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Article ; Online: Magnetoviscosity of dilute suspensions of magnetic ellipsoids obtained through rotational Brownian dynamics simulations.

Sánchez, J H / Rinaldi, C

Journal of colloid and interface science

2009 Volume 331, Issue 2, Page(s) 500–506

Abstract: The magnetic field dependent viscosity (magnetoviscosity) of dilute suspensions of magnetic tri-axial ellipsoidal particles suspended in a Newtonian fluid and under applied shear and magnetic fields was studied numerically. Brownian dynamics simulations ... ...

Abstract	The magnetic field dependent viscosity (magnetoviscosity) of dilute suspensions of magnetic tri-axial ellipsoidal particles suspended in a Newtonian fluid and under applied shear and magnetic fields was studied numerically. Brownian dynamics simulations were performed to compute the intrinsic magnetoviscosity of the suspension. Results are presented for the response of dilute suspensions of ellipsoidal particles to constant magnetic and shear flow fields. Suspensions of ellipsoidal particles show a significant effect of aspect ratio on the intrinsic magnetoviscosity of the suspension, and this effect is more pronounced as the aspect ratio becomes more extreme. The use of an effective rotational diffusion coefficient D(r,eff) collapses the normalized intrinsic magnetoviscosity of all suspensions to a master curve as a function of Péclet number with the Langevin parameter alpha=(mu(0)muH)/(k(B)T) as parameter, up to a critical value of alpha for which the results for suspensions of spherical particles deviate from those of suspensions of ellipsoids. This discrepancy is attributed to the action of the shear-torque on the ellipsoidal particles, which tends to orient these particles in the direction of maximum deformation of the simple shear flow, and which does not act on spherical particles.
Language	English
Publishing date	2009-03-15
Publishing country	United States
Document type	Journal Article
ZDB-ID	241597-5
ISSN	1095-7103 ; 0021-9797
ISSN (online)	1095-7103
ISSN	0021-9797
DOI	10.1016/j.jcis.2008.11.061
Database	MEDical Literature Analysis and Retrieval System OnLINE

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Article: Lack of di-(2-ethylhexyl) phthalate activity in the C3H 10T 1 2 cell transformation system.

Sanchez, J H / Abernethy, D J / Boreiko, C J

Toxicology in vitro : an international journal published in association with BIBRA

2010 Volume 1, Issue 1, Page(s) 49–53

Abstract: The widely used plasticizer and rodent carcinogen di-(2-ethylhexyl) phthalate (DEHP) was examined for activity in the C3H 10T 1 2 murine fibroblast cell transformation system. Treatment with DEHP or its metabolite, mono-(2-ethylhexyl) phthalate, did not ... ...

Abstract	The widely used plasticizer and rodent carcinogen di-(2-ethylhexyl) phthalate (DEHP) was examined for activity in the C3H 10T 1 2 murine fibroblast cell transformation system. Treatment with DEHP or its metabolite, mono-(2-ethylhexyl) phthalate, did not produce oncogenic transformation, initiate the process of transformation in cultures treated with a tumour promoter or promote the process of transformation in cultures pretreated with a chemical carcinogen. These findings are consistent with the suggestion that the carcinogenicity of DEHP is mediated by an indirect mechanism and not by covalent interaction of DEHP with DNA.
Language	English
Publishing date	2010-07-28
Publishing country	England
Document type	Journal Article
ZDB-ID	639064-x
ISSN	1879-3177 ; 0887-2333
ISSN (online)	1879-3177
ISSN	0887-2333
DOI	10.1016/0887-2333(87)90038-5
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Article: Vivipary in the Cactaceae: Its taxonomic occurrence and biological significance

Cota-Sanchez, J.H

Flora. 2004, v. 199, no. 6

2004

Keywords	Cactaceae ; epiphytes ; sexual reproduction ; vivipary (plants) ; plant taxonomy ; plant morphology ; fruits (plant anatomy)
Language	English
Size	p. 481-490.
Document type	Article
ZDB-ID	5580-3
ISSN	0367-2530 ; 0373-6490
ISSN	0367-2530 ; 0373-6490
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: A theoretical approach to the photochemical activation of matrix isolated aluminum atoms and their reaction with methane.

Pacheco-Blas, M A / Novaro, O A / Pacheco-Sánchez, J H

The Journal of chemical physics

2010 Volume 133, Issue 17, Page(s) 174307

Abstract: The photochemical activation of Al atoms in cryogenic matrices to induce their reaction with methane has been experimentally studied before. Here, a theoretical study of the nonadiabatic transition probabilities for the ground ((2)P:3s(2)3p(1)) and the ... ...

