Article ; Online: Pattern Formation in Evaporative Drying of a Polymer Solution Droplet over a Soft Swellable Substrate.
Langmuir : the ACS journal of surfaces and colloids
2023 Volume 39, Issue 27, Page(s) 9526–9537
Abstract: We report morphological evolution and pattern formation during evaporative drying of a droplet of polymethylmethacrylate (PMMA) dissolved in tetrahydrofuran over a soft, swellable cross-linked Sylgard 184 substrate. In contrast to the well-known coffee ... ...
Abstract | We report morphological evolution and pattern formation during evaporative drying of a droplet of polymethylmethacrylate (PMMA) dissolved in tetrahydrofuran over a soft, swellable cross-linked Sylgard 184 substrate. In contrast to the well-known coffee ring formation due to the evaporation of a polymer solution droplet over a rigid substrate, we show that the situation becomes far more complicated over a Sylgard 184 substrate due to solvent penetration and associated swelling. The combined effect of evaporation and diffusive penetration leads to significantly faster solvent loss and results in the formation of an in situ thin polymer shell over the free surface of the evaporating droplet due to the attainment of local glass-transition concentration. The diffusive penetration of the solvent also leads to the spreading of the three-phase contact line (TPCL) of the droplet after dispensing. The vertical component of surface tension acting at the TPCL results in the formation of peripheral creases along the boundary of the droplet after the TPCL pins. With the progressive solvent loss, the shell eventually collapses, resulting in a buckled morphology with a central depression. We show that the evolution pathway and the final deposit morphology depend strongly on the initial PMMA concentration ( |
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Language | English |
Publishing date | 2023-06-29 |
Publishing country | United States |
Document type | Journal Article |
ZDB-ID | 2005937-1 |
ISSN | 1520-5827 ; 0743-7463 |
ISSN (online) | 1520-5827 |
ISSN | 0743-7463 |
DOI | 10.1021/acs.langmuir.3c01069 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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