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  1. Book ; Online ; E-Book: Pesticides in soils

    Rodríguez-Cruz, M. Sonia / Sánchez-Martín, M. Jesús

    occurrence, fate, control and remediation

    (The handbook of environmental chemistry ; volume 113)

    2022  

    Author's details volume editors: M. Sonia Rodríguez-Cruz, M. Jesús Sánchez-Martín ; with contributions by A. Barra Caracciolo [und weiteren]
    Series title The handbook of environmental chemistry ; volume 113
    Collection
    Keywords Environmental chemistry ; Soil science ; Environmental protection ; Civil engineering ; Pollution ; Industrial microbiology
    Subject code 577.14
    Language English
    Size 1 Online-Ressource (xii, 377 Seiten), Illustrationen
    Publisher Springer
    Publishing place Cham
    Publishing country Switzerland
    Document type Book ; Online ; E-Book
    Remark Zugriff für angemeldete ZB MED-Nutzerinnen und -Nutzer
    HBZ-ID HT021364817
    ISBN 978-3-030-90546-0 ; 9783030905453 ; 9783030905477 ; 3-030-90546-2 ; 3030905454 ; 3030905470
    Database ZB MED Catalogue: Medicine, Health, Nutrition, Environment, Agriculture

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  2. Article ; Online: The role of two organic amendments to modify the environmental fate of S-metolachlor in agricultural soils.

    Marín-Benito, Jesús M / Herrero-Hernández, Eliseo / Ordax, José M / Sánchez-Martín, M Jesús / Rodríguez-Cruz, M Sonia

    Environmental research

    2021  Volume 195, Page(s) 110871

    Abstract: S-metolachlor is a widely used herbicide that may contaminate groundwater when applied to irrigated crops, especially when the soil has a low organic carbon (OC) content. The objective here was to assess the capacity of two organic wastes, namely, green ... ...

    Abstract S-metolachlor is a widely used herbicide that may contaminate groundwater when applied to irrigated crops, especially when the soil has a low organic carbon (OC) content. The objective here was to assess the capacity of two organic wastes, namely, green compost (GC) and pelletised organo-mineral manure fertilizer (PM), applied to two soils (S) with different textures at a rate of 10% dry weight to modify the fate of S-metolachlor. The herbicide's Freundlich adsorption coefficient (Kf) increased within a range of 3.2-8.2 times in S + GC and 3.8-6.8 times in S + PM. A positive correlation between adsorption and OC and the coefficient of variation of the OC normalised adsorption coefficients (Kf
    MeSH term(s) Acetamides ; Adsorption ; Herbicides/analysis ; Soil ; Soil Pollutants/analysis
    Chemical Substances Acetamides ; Herbicides ; Soil ; Soil Pollutants ; metolachlor (X0I01K05X2)
    Language English
    Publishing date 2021-02-10
    Publishing country Netherlands
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 205699-9
    ISSN 1096-0953 ; 0013-9351
    ISSN (online) 1096-0953
    ISSN 0013-9351
    DOI 10.1016/j.envres.2021.110871
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    In stock of ZB MED Cologne/Königswinter

    Zs.A 726: Show issues Location:
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  3. Article: The role of two organic amendments to modify the environmental fate of S-metolachlor in agricultural soils

    Marín-Benito, Jesús M / Herrero-Hernández, Eliseo / Ordax, José M / Sánchez-Martín, M. Jesús / Rodríguez-Cruz, M. Sonia

    Environmental research. 2021 Apr., v. 195

    2021  

    Abstract: S-metolachlor is a widely used herbicide that may contaminate groundwater when applied to irrigated crops, especially when the soil has a low organic carbon (OC) content. The objective here was to assess the capacity of two organic wastes, namely, green ... ...