Abstract	The photochemical activation of Al atoms in cryogenic matrices to induce their reaction with methane has been experimentally studied before. Here, a theoretical study of the nonadiabatic transition probabilities for the ground ((2)P:3s(2)3p(1)) and the lowest excited states ((2)S:3s(2)4s(1) and (2)D:3s(2)3d(1)) of an aluminum atom interacting with a methane molecule (CH(4)) was carried out through ab initio Hartree-Fock self-consistent field calculations. This was followed by a multiconfigurational study of the correlation energy obtained by extensive variational and perturbational configuration interaction analyses using the CIPSI program. The (2)D state is readily inserted into a C-H bond, this being a prelude to a sequence of avoided crossings with the initially repulsive (to CH(4)) lower lying states (2)P and (2)S. We then use a direct extension of the Landau-Zener theory to obtain transition probabilities at each avoided crossing, allowing the formation of an HAlCH(3) intermediate that eventually leads to the final pair of products H+AlCH(3) and HAl+CH(3).
Language	English
Publishing date	2010-11-07
Publishing country	United States
Document type	Journal Article
ZDB-ID	3113-6
ISSN	1089-7690 ; 0021-9606
ISSN (online)	1089-7690
ISSN	0021-9606
DOI	10.1063/1.3499813
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Article: Differential effects of tumour promoters on the growth of normal human bronchial epithelial cells and human lung tumour cell lines.

Sanchez, J H / Boreiko, C J / Furlong, J / Hesterberg, T W

Toxicology in vitro : an international journal published in association with BIBRA

2010 Volume 1, Issue 4, Page(s) 183–188

Abstract: The effects of the tumour promoter, 12-O-tetradecanoylphorbol-13-acetate (TPA) on the colony-forming efficiency and growth of normal human bronchial epithelial (NHBE) cells and five lung squamous carcinoma cell lines were compared in medium containing 1% ...

Abstract	The effects of the tumour promoter, 12-O-tetradecanoylphorbol-13-acetate (TPA) on the colony-forming efficiency and growth of normal human bronchial epithelial (NHBE) cells and five lung squamous carcinoma cell lines were compared in medium containing 1% foetal bovine serum. TPA (0.1-5.0 ng/ml) inhibited the growth of NHBE cells and one carcinoma cell line, while four of the five carcinoma lines were less sensitive to the growth inhibitory properties of TPA but were slightly inhibited at higher TPA concentrations. The responses of NHBE cells and carcinoma cells to TPA, and the related compounds, mezerein, 4-O-methyl TPA, and phorbol were then compared in serum-free medium. In general, the removal of serum from the medium increased the differences in the responses to TPA between normal and tumour cells. Two carcinoma lines inhibited by TPA in 1% serum were stimulated by TPA in the absence of serum. Mezerein and, to a lesser extent, 4-O-methyl TPA also produced differential responses in colony-forming efficiencies between tumour lines and NHBE cells. Phorbol had no effect on either NHBE cells or on carcinoma cell lines. The relative insensitivity of carcinoma cell lines to the growth inhibitory effects of tumour promoters is consistent with the hypothesis that tumour promotion involves selection against normal cells to permit clonal expansion of preneoplastic or neoplastic cell types.
Language	English
Publishing date	2010-07-28
Publishing country	England
Document type	Journal Article
ZDB-ID	639064-x
ISSN	1879-3177 ; 0887-2333
ISSN (online)	1879-3177
ISSN	0887-2333
DOI	10.1016/0887-2333(87)90019-1
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Article: An SEM Survey of The Leaf Epidermis in Danthonioid Grasses (Poaceae: Danthonioideae)

Reimer, E / Cota-Sanchez, J.H

Systematic botany. 2007 Jan-Mar, v. 32, no. 1

2007

Abstract: This study comprised a scanning electron microscope survey of abaxial epidermal features in subfamily Danthonioideae, with emphasis on North American Danthonia. The survey included 21 taxa, encompassing seven genera (Austrodanthonia, Cortaderia, ... ...

