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  1. Article ; Online: Kiwi peel waste as a recyclable adsorbent to remove textile dyes from water: Direct Blue 78 removal and recovery.

    Gubitosa, Jennifer / Rizzi, Vito / Fini, Paola / Nuzzo, Sergio / Cosma, Pinalysa

    Physical chemistry chemical physics : PCCP

    2024  Volume 26, Issue 13, Page(s) 9891–9905

    Abstract: According to circular bioeconomy principles, the use of kiwi peels to remove Direct Blue 78 (DB) from water is investigated during this work, proposing food waste as a recyclable adsorbent substrate. Direct Blue 78 (DB) was adopted as a model pollutant, ... ...

    Abstract According to circular bioeconomy principles, the use of kiwi peels to remove Direct Blue 78 (DB) from water is investigated during this work, proposing food waste as a recyclable adsorbent substrate. Direct Blue 78 (DB) was adopted as a model pollutant, employing its visible spectrum to monitor its adsorption. The adsorption process was thus fully characterized, investigating the roles of ionic strength, pH values, adsorbent/pollutant amounts, and temperature. The thermodynamics, kinetics, and adsorption isotherms were also studied. To extend the kiwi peels' lifetime, quite complete desorption was obtained by adopting hot water as a safe and eco-friendly strategy. Despite the relatively low kiwi peels' maximum adsorption capacity (6 mg g
    Language English
    Publishing date 2024-03-27
    Publishing country England
    Document type Journal Article
    ZDB-ID 1476244-4
    ISSN 1463-9084 ; 1463-9076
    ISSN (online) 1463-9084
    ISSN 1463-9076
    DOI 10.1039/d4cp00174e
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  2. Article ; Online: The Adsorption Efficiency of Regenerable Chitosan-TiO

    Gubitosa, Jennifer / Rizzi, Vito / Fini, Paola / Nuzzo, Sergio / Cosma, Pinalysa

    International journal of molecular sciences

    2023  Volume 24, Issue 10

    Abstract: In this work, the great performance of chitosan-based films blended with ... ...

    Abstract In this work, the great performance of chitosan-based films blended with TiO
    MeSH term(s) 2,4-Dinitrophenol ; Water ; Chitosan/chemistry ; Adsorption ; Thermodynamics ; Environmental Pollutants ; Kinetics ; Water Pollutants, Chemical/chemistry ; Hydrogen-Ion Concentration
    Chemical Substances titanium dioxide (15FIX9V2JP) ; 2,4-Dinitrophenol (Q13SKS21MN) ; Water (059QF0KO0R) ; Chitosan (9012-76-4) ; Environmental Pollutants ; Water Pollutants, Chemical
    Language English
    Publishing date 2023-05-10
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2019364-6
    ISSN 1422-0067 ; 1422-0067 ; 1661-6596
    ISSN (online) 1422-0067
    ISSN 1422-0067 ; 1661-6596
    DOI 10.3390/ijms24108552
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  3. Article ; Online: Chitosan/snail slime films as multifunctional platforms for potential biomedical and cosmetic applications: physical and chemical characterization.

    Gubitosa, Jennifer / Rizzi, Vito / Fini, Paola / Fanelli, Fiorenza / Sibillano, Teresa / Corriero, Nicola / Cosma, Pinalysa

    Journal of materials chemistry. B

    2023  Volume 11, Issue 12, Page(s) 2638–2649

    Abstract: Due to the pollution problem, the use of more sustainable materials with a reduced environmental impact, spanning across biocompatible and biodegradable polymers, is growing worldwide in many different fields, particularly when referring to applications ... ...

