Article ; Online: Gradient Transformation of the Double Gyroid to the Double Diamond in Soft Matter.
ACS nano
2024 Volume 18, Issue 13, Page(s) 9443–9450
Abstract: Transitions between gyroid and diamond intercatenated double network phases occur in many types of soft matter, but to date, the structural pathway and the crystallographic relationships remain unclear. Slice and view scanning electron microscopy ... ...
Abstract | Transitions between gyroid and diamond intercatenated double network phases occur in many types of soft matter, but to date, the structural pathway and the crystallographic relationships remain unclear. Slice and view scanning electron microscopy tomography of a diblock copolymer affords monitoring of the evolving shape of the intermaterial dividing surface, allowing structural characterization of both the majority and minority domains. Two trihedral malleable mesoatoms combine to form a single tetrahedral mesoatom in a volume additive manner while preserving network topology, as the types of loops, the number of mesoatoms in a loop, minority domain strut lengths, and directions that connect a given mesoatom to its neighbors evolve across a 150 nm wide transition zone (TZ). The [111] |
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Language | English |
Publishing date | 2024-03-11 |
Publishing country | United States |
Document type | Journal Article |
ISSN | 1936-086X |
ISSN (online) | 1936-086X |
DOI | 10.1021/acsnano.3c11101 |
Database | MEDical Literature Analysis and Retrieval System OnLINE |
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