Abstract	This study comprised a scanning electron microscope survey of abaxial epidermal features in subfamily Danthonioideae, with emphasis on North American Danthonia. The survey included 21 taxa, encompassing seven genera (Austrodanthonia, Cortaderia, Danthonia, Merxmuellera, Notodanthonia, Rytidosperma, Tribolium) and the eight North American Danthonia species. We investigated micromorphological characters to determine taxonomic utility and whether North American representatives of Danthonia are distinct. We examined micromorphological epidermal features: macrohairs, bicellular microhairs, prickle hairs, silica bodies, and stomata. We found no distinguishing characters at the subfamilial level. Danthonia is characterized by the absence of abaxial stomata and presence of bicellular microhairs with basal and terminal cells of equal length and microhairs with long basal cells relative to terminal cells. Prickle hairs in the abaxial epidermal costal regions of four species of North American Danthonia are reported for the first time.
Keywords	Danthonia ; plant taxonomy ; geographical distribution ; plant morphology ; leaves ; epidermis (plant) ; ultrastructure ; North America
Language	English
Dates of publication	2007-01
Size	p. 60-70.
Document type	Article
ZDB-ID	2052625-8
ISSN	1548-2324 ; 0363-6445
ISSN (online)	1548-2324
ISSN	0363-6445
Database	NAL-Catalogue (AGRICOLA)

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Article: Vivipary in the cactus family: A reply to Ortega-Baes’ et al. evaluation of 25 species from northwestern Argentina

Cota-Sánchez, J.H / Reyes-Olivas, A / Abreu, D.D

Journal of arid environments. 2011 Sept., v. 75, issue 9

2011

Abstract: This is a reply to Ortega-Baes’ et al. (2010) survey of 25 Argentinean species of cacti evaluated for vivipary. We argue that the sample size and geographic area of the species investigated is insufficient to totally exclude the putative commonness of ... ...

Abstract	This is a reply to Ortega-Baes’ et al. (2010) survey of 25 Argentinean species of cacti evaluated for vivipary. We argue that the sample size and geographic area of the species investigated is insufficient to totally exclude the putative commonness of this condition in the Cactaceae. We indicate possible reasons why they did not find viviparous fruits in their survey. Failure to detect vivipary in cacti of NW Argentina may be correlated with limited taxonomic sampling and geographic region in addition to intrinsic and extrinsic plant factors, including different stages of fruit and seed development and genetic, ecological, and edaphic aspects, which, individually or in concert, control precocious germination. We uphold that viviparity is putatively frequent in this family and list 16 new cases for a total of 53 viviparous cacti, which make up ca. 4% incidence of viviparism in the Cactaceae, a substantially higher percentage than most angiosperm families exhibiting this condition. The Cactaceae ranks fourth in frequency of viviparity after the aquatic families of mangroves and seagrasses. We suggest the re-evaluation of cactus vivipary, primarily as a reproductive adaptation to changing environments and physiological stress with a secondary role as a reproductive strategy with limited offspring dispersal/survival and fitness advantages.
Keywords	Cactaceae ; adaptation ; cacti and succulents ; fruiting ; fruits ; germination ; progeny ; surveys ; Argentina
Language	English
Dates of publication	2011-09
Size	p. 878-880.
Document type	Article
ZDB-ID	428507-4
ISSN	1095-922X ; 0140-1963
ISSN (online)	1095-922X
ISSN	0140-1963
DOI	10.1016/j.jaridenv.2011.04.015
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Transition probabilities for the Au ((2)S, (2)D, and (2)P) with SiH(4) reaction.

Pacheco-Sánchez, J H / Luna-García, H M / García-Cruz, L M / Novaro, O

The Journal of chemical physics

2010 Volume 132, Issue 4, Page(s) 44301

Abstract: Transition probabilities on the interaction of the ground and the lowest excited states of gold Au ((2)S:5d(10)6s(1), (2)D:5d(9)6s(2), and (2)P:5d(10)6p(1)) with silane (SiH(4)) are studied through ab initio Hartree-Fock self-consistent field ... ...