    Abstract S-metolachlor is a widely used herbicide that may contaminate groundwater when applied to irrigated crops, especially when the soil has a low organic carbon (OC) content. The objective here was to assess the capacity of two organic wastes, namely, green compost (GC) and pelletised organo-mineral manure fertilizer (PM), applied to two soils (S) with different textures at a rate of 10% dry weight to modify the fate of S-metolachlor. The herbicide's Freundlich adsorption coefficient (Kf) increased within a range of 3.2–8.2 times in S + GC and 3.8–6.8 times in S + PM. A positive correlation between adsorption and OC and the coefficient of variation of the OC normalised adsorption coefficients (Kfₒc) higher than 20% indicated the evident influence on this process of soil OC content and its nature. The increase in adsorption did not prevent the dissipation of S-metolachlor in the amended soils, although the degradation rate decreased up to ~2 times or was not significantly modified across the different soil types. The S-metolachlor metabolites, metolachlor ethane sulfonic acid and metolachlor oxanilic acid, were detected in the herbicide's dissipation in the unamended soils, but they were not detected in the amended soils. The mobility experiments indicated leached amounts of S-metolachlor higher than 50% in unamended soil. The amounts decreased 1.1–1.7 times and 1.7–1.8 times in the S + GC and S + PM when a saturated flow was applied. Moreover, breakthrough curves indicated a slow leaching kinetics of herbicide in amended soils, with low concentrations continuously detected in the leachates together with a decrease in the maximum peak concentration. The results show the effect of the application of organic wastes especially in sandy soils to promote the immobilisation and/or degradation of S-metolachlor, avoiding its transfer to other environmental compartments.
    Keywords adsorption ; composts ; environmental fate ; groundwater contamination ; irrigation ; metabolites ; metolachlor ethanesulfonic acid ; metolachlor oxanilic acid ; organic carbon ; research ; saturated flow ; sorption isotherms
    Language English
    Dates of publication 2021-04
    Publishing place Elsevier Inc.
    Document type Article
    Note NAL-AP-2-clean
    ZDB-ID 205699-9
    ISSN 1096-0953 ; 0013-9351
    ISSN (online) 1096-0953
    ISSN 0013-9351
    DOI 10.1016/j.envres.2021.110871
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    In stock of ZB MED Cologne/Königswinter

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  4. Article: Physicochemical Study of the Sorption of Pesticides by Wood Components

    Rodríguez-Cruz, M. Sonia / del Hoyo, Carmen / Sánchez-Martín, M. Jesús / Valderrábano, Marta

    Journal of environmental quality. 2009 Mar., v. 38, no. 2

    2009  

    Abstract: The sorption–desorption and interaction mechanisms of three non-ionic (linuron, alachlor, and metalaxyl) and two ionic (paraquat and dicamba) pesticides by three commercial lignins (hydrophobic macromolecule) and cellulose (hydrophilic macromolecule) as ... ...

    Abstract The sorption–desorption and interaction mechanisms of three non-ionic (linuron, alachlor, and metalaxyl) and two ionic (paraquat and dicamba) pesticides by three commercial lignins (hydrophobic macromolecule) and cellulose (hydrophilic macromolecule) as wood components were studied. Wood is a low-cost and environmentally friendly material proposed in recent years to immobilize pesticides in soils. The influence of sorbent and pesticide properties and the identification of the functional groups of the organic molecules involved in sorption were evaluated by a statistical approach and by Fourier transform infrared spectroscopy. The sorption isotherms of non-ionic pesticides by the lignins and cellulose fit the Freundlich model, and those of the ionic pesticides also fit the Langmuir model. The sorption constants of pesticides by cellulose were 62-, 9-, 24-, 119-, and 3-fold lower than those for the sorption by lignins. A predictive model of pesticide sorption indicated that 88.5% of the variability in the sorption coefficient normalized to the organic carbon content could be explained in terms of the variability of the polarity index and the octanol–water partition coefficient of sorbent and sorbate. The greater irreversibility observed for ionic pesticides was attributed to the involvement of simultaneous interaction mechanisms. The results obtained contribute the knowledge of sorption capacity of pesticides by lignin/cellulose, the main components of woods and ubiquitous materials in the environment.
    MeSH term(s) Acetamides/chemistry ; Adsorption ; Alanine/analogs & derivatives/chemistry ; Cellulose/chemistry ; Dicamba/chemistry ; Humic Substances ; Lignin/chemistry ; Linuron/chemistry ; Paraquat/chemistry ; Pesticides/chemistry ; Spectroscopy, Fourier Transform Infrared
    Keywords alachlor ; cellulose ; desorption ; dicamba ; Fourier transform infrared spectroscopy ; humic acids ; hydrophobicity ; immobilization in soil ; lignin ; linuron ; metalaxyl ; octanol-water partition coefficients ; paraquat ; pesticides ; physicochemical properties ; simulation models ; soil organic carbon ; soil organic matter ; sorption ; sorption isotherms ; wood products
    Language English
    Dates of publication 2009-03
    Size p. 719-728.
    Publishing place American Society of Agronomy, Crop Science Society of America, Soil Science Society
    Document type Article
    Note epub
    ZDB-ID 120525-0
    ISSN 1537-2537 ; 0047-2425
    ISSN (online) 1537-2537
    ISSN 0047-2425
    DOI 10.2134/jeq2008.0150
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    In stock of ZB MED Bonn / Germany

    Z 2687: Show issues

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  5. Article: Physicochemical study of the sorption of pesticides by wood components.