    Abstract Due to the pollution problem, the use of more sustainable materials with a reduced environmental impact, spanning across biocompatible and biodegradable polymers, is growing worldwide in many different fields, particularly when referring to applications in Life Sciences. Accordingly, with the aim of developing multifunctional materials for potential cosmetic/biomedical purposes, this work reports the physical and chemical characterization of chitosan-based films blended with snail slime, exhibiting antioxidant and sunscreen features. A suitable formulation for preparing free-standing chitosan platforms, mixing low molecular weight chitosan, lactic acid, glycerol, and snail slime into an appropriate ratio, is thus described. The results obtained by morphological analysis and ATR-FTIR spectroscopy, XRD, swelling analysis (also when varying pH, ionic strength, and temperature), and WVTR measurements evidence a uniform distribution of snail slime inside the chitosan network, forming more compacted structures. At first, the UV-Vis analysis is used to investigate the theoretical Sun Protection Factor, finding that these innovative platforms can be used for preventing sunburn. Then, the antioxidant features are investigated using the ABTS assay, displaying a snail slime-mediated and dose-dependent boosted activity.
    MeSH term(s) Chitosan/chemistry ; Antioxidants ; Polymers ; Sunscreening Agents ; Spectroscopy, Fourier Transform Infrared
    Chemical Substances Chitosan (9012-76-4) ; Antioxidants ; Polymers ; Sunscreening Agents
    Language English
    Publishing date 2023-03-22
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2702241-9
    ISSN 2050-7518 ; 2050-750X
    ISSN (online) 2050-7518
    ISSN 2050-750X
    DOI 10.1039/d2tb02119f
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  4. Article: From agricultural wastes to a resource: Kiwi Peels, as long-lasting, recyclable adsorbent, to remove emerging pollutants from water. The case of Ciprofloxacin removal

    Gubitosa, Jennifer / Rizzi, Vito / Cignolo, Domenico / Fini, Paola / Fanelli, Fiorenza / Cosma, Pinalysa

    Sustainable chemistry and pharmacy. 2022 Oct., v. 29

    2022  

    Abstract: This work accounts for the first example of dry Kiwi Peels to remove emerging pollutants from water. Both the inner and outer sides of Kiwi Peels were characterized by using in synergy FTIR-ATR, TG, and SEM analyses before and after its use and re-use, ... ...

    Abstract This work accounts for the first example of dry Kiwi Peels to remove emerging pollutants from water. Both the inner and outer sides of Kiwi Peels were characterized by using in synergy FTIR-ATR, TG, and SEM analyses before and after its use and re-use, proposing it as long-lasting, recyclable adsorbent material. Among the tested 14 emerging pollutants, 6 of them were successfully removed by Kiwi Peels, also if present in mixtures, calculating the Kiwi Peels maximum adsorption capacities, occurring in the range of 1–4 mg/g. To infer information about the behavior of Kiwi Peels during water treatments, Ciprofloxacin, a well-known and largely used antibiotic, was selected as a dangerous model contaminant. The roles of ionic strength, pH values, adsorbent/pollutant amounts, and temperature values during the adsorption process were assessed, giving physical and chemical information about the whole adsorption process. The thermodynamics, the adsorption isotherms, and kinetics were studied. The Freundlich model, with a good correlation, well described the obtained results, indicating the heterogenous character of the Ciprofloxacin adsorption with the formation of a multilayer of pollutant molecules onto the adsorbent surface. If, on the one hand, in the range of temperatures 283–303 K, the Ciprofloxacin adsorption was favored by increasing the temperature, on the other hand, the adsorption was hindered by further incrementing of temperature due to the pollutant desorption. Until the occurrence of desorption, the process occurred with ΔH° and ΔS° > 0 with a ΔG° < 0. Both the pseudo-first and pseudo-second-order kinetic equations seemed to describe the process with the applicability of the Weber-Morris model. The results suggested the main presence of electrostatic interaction between the pollutant and adsorbent by changing the pH values and ionic strength of Ciprofloxacin solutions. As a whole, from the obtained results, the best condition to remove Ciprofloxacin is neutral pH in the absence of salt at 303 K. The Kiwi Peels and Ciprofloxacin recycling was also investigated by performing desorption experiments using 0.1 M MgCl₂ solution, increasing the Kiwi Peels maximum adsorption capacity at least from 4 to 40 mg/g for Ciprofloxacin. At least 10 cycles of adsorption/desorption were performed, desorbing almost 75% of adsorbed pollutants during each run. Preliminary information about the possibility of inducing the solid-state pollutant photodegradation by using Advanced Oxidation Processes was also explored, giving a possible alternative for pollutant desorption and adsorbent recycling.
    Keywords adsorbents ; adsorption ; antibiotics ; ciprofloxacin ; desorption ; electrostatic interactions ; green chemistry ; ionic strength ; models ; oxidation ; pH ; photolysis ; pollutants ; sorption isotherms ; temperature ; thermodynamics
    Language English
    Dates of publication 2022-10
    Publishing place Elsevier B.V.
    Document type Article
    ISSN 2352-5541
    DOI 10.1016/j.scp.2022.100749
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  5. Article: Snail slime-based gold nanoparticles: An interesting potential ingredient in cosmetics as an antioxidant, sunscreen, and tyrosinase inhibitor

    Rizzi, Vito / Gubitosa, Jennifer / Fini, Paola / Nuzzo, Sergio / Agostiano, Angela / Cosma, Pinalysa

    Journal of photochemistry and photobiology. 2021 Nov., v. 224

    2021  

    Abstract: Due to their properties, snail slime-based products have been appreciated and used worldwide. So, as an alternative and innovative use of snail slime, it was adopted to induce gold nanoparticles' formation, conferring them interesting properties. By a ... ...

