	1350-4177
DOI	10.1016/j.ultsonch.2020.105177
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Article ; Online: The reversed Goldstein technique to correct a hypoplastic Cupid's bow following bilateral cleft lip repair.

Francesconi, Giuseppe / Rigamonti, Marco

Plastic and reconstructive surgery

2005 Volume 116, Issue 5, Page(s) 90e–94e; discussion 95e–96e

MeSH term(s)	Adolescent ; Cleft Lip/surgery ; Humans ; Lip/pathology ; Lip/surgery ; Male ; Oral Surgical Procedures/methods
Language	English
Publishing date	2005-10
Publishing country	United States
Document type	Case Reports ; Journal Article
ZDB-ID	208012-6
ISSN	1529-4242 ; 0032-1052 ; 0096-8501
ISSN (online)	1529-4242
ISSN	0032-1052 ; 0096-8501
DOI	10.1097/01.prs.0000182356.13944.01
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Article: Localization of Ras signaling complex in budding yeast

Belotti, Fiorella / Tisi, Renata / Paiardi, Chiara / Rigamonti, Marco / Groppi, Silvia / Martegani, Enzo

Biochimica et biophysica acta. Molecular cell research. 2012 July, v. 1823, no. 7

2012

Abstract: In Saccharomyces cerevisiae, cAMP/pKA pathway plays a major role in metabolism, stress resistance and proliferation control. cAMP is produced by adenylate cyclase, which is activated both by Gpr1/Gpa2 system and Ras proteins, regulated by Cdc25/Sdc25 ... ...

Abstract	In Saccharomyces cerevisiae, cAMP/pKA pathway plays a major role in metabolism, stress resistance and proliferation control. cAMP is produced by adenylate cyclase, which is activated both by Gpr1/Gpa2 system and Ras proteins, regulated by Cdc25/Sdc25 guanine exchange factors and Ira GTPase activator proteins. Recently, both Ras2 and Cdc25 RasGEF were reported to localize not only in plasma membrane but also in internal membranes. Here, the subcellular localization of Ras signaling complex proteins was investigated both by fluorescent tagging and by biochemical cell membrane fractionation on sucrose gradients. Although a consistent minor fraction of Ras signaling complex components was found in plasma membrane during exponential growth on glucose, Cdc25 appears to localize mainly on ER membranes, while Ira2 and Cyr1 are also significantly present on mitochondria. Moreover, PKA Tpk1 catalytic subunit overexpression induces Ira2 protein to move from mitochondria to ER membranes. These data confirm the hypothesis that different branches of Ras signaling pathways could involve different subcellular compartments, and that relocalization of Ras signaling complex components is subject to PKA control.
Keywords	Saccharomyces cerevisiae ; adenylate cyclase ; cAMP-dependent protein kinase ; fluorescence ; fractionation ; glucose ; guanine ; guanosinetriphosphatase ; metabolism ; mitochondria ; plasma membrane ; protein subunits ; proteins ; signal transduction ; stress tolerance ; sucrose ; yeasts
Language	English
Dates of publication	2012-07
Size	p. 1208-1216.
Publishing place	Elsevier B.V.
Document type	Article
ZDB-ID	283444-3
ISSN	0167-4889
ISSN	0167-4889
DOI	10.1016/j.bbamcr.2012.04.016
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Article: Localization of Ras signaling complex in budding yeast.

Belotti, Fiorella / Tisi, Renata / Paiardi, Chiara / Rigamonti, Marco / Groppi, Silvia / Martegani, Enzo