    Rodríguez-Cruz, M Sonia / Valderrábano, Marta / Del Hoyo, Carmen / Sánchez-Martín, M Jesús

    Journal of environmental quality

    2009  Volume 38, Issue 2, Page(s) 719–728

    Abstract: The sorption-desorption and interaction mechanisms of three non-ionic (linuron, alachlor, and metalaxyl) and two ionic (paraquat and dicamba) pesticides by three commercial lignins (hydrophobic macromolecule) and cellulose (hydrophilic macromolecule) as ... ...

    Abstract The sorption-desorption and interaction mechanisms of three non-ionic (linuron, alachlor, and metalaxyl) and two ionic (paraquat and dicamba) pesticides by three commercial lignins (hydrophobic macromolecule) and cellulose (hydrophilic macromolecule) as wood components were studied. Wood is a low-cost and environmentally friendly material proposed in recent years to immobilize pesticides in soils. The influence of sorbent and pesticide properties and the identification of the functional groups of the organic molecules involved in sorption were evaluated by a statistical approach and by Fourier transform infrared spectroscopy. The sorption isotherms of non-ionic pesticides by the lignins and cellulose fit the Freundlich model, and those of the ionic pesticides also fit the Langmuir model. The sorption constants of pesticides by cellulose were 62-, 9-, 24-, 119-, and 3-fold lower than those for the sorption by lignins. A predictive model of pesticide sorption indicated that 88.5% of the variability in the sorption coefficient normalized to the organic carbon content could be explained in terms of the variability of the polarity index and the octanol-water partition coefficient of sorbent and sorbate. The greater irreversibility observed for ionic pesticides was attributed to the involvement of simultaneous interaction mechanisms. The results obtained contribute the knowledge of sorption capacity of pesticides by lignin/cellulose, the main components of woods and ubiquitous materials in the environment.
    MeSH term(s) Acetamides/chemistry ; Adsorption ; Alanine/analogs & derivatives ; Alanine/chemistry ; Cellulose/chemistry ; Dicamba/chemistry ; Humic Substances ; Lignin/chemistry ; Linuron/chemistry ; Paraquat/chemistry ; Pesticides/chemistry ; Spectroscopy, Fourier Transform Infrared
    Chemical Substances Acetamides ; Humic Substances ; Pesticides ; Linuron (01XP1SU59O) ; metalaxyl (16K4M187IF) ; alachlor (24S2S61PXL) ; Cellulose (9004-34-6) ; Lignin (9005-53-2) ; Alanine (OF5P57N2ZX) ; Paraquat (PLG39H7695) ; Dicamba (SJG3M6RY6H)
    Language English
    Publishing date 2009-03
    Publishing country United States
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 120525-0
    ISSN 1537-2537 ; 0047-2425
    ISSN (online) 1537-2537
    ISSN 0047-2425
    DOI 10.2134/jeq2008.0150
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Cologne/Königswinter

    Zs.A 2958: Show issues Location:
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  6. Article ; Online: Effect of different wood pretreatments on the sorption-desorption of linuron and metalaxyl by woods.

    Rodríguez-Cruz, M Sonia / Andrades, M Soledad / Parada, A María / Sánchez-Martín, M Jesús

    Journal of agricultural and food chemistry

    2008  Volume 56, Issue 16, Page(s) 7339–7346

    Abstract: The sorption-desorption of two different pesticides, linuron and metalaxyl, by woods was studied. Sorbent/solution ratio and sorption kinetics were also determined. Untreated wood and water, NaOH, HCl, and octadecyltrimethylammonium bromide (ODTMA) ... ...

