Article ; Online: Divergent Synthesis of Six Recent Berkeleylactones.
2023 Volume 86, Issue 2, Page(s) 423–428
Abstract: The six recently isolated berkeleylactones E, J, K, M, N, and O were synthesized for the first time by a divergent strategy starting from a common intermediate in our synthesis of berkeleylactone A. Key features were the stereoselective formation of the ... ...
Abstract | The six recently isolated berkeleylactones E, J, K, M, N, and O were synthesized for the first time by a divergent strategy starting from a common intermediate in our synthesis of berkeleylactone A. Key features were the stereoselective formation of the γ,δ-dihydroxy-α,β-unsaturated ester moiety and the development of a general protection group strategy. Along the way we also established a short high-yielding formal synthesis of the often-synthesized antibiotic A26771B. |
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MeSH term(s) | Stereoisomerism ; Anti-Bacterial Agents ; Esters |
Chemical Substances | Anti-Bacterial Agents ; Esters |
Language | English |
Publishing date | 2023-02-13 |
Publishing country | United States |
Document type | Journal Article |
ZDB-ID | 304325-3 |
ISSN | 1520-6025 ; 0163-3864 |
ISSN (online) | 1520-6025 |
ISSN | 0163-3864 |
DOI | 10.1021/acs.jnatprod.3c00053 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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