    Abstract Due to their properties, snail slime-based products have been appreciated and used worldwide. So, as an alternative and innovative use of snail slime, it was adopted to induce gold nanoparticles' formation, conferring them interesting properties. By a simple, one-pot, and eco-friendly approach, 14 ± 6 nm wide hybrid gold nanoparticles, having an inorganic metallic core decorated by the slime's main components, were obtained. Among their several properties, their antioxidant and tyrosinase inhibition activity were investigated through the DPPH and ABTS and the tyrosinase assays, respectively. After assessing their non-cytotoxicity in our previous work, the results revealed positive responses, enabling their use as a potential novel multifunctional ingredient in cosmetics. Interestingly, the gold nanoparticle photostability, investigated by means of a solar simulator lamp, suggests using them in commercial cosmetic sunscreen products as a potential alternative to the commonly used inorganic sunscreen ingredients. The theoretical Sun Protection Factor was evaluated, obtaining values in the range 0–12. The proposed environmentally friendly and cost-effective protocol for nanoparticle synthesis, following the principles of Green Chemistry, opens a hugely attractive space toward the study of snail slime-based gold nanoparticles as a potential multipurpose platform in cosmetics.
    Keywords antioxidants ; cost effectiveness ; green chemistry ; ingredients ; nanogold ; photobiology ; photochemistry ; photostability ; snails ; sunscreens
    Language English
    Dates of publication 2021-11
    Publishing place Elsevier B.V.
    Document type Article
    ZDB-ID 623022-2
    ISSN 1873-2682 ; 1011-1344
    ISSN (online) 1873-2682
    ISSN 1011-1344
    DOI 10.1016/j.jphotobiol.2021.112309
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    Zs.A 2347: Show issues Location:
    Je nach Verfügbarkeit (siehe Angabe bei Bestand)
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    Jg. 1995 - 2021: Lesesall (2.OG)
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  6. Article ; Online: Snail slime-based gold nanoparticles: An interesting potential ingredient in cosmetics as an antioxidant, sunscreen, and tyrosinase inhibitor.

    Rizzi, Vito / Gubitosa, Jennifer / Fini, Paola / Nuzzo, Sergio / Agostiano, Angela / Cosma, Pinalysa

    Journal of photochemistry and photobiology. B, Biology

    2021  Volume 224, Page(s) 112309

    Abstract: Due to their properties, snail slime-based products have been appreciated and used worldwide. So, as an alternative and innovative use of snail slime, it was adopted to induce gold nanoparticles' formation, conferring them interesting properties. By a ... ...

    Abstract Due to their properties, snail slime-based products have been appreciated and used worldwide. So, as an alternative and innovative use of snail slime, it was adopted to induce gold nanoparticles' formation, conferring them interesting properties. By a simple, one-pot, and eco-friendly approach, 14 ± 6 nm wide hybrid gold nanoparticles, having an inorganic metallic core decorated by the slime's main components, were obtained. Among their several properties, their antioxidant and tyrosinase inhibition activity were investigated through the DPPH and ABTS and the tyrosinase assays, respectively. After assessing their non-cytotoxicity in our previous work, the results revealed positive responses, enabling their use as a potential novel multifunctional ingredient in cosmetics. Interestingly, the gold nanoparticle photostability, investigated by means of a solar simulator lamp, suggests using them in commercial cosmetic sunscreen products as a potential alternative to the commonly used inorganic sunscreen ingredients. The theoretical Sun Protection Factor was evaluated, obtaining values in the range 0-12. The proposed environmentally friendly and cost-effective protocol for nanoparticle synthesis, following the principles of Green Chemistry, opens a hugely attractive space toward the study of snail slime-based gold nanoparticles as a potential multipurpose platform in cosmetics.
    MeSH term(s) Animals ; Antioxidants/pharmacology ; Cosmetics/chemistry ; Enzyme Inhibitors/pharmacology ; Gold/chemistry ; Metal Nanoparticles/chemistry ; Monophenol Monooxygenase/antagonists & inhibitors ; Mucus ; Snails ; Sunscreening Agents/pharmacology
    Chemical Substances Antioxidants ; Cosmetics ; Enzyme Inhibitors ; Sunscreening Agents ; Gold (7440-57-5) ; Monophenol Monooxygenase (EC 1.14.18.1)
    Language English
    Publishing date 2021-09-21
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 623022-2
    ISSN 1873-2682 ; 1011-1344
    ISSN (online) 1873-2682
    ISSN 1011-1344
    DOI 10.1016/j.jphotobiol.2021.112309
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    In stock of ZB MED Cologne/Königswinter