Biochimica et biophysica acta

2012 Volume 1823, Issue 7, Page(s) 1208–1216

Abstract	In Saccharomyces cerevisiae, cAMP/pKA pathway plays a major role in metabolism, stress resistance and proliferation control. cAMP is produced by adenylate cyclase, which is activated both by Gpr1/Gpa2 system and Ras proteins, regulated by Cdc25/Sdc25 guanine exchange factors and Ira GTPase activator proteins. Recently, both Ras2 and Cdc25 RasGEF were reported to localize not only in plasma membrane but also in internal membranes. Here, the subcellular localization of Ras signaling complex proteins was investigated both by fluorescent tagging and by biochemical cell membrane fractionation on sucrose gradients. Although a consistent minor fraction of Ras signaling complex components was found in plasma membrane during exponential growth on glucose, Cdc25 appears to localize mainly on ER membranes, while Ira2 and Cyr1 are also significantly present on mitochondria. Moreover, PKA Tpk1 catalytic subunit overexpression induces Ira2 protein to move from mitochondria to ER membranes. These data confirm the hypothesis that different branches of Ras signaling pathways could involve different subcellular compartments, and that relocalization of Ras signaling complex components is subject to PKA control.
MeSH term(s)	Catalytic Domain ; Cyclic AMP-Dependent Protein Kinases/metabolism ; Endoplasmic Reticulum/metabolism ; Guanosine Diphosphate/metabolism ; Guanosine Triphosphate/metabolism ; Mitochondrial Membranes/metabolism ; Multiprotein Complexes/metabolism ; Protein Transport ; Saccharomyces cerevisiae/cytology ; Saccharomyces cerevisiae/metabolism ; Saccharomyces cerevisiae Proteins/metabolism ; Signal Transduction ; ras Proteins/metabolism
Chemical Substances	Multiprotein Complexes ; Saccharomyces cerevisiae Proteins ; Guanosine Diphosphate (146-91-8) ; Guanosine Triphosphate (86-01-1) ; Cyclic AMP-Dependent Protein Kinases (EC 2.7.11.11) ; ras Proteins (EC 3.6.5.2)
Language	English
Publishing date	2012-07
Publishing country	Netherlands
Document type	Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	60-7
ISSN	1879-2596 ; 1879-260X ; 1872-8006 ; 1879-2642 ; 1879-2618 ; 1879-2650 ; 0006-3002 ; 0005-2728 ; 0005-2736 ; 0304-4165 ; 0167-4838 ; 1388-1981 ; 0167-4889 ; 0167-4781 ; 0304-419X ; 1570-9639 ; 0925-4439 ; 1874-9399
ISSN (online)	1879-2596 ; 1879-260X ; 1872-8006 ; 1879-2642 ; 1879-2618 ; 1879-2650
ISSN	0006-3002 ; 0005-2728 ; 0005-2736 ; 0304-4165 ; 0167-4838 ; 1388-1981 ; 0167-4889 ; 0167-4781 ; 0304-419X ; 1570-9639 ; 0925-4439 ; 1874-9399
DOI	10.1016/j.bbamcr.2012.04.016
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Article ; Online: The critical view of safety during laparoscopic cholecystectomy: Strasberg Yes or No? An Italian Multicentre study.

Sgaramella, Lucia Ilaria / Gurrado, Angela / Pasculli, Alessandro / de Angelis, Nicola / Memeo, Riccardo / Prete, Francesco Paolo / Berti, Stefano / Ceccarelli, Graziano / Rigamonti, Marco / Badessi, Francesco Giuseppe Aldo / Solari, Nicola / Milone, Marco / Catena, Fausto / Scabini, Stefano / Vittore, Francesco / Perrone, Gennaro / de Werra, Carlo / Cafiero, Ferdinando / Testini, Mario

Surgical endoscopy

2020 Volume 35, Issue 7, Page(s) 3698–3708

Abstract: Background: Laparoscopic cholecystectomy is considered the gold standard for the treatment of gallbladder lithiasis; nevertheless, the incidence of bile duct injuries (BDI) is still high (0.3-0.8%) compared to open cholecystectomy (0.2%). In 1995, ... ...

Abstract	Background: Laparoscopic cholecystectomy is considered the gold standard for the treatment of gallbladder lithiasis; nevertheless, the incidence of bile duct injuries (BDI) is still high (0.3-0.8%) compared to open cholecystectomy (0.2%). In 1995, Strasberg introduced the "Critical View of Safety" (CVS) to reduce the risk of BDI. Despite its widespread use, the scientific evidence supporting this technique to prevent BDI is controversial. Methods: Between March 2017 and March 2019, the data of patients submitted to laparoscopic cholecystectomy in 30 Italian surgical departments were collected on a national database. A survey was submitted to all members of Italian Digestive Pathology Society to obtain data on the preoperative workup, the surgical and postoperative management of patients and to judge, at the end of the procedure, if the isolation of the elements was performed according to the CVS. In the case of a declared critical view, iconographic documentation was obtained, finally reviewed by an external auditor. Results: Data from 604 patients were analysed. The study population was divided into two groups according to the evidence (Group A; n = 11) or absence (Group B; N = 593) of BDI and perioperative bleeding. The non-use of CVS was found in 54.6% of procedures in the Group A, and 25.8% in the Group B, and evaluating the operator-related variables the execution of CVS was associated with a significantly lower incidence of BDI and intraoperative bleeding. Conclusions: The CVS confirmed to be the safest technique to recognize the elements of the Calot triangle and, if correctly performed, it significantly impacted on preventing intraoperative complications. Additional educational programs on the correct application of CVS in clinical practice would be desirable to avoid extreme conditions that may require additional procedures.
MeSH term(s)	Bile Duct Diseases ; Bile Ducts ; Cholecystectomy, Laparoscopic/adverse effects ; Gallbladder ; Humans ; Intraoperative Complications/epidemiology ; Intraoperative Complications/prevention & control ; Italy/epidemiology
Language	English
Publishing date	2020-08-11
Publishing country	Germany
Document type	Journal Article ; Multicenter Study ; Research Support, Non-U.S. Gov't
ZDB-ID	639039-0
ISSN	1432-2218 ; 0930-2794
ISSN (online)	1432-2218
ISSN	0930-2794
DOI	10.1007/s00464-020-07852-6
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Article: Testing for localized stimulus enhancement and object movement reenactment in pig-tailed macaques (Macaca nemestrina) and young children (Homo sapiens).