Abstract	Transition probabilities on the interaction of the ground and the lowest excited states of gold Au ((2)S:5d(10)6s(1), (2)D:5d(9)6s(2), and (2)P:5d(10)6p(1)) with silane (SiH(4)) are studied through ab initio Hartree-Fock self-consistent field calculations, where the atom's core is represented by relativistic effective core potentials. These calculations are followed by a multiconfigurational self-consistent field study. The correlation energy is accounted for through extensive variational and perturbative second order multireference Moller-Plesset configuration interaction analysis of selected perturbations obtained by iterative process calculations using the CIPSI program package. It is found that the Au atom in the ((2)P:5d(10)6p(1)) state inserts in the Si-H bond. In this interaction its corresponding D (2)A(') potential energy surface is initially attractive and only becomes repulsive after encountering an avoided crossing with the initially repulsive C (2)A(') surface linked to the Au((2)D:5d(9)6s(2))-SiH(4) fragments. The A, B, and C (2)A(') curves derived from the Au((2)D:5d(9)6s(2)) atom interaction with silane are initially repulsive, each one of them showing two avoided crossings, while the A (2)A(') curve goes sharply downwards until it meets the X (2)A(') curve interacting adiabatically, which is linked with the Au((2)S:5d(10)6s(1))-SiH(4) moieties. The A (2)A(') curve becomes repulsive after the avoided crossing with the X (2)A('), curve. The lowest-lying X (2)A(') potential leads to the HAuSiH(3) X (2)A(') intermediate molecule. This intermediate molecule, diabatically correlated with the Au((2)P:5d(10)6p(1))+SiH(4) system which lies 3.34 kcal/mol above the ground state reactants, has been carefully characterized as have the dissociation channels leading to the AuH+SiH(3) and H+AuSiH(3) products. These products are reached from the HAuSiH(3) intermediate without any activation barrier. The Au-SiH(4) calculation results are successfully compared to experiment. Landau-Zener theory of avoided crossings is applied to these interactions considering the angle theta instead of the distance r as the reaction coordinate.
Language	English
Publishing date	2010-01-28
Publishing country	United States
Document type	Journal Article
ZDB-ID	3113-6
ISSN	1089-7690 ; 0021-9606
ISSN (online)	1089-7690
ISSN	0021-9606
DOI	10.1063/1.3298586
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Article: Vivipary in the cactus family: A reply to Ortega- Baes' et al. evaluation of 25 species from northwestern Argentina

Cota-Sánchez, J. H. / Reyes-Olivas, Á. / Abreu, D. D.

Journal of arid environments

2011 Volume 75, Issue 9, Page(s) 878

Language	English
Document type	Article
ZDB-ID	428507-4
ISSN	0140-1963
Database	Current Contents Nutrition, Environment, Agriculture

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Article: Ab initio study of the reactions of Ga((2)P, (2)S, and (2)P) with silane.

Pacheco-Sánchez, J H / Luna-García, H / Castillo, S

The Journal of chemical physics

2004 Volume 121, Issue 12, Page(s) 5777–5782

Abstract: The interactions of Ga((2)P:4s(2)4p(1), (2)S:4s(2)5s(1), and (2)P:4s(2)5p(1)) with SiH(4) are studied by means of Hartree-Fock self-consistent field (SCF) and multiconfigurational SCF followed by extensive variational and perturbational second-order ... ...

Abstract	The interactions of Ga((2)P:4s(2)4p(1), (2)S:4s(2)5s(1), and (2)P:4s(2)5p(1)) with SiH(4) are studied by means of Hartree-Fock self-consistent field (SCF) and multiconfigurational SCF followed by extensive variational and perturbational second-order multireference Møller-Plesset configuration by perturbation selected by iterative process calculations, using relativistic effective core potentials. The Ga atom in its (2)P(4s(2)5p(1)) state can spontaneously insert into the SiH(4). The Ga atom in its (2)S(4s(2)5s(1)) state is inserted into the SiH(4). In this interaction the 3 (2)A(') potential energy surface initially attractive becomes repulsive after meeting the 2 (2)A(') surface linked with the Ga((2)P:4s(2)4p(1))+SiH(4) fragments. The two (2)A(') curves (2 (2)A(') and X (2)A(')) derived from the interaction of Ga((2)P:4s(2)4p(1)) atom with silane molecule are initially repulsive. The 2 (2)A(') curve after an avoided crossing with the 3 (2)A(') curve goes down until it meets the X (2)A(') curve. The 2 (2)A(') curve becomes repulsive after the avoided crossing with the X (2)A(') curve. The X (2)A(') curve becomes attractive only after its avoided crossing with the 2 (2)A(') curve. The lowest-lying X (2)A(') potential leads to the HGaSiH(3)X (2)A(') intermediate molecule. This intermediate molecule, diabatically correlated with the Ga((2)S:4s(2)5s(1))+SiH(4) fragments, which lies 1.5 kcal/mol above the ground state reactants leads to the GaH+SiH(3) or H+GaSiH(3) products through the dissociation channels. These products are reached from the HGaSiH(3) intermediate without activation barriers. This work shows that the Ga atom at its first excited state in the presence of silane molecules in gas phase leads to the formation of SiH(3) radicals, H atoms, GaH hydrides, as well as gallium silicide molecules.
Language	English
Publishing date	2004-09-22
Publishing country	United States
Document type	Journal Article
ZDB-ID	3113-6
ISSN	1089-7690 ; 0021-9606
ISSN (online)	1089-7690
ISSN	0021-9606
DOI	10.1063/1.1785147
Database	MEDical Literature Analysis and Retrieval System OnLINE

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