    Zs.A 2347: Show issues Location:
    Je nach Verfügbarkeit (siehe Angabe bei Bestand)
    bis Jg. 1994: Bestellungen von Artikeln über das Online-Bestellformular
    Jg. 1995 - 2021: Lesesall (2.OG)
    ab Jg. 2022: Lesesaal (EG)

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  7. Article: Amino-grafted mesoporous MCM-41 and SBA-15 recyclable adsorbents: Desert-rose-petals-like SBA-15 type as the most efficient to remove azo textile dyes and their mixture from water

    Rizzi, Vito / Gubitosa, Jennifer / Fini, Paola / Nuzzo, Sergio / Cosma, Pinalysa

    Sustainable materials and technologies. 2020 Dec., v. 26

    2020  

    Abstract: Amino-grafted Mobil Composition of Matter N. 41 (MCM-41/NH₂) and Santa Barbara Amorphous (SBA-15/NH₂) type mesoporous adsorbents were successfully used and compared in this work to remove azo dyes (and their mixture) from highly colored solutions. This ... ...

    Abstract Amino-grafted Mobil Composition of Matter N. 41 (MCM-41/NH₂) and Santa Barbara Amorphous (SBA-15/NH₂) type mesoporous adsorbents were successfully used and compared in this work to remove azo dyes (and their mixture) from highly colored solutions. This paper reports a very fast removal and recycle (in 5 min) of great amounts of textile dyes (about the 100%) by materials characterized by high adsorption/desorption capacities. A qₘₐₓ ≈ 250 mg/g for each adsorption cycle, that should be potentially increase to ≈ 1250 mg/g, under appropriate experimental conditions, was found for the proposed adsorbents. The UV–Vis absorption spectra of dyes were used to support this finding, determining the rate of adsorption. Several parameters affecting the adsorption process were investigated: the contact time, dyes solution pH values and amount of the adsorbent materials, ranging from 0.4 mg to 12 mg, and dyes (5 × 10⁻⁵ M and 1 × 10⁻⁵ M). Further, the Nitrogen adsorption/desorption isotherms, SAXS patterns, TG analyses, Zeta-potential measurements and microscopic imaging techniques, such as SEM and TEM, were used to detail the nature of interaction between dyes and adsorbents, and to investigate the morphology and the mesoporous array of the amino grafted MCM-41 and SBA-15.
    Keywords Barbara ; adsorbents ; adsorption ; azo dyes ; color ; desorption ; fabrics ; image analysis ; nitrogen ; pH ; paper ; porous media ; solutions ; ultraviolet-visible spectroscopy ; water ; zeta potential
    Language English
    Dates of publication 2020-12
    Publishing place Elsevier B.V.
    Document type Article
    Note NAL-light
    ISSN 2214-9937
    DOI 10.1016/j.susmat.2020.e00231
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  8. Article ; Online: Development of Spirulina sea-weed raw extract/polyamidoamine hydrogel system as novel platform in photodynamic therapy: Photostability and photoactivity of chlorophyll a.

    Rizzi, Vito / Gubitosa, Jennifer / Fini, Paola / Fraix, Aurore / Sortino, Salvatore / Agostiano, Angela / Cosma, Pinalysa

    Materials science & engineering. C, Materials for biological applications

    2020  Volume 119, Page(s) 111593

    Abstract: The aim of this paper is to present and characterize Polyamidoamine-based hydrogels (PAA) as scaffolds to host photoactive Chlorophyll a (Chl a) from Spirulina (Arthrospira platensis) sea-weed Extract (SE), for potential applications in Photodynamic ... ...