Rigamonti, Marco M / Custance, Deborah M / Previde, Emanuela Prato / Spiezio, Caterina

Journal of comparative psychology (Washington, D.C. : 1983)

2005 Volume 119, Issue 3, Page(s) 257–272

Abstract: Four puzzle boxes were used to investigate localized stimulus enhancement and object movement reenactment (OMR) in 13 pig-tailed macaques (Macaca nemestrina) and 30 human infants (Homo sapiens). Participants received contrasting demonstrations on each ... ...

Abstract	Four puzzle boxes were used to investigate localized stimulus enhancement and object movement reenactment (OMR) in 13 pig-tailed macaques (Macaca nemestrina) and 30 human infants (Homo sapiens). Participants received contrasting demonstrations on each box. A circular lid was gripped by its rim or handle and swiveled to the left or right. A flap door was pushed or flipped. A sliding lid was pushed to the left or right. A pin bolt was demonstrated being pushed down, or the participants were left to solve the puzzle for themselves. Despite the fact that the monkeys watched the demonstrations about 60% of the time, only a weak OMR effect was found on the sliding lid. In contrast, the children watched significantly more, and there was clear evidence of socially mediated learning on all of the boxes.
MeSH term(s)	Age Factors ; Animals ; Attention ; Child, Preschool ; Cohort Studies ; Female ; Humans ; Imitative Behavior ; Infant ; Macaca nemestrina ; Male ; Motion Perception ; Orientation ; Problem Solving ; Psychology, Child ; Psychomotor Performance ; Species Specificity
Language	English
Publishing date	2005-08
Publishing country	United States
Document type	Comparative Study ; Journal Article ; Research Support, Non-U.S. Gov't
ZDB-ID	3130-6
ISSN	1939-2087 ; 0735-7036 ; 0093-4127
ISSN (online)	1939-2087
ISSN	0735-7036 ; 0093-4127
DOI	10.1037/0735-7036.119.3.257
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Article ; Online: Correction: Minimally invasive vs. open segmental resection of the splenic flexure for cancer: a nationwide study of the Italian Society of Surgical Oncology-Colorectal Cancer Network (SICO-CNN).

Degiuli, Maurizio / Ortenzi, Monica / Tomatis, Mariano / Puca, Lucia / Cianflocca, Desiree / Rega, Daniela / Maroli, Annalisa / Elmore, Ugo / Pecchini, Francesca / Milone, Marco / La Mendola, Roberta / Soligo, Erica / Deidda, Simona / Spoletini, Domenico / Cassini, Diletta / Aprile, Alessandra / Mineccia, Michela / Nikaj, Herald / Marchegiani, Francesco /

Maiello, Fabio / Bombardini, Cristina / Zuolo, Michele / Carlucci, Michele / Ferraro, Luca / Falato, Armando / Biondi, Alberto / Persiani, Roberto / Marsanich, Patrizia / Fusario, Daniele / Solaini, Leonardo / Pollesel, Sara / Rizzo, Gianluca / Coco, Claudio / Di Leo, Alberto / Cavaliere, Davide / Roviello, Franco / Muratore, Andrea / D'Ugo, Domenico / Bianco, Francesco / Bianchi, Paolo Pietro / De Nardi, Paola / Rigamonti, Marco / Anania, Gabriele / Belluco, Claudio / Polastri, Roberto / Pucciarelli, Salvatore / Gentilli, Sergio / Ferrero, Alessandro / Scabini, Stefano / Baldazzi, Gianandrea / Carlini, Massimo / Restivo, Angelo / Testa, Silvio / Parini, Dario / De Palma, Giovanni Domenico / Piccoli, Micaela / Rosati, Riccardo / Spinelli, Antonino / Delrio, Paolo / Borghi, Felice / Guerrieri, Marco / Reddavid, Rossella

Surgical endoscopy

2023 Volume 37, Issue 6, Page(s) 5008–5009

Language	English
Publishing date	2023-05-09
Publishing country	Germany
Document type	Published Erratum
ZDB-ID	639039-0
ISSN	1432-2218 ; 0930-2794
ISSN (online)	1432-2218
ISSN	0930-2794
DOI	10.1007/s00464-023-10102-0
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