    Abstract The sorption-desorption of two different pesticides, linuron and metalaxyl, by woods was studied. Sorbent/solution ratio and sorption kinetics were also determined. Untreated wood and water, NaOH, HCl, and octadecyltrimethylammonium bromide (ODTMA) treated pine (softwood) and oak (hardwood) were used as sorbents. Linuron and metalaxyl were sorbed by untreated woods up to 80 and 40%, respectively, in a short time when the sorbent/solution ratio of 1:10 was used. Sorption of pesticides was significantly higher by pine, having higher lignin content, than by oak. Freundlich sorption constants (K(f)) were 96.2 and 74.4 (linuron) and 8.28 and 4.95 (metalaxyl) for untreated pine and oak woods and increased 1.04-2.35-fold (linuron) and 1.33-2.17-fold (metalaxyl) when woods were treated. The sorption was higher by HCl- and ODTMA-treated woods. Additionally, Freundlich desorption constants also indicated greater sorption irreversibility of both pesticides for treated woods than for untreated woods. The results revealed wood residues as a promising, low-cost, and environmentally friendly material to immobilize pesticides in soils, preventing water contamination. Wood treatments aimed at removing soluble wood extracts or at modifying wood chemical structure could increase their sorption capacity.
    MeSH term(s) Adsorption ; Alanine/analogs & derivatives ; Alanine/chemistry ; Alkanes/pharmacology ; Fungicides, Industrial/chemistry ; Herbicides/chemistry ; Hydrochloric Acid/pharmacology ; Kinetics ; Linuron/chemistry ; Pinus/chemistry ; Quaternary Ammonium Compounds/pharmacology ; Quercus/chemistry ; Sodium Hydroxide/pharmacology ; Solutions ; Water Pollution/prevention & control ; Wood/chemistry ; Wood/drug effects
    Chemical Substances Alkanes ; Fungicides, Industrial ; Herbicides ; Quaternary Ammonium Compounds ; Solutions ; octadecyltrimethylammonium bromide ; Linuron (01XP1SU59O) ; metalaxyl (16K4M187IF) ; Sodium Hydroxide (55X04QC32I) ; Alanine (OF5P57N2ZX) ; Hydrochloric Acid (QTT17582CB)
    Language English
    Publishing date 2008-08-27
    Publishing country United States
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 241619-0
    ISSN 1520-5118 ; 0021-8561
    ISSN (online) 1520-5118
    ISSN 0021-8561
    DOI 10.1021/jf800980w
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Cologne/Königswinter

    Zs.A 1172: Show issues Location:
    Je nach Verfügbarkeit (siehe Angabe bei Bestand)
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  7. Article ; Audio / Video: Effect of Different Wood Pretreatments on the Sorption-Desorption of Linuron and Metalaxyl by Woods

    Rodríguez-Cruz, M. Sonia / Andrades, M. Soledad / Parada, A. María / Sánchez-Martín, M. Jesus

    Journal of agricultural and food chemistry. 2008 Aug. 27, v. 56, no. 16

    2008  

    Abstract: The sorption-desorption of two different pesticides, linuron and metalaxyl, by woods was studied. Sorbent/solution ratio and sorption kinetics were also determined. Untreated wood and water, NaOH, HCl, and octadecyltrimethylammonium bromide (ODTMA) ... ...

    Abstract The sorption-desorption of two different pesticides, linuron and metalaxyl, by woods was studied. Sorbent/solution ratio and sorption kinetics were also determined. Untreated wood and water, NaOH, HCl, and octadecyltrimethylammonium bromide (ODTMA) treated pine (softwood) and oak (hardwood) were used as sorbents. Linuron and metalaxyl were sorbed by untreated woods up to 80 and 40%, respectively, in a short time when the sorbent/solution ratio of 1:10 was used. Sorption of pesticides was significantly higher by pine, having higher lignin content, than by oak. Freundlich sorption constants (Kf) were 96.2 and 74.4 (linuron) and 8.28 and 4.95 (metalaxyl) for untreated pine and oak woods and increased 1.04-2.35-fold (linuron) and 1.33-2.17-fold (metalaxyl) when woods were treated. The sorption was higher by HCl- and ODTMA-treated woods. Additionally, Freundlich desorption constants also indicated greater sorption irreversibility of both pesticides for treated woods than for untreated woods. The results revealed wood residues as a promising, low-cost, and environmentally friendly material to immobilize pesticides in soils, preventing water contamination. Wood treatments aimed at removing soluble wood extracts or at modifying wood chemical structure could increase their sorption capacity.
    Keywords softwood ; pretreatment ; sorption ; desorption ; linuron ; metalaxyl ; kinetics ; adsorbents ; sodium hydroxide ; hydrochloric acid ; hardwood ; Quercus ; Pinus ; herbicide residues ; pollution control
    Language English
    Dates of publication 2008-0827
    Size p. 7339-7346.
    Document type Article ; Audio / Video
    ZDB-ID 241619-0
    ISSN 1520-5118 ; 0021-8561
    ISSN (online) 1520-5118
    ISSN 0021-8561
    DOI 10.1021/jf800980w
    Database NAL-Catalogue (AGRICOLA)

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    In stock of ZB MED Bonn / Germany

    Z 1185: Show issues

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