    Abstract The aim of this paper is to present and characterize Polyamidoamine-based hydrogels (PAA) as scaffolds to host photoactive Chlorophyll a (Chl a) from Spirulina (Arthrospira platensis) sea-weed Extract (SE), for potential applications in Photodynamic Therapy (PDT). The pigment extracted from SE was blended inside PAA without further purification, according to Green Chemistry principles. A comprehensive investigation of this hybrid platform, PAA/SE-based, was thus performed in our laboratory and, by means of Visible absorption and emission spectroscopies, the Chl a features, stability and photoactivity were studied. The obtained results evidenced the presence of two main Chl a forms, monomeric and dimeric, interacting with hydrogel polyamidoamines network. To better understand the nature of this interaction, the spectroscopic investigation of this system was performed both before and after the solidification of the hydrogel, that occurred at least in 24 h. Then, focusing the attention on solid scaffold, the
    MeSH term(s) Chlorophyll ; Chlorophyll A ; Hydrogels ; Photochemotherapy ; Plant Extracts/pharmacology ; Polyamines ; Spirulina
    Chemical Substances Hydrogels ; Plant Extracts ; Poly(amidoamine) ; Polyamines ; Chlorophyll (1406-65-1) ; Chlorophyll A (YF5Q9EJC8Y)
    Language English
    Publishing date 2020-10-08
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 2012160-X
    ISSN 1873-0191 ; 0928-4931
    ISSN (online) 1873-0191
    ISSN 0928-4931
    DOI 10.1016/j.msec.2020.111593
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  9. Article ; Online: Effect of a Composite Alginate/Grape Pomace Extract Packaging Material for Improving Meat Storage.

    Aresta, Antonella Maria / De Vietro, Nicoletta / Gubitosa, Jennifer / Rizzi, Vito / De Pasquale, Ilaria / Fini, Paola / Cosma, Pinalysa / Curri, Maria Lucia / Zambonin, Carlo

    International journal of molecular sciences

    2023  Volume 24, Issue 21

    Abstract: The development of food packaging materials that reduce the production of plastic, preserving at the same time the quality of food, is a topic of great interest today for the scientific community. Therefore, this article aims to report the effectiveness ... ...

    Abstract The development of food packaging materials that reduce the production of plastic, preserving at the same time the quality of food, is a topic of great interest today for the scientific community. Therefore, this article aims to report the effectiveness of an eco-friendly packaging material based on alginic acid and grape pomace extract from
    MeSH term(s) Animals ; Vitis/chemistry ; Alginates ; Biogenic Amines ; Meat/analysis ; Plant Extracts
    Chemical Substances Alginates ; Biogenic Amines ; Plant Extracts
    Language English
    Publishing date 2023-11-03
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2019364-6
    ISSN 1422-0067 ; 1422-0067 ; 1661-6596
    ISSN (online) 1422-0067
    ISSN 1422-0067 ; 1661-6596
    DOI 10.3390/ijms242115958
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  10. Article ; Online: Realizing Eco-Friendly Water-Resistant Sodium-Alginate-Based Films Blended with a Polyphenolic Aqueous Extract from Grape Pomace Waste for Potential Food Packaging Applications.

    Gubitosa, Jennifer / Rizzi, Vito / Marasciulo, Cosma / Maggi, Filippo / Caprioli, Giovanni / Mustafa, Ahmed M / Fini, Paola / De Vietro, Nicoletta / Aresta, Antonella Maria / Cosma, Pinalysa

    International journal of molecular sciences

    2023  Volume 24, Issue 14

    Abstract: Water-resistant and environmentally friendly sodium-alginate-based films have been investigated to develop functional materials to extend the food's shelf-life. A water-stable alginate-based film was prepared, employing both the internal and external ... ...

    Abstract Water-resistant and environmentally friendly sodium-alginate-based films have been investigated to develop functional materials to extend the food's shelf-life. A water-stable alginate-based film was prepared, employing both the internal and external gelation approach in the presence of CaCl
    MeSH term(s) Alginates/chemistry ; Vitis ; Food Packaging ; Water ; Plant Extracts/pharmacology ; Calcium Chloride ; Sodium
    Chemical Substances Alginates ; Water (059QF0KO0R) ; Plant Extracts ; Calcium Chloride (M4I0D6VV5M) ; Sodium (9NEZ333N27)
    Language English
    Publishing date 2023-07-14
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2019364-6
    ISSN 1422-0067 ; 1422-0067 ; 1661-6596
    ISSN (online) 1422-0067
    ISSN 1422-0067 ; 1661-6596
    DOI 10.3390/ijms241411462
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