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  1. AU="Suits, Arthur G"
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  1. Article ; Online: Roaming Reactions and Dynamics in the van der Waals Region.

    Suits, Arthur G

    Annual review of physical chemistry

    2020  Volume 71, Page(s) 77–100

    Abstract: Roaming reactions were first clearly identified in photodissociation of formaldehyde 15 years ago, and roaming dynamics are now recognized as a universal aspect of chemical reactivity. These reactions typically involve frustrated near-dissociation of a ... ...

    Abstract Roaming reactions were first clearly identified in photodissociation of formaldehyde 15 years ago, and roaming dynamics are now recognized as a universal aspect of chemical reactivity. These reactions typically involve frustrated near-dissociation of a quasibound system to radical fragments, followed by reorientation at long range and intramolecular abstraction. The consequences can be unexpected formation of molecular products, depletion of the radical pool in chemical systems, and formation of products with unusual internal state distributions. In this review, I examine some current aspects of roaming reactions with an emphasis on experimental results, focusing on possible quantum effects in roaming and roaming dynamics in bimolecular systems. These considerations lead to a more inclusive definition of roaming reactions as those for which key dynamics take place at long range.
    Language English
    Publishing date 2020-02-18
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1470474-2
    ISSN 1545-1593 ; 0066-426X
    ISSN (online) 1545-1593
    ISSN 0066-426X
    DOI 10.1146/annurev-physchem-050317-020929
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Crossed-Beam Imaging of the Reaction of OH with Propanol Isomers.

    Dias, Nureshan / Li, Hongwei / Suits, Arthur G

    The journal of physical chemistry. A

    2023  Volume 127, Issue 24, Page(s) 5202–5208

    Abstract: We present a crossed-beam imaging study of the reactions of OH radicals with 1- and 2-propanol at a collision energy of 8 kcal ... ...

    Abstract We present a crossed-beam imaging study of the reactions of OH radicals with 1- and 2-propanol at a collision energy of 8 kcal mol
    Language English
    Publishing date 2023-06-11
    Publishing country United States
    Document type Journal Article
    ISSN 1520-5215
    ISSN (online) 1520-5215
    DOI 10.1021/acs.jpca.3c02703
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Tribute to Paul L. Houston.

    Bowman, Joel M / Kable, Scott H / Suits, Arthur G

    The journal of physical chemistry. A

    2023  Volume 127, Issue 9, Page(s) 2068–2070

    Language English
    Publishing date 2023-03-09
    Publishing country United States
    Document type Journal Article
    ISSN 1520-5215
    ISSN (online) 1520-5215
    DOI 10.1021/acs.jpca.3c00707
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Invited Review Article: Photofragment imaging.

    Suits, Arthur G

    The Review of scientific instruments

    2018  Volume 89, Issue 11, Page(s) 111101

    Abstract: Photodissociation studies in molecular beams that employ position-sensitive particle detection to map product recoil velocities emerged thirty years ago and continue to evolve with new laser and detector technologies. These powerful methods allow ... ...

    Abstract Photodissociation studies in molecular beams that employ position-sensitive particle detection to map product recoil velocities emerged thirty years ago and continue to evolve with new laser and detector technologies. These powerful methods allow application of tunable laser detection of single product quantum states, simultaneous measurement of velocity and angular momentum polarization, measurement of joint product state distributions for the detected and undetected products, coincident detection of multiple product channels, and application to radicals and ions as well as closed-shell molecules. These studies have permitted deep investigation of photochemical dynamics for a broad range of systems, revealed new reaction mechanisms, and addressed problems of practical importance in atmospheric, combustion, and interstellar chemistry. This review presents an historical overview, a detailed technical account of the range of methods employed, and selected experimental highlights illustrating the capabilities of the method.
    Language English
    Publishing date 2018-11-29
    Publishing country United States
    Document type Journal Article
    ZDB-ID 209865-9
    ISSN 1089-7623 ; 0034-6748
    ISSN (online) 1089-7623
    ISSN 0034-6748
    DOI 10.1063/1.5045325
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Kinetics of CN (

    Thawoos, Shameemah / Hall, Gregory E / Cavallotti, Carlo / Suits, Arthur G

    Faraday discussions

    2023  Volume 245, Page(s) 245–260

    Abstract: We present an experimental and theoretical investigation of the reaction of vibrationally excited CN ( ...

    Abstract We present an experimental and theoretical investigation of the reaction of vibrationally excited CN (
    Language English
    Publishing date 2023-09-20
    Publishing country England
    Document type Journal Article
    ISSN 1364-5498
    ISSN (online) 1364-5498
    DOI 10.1039/d3fd00029j
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Cold collisions of hot molecules.

    Perera, Chatura A / Amarasinghe, Chandika / Guo, Hua / Suits, Arthur G

    Physical chemistry chemical physics : PCCP

    2023  Volume 25, Issue 34, Page(s) 22595–22606

    Abstract: In this Perspective, we review our recent work on rotationally inelastic collisions of highly vibrationally excited NO molecules prepared in single rotational and parity levels ... ...

    Abstract In this Perspective, we review our recent work on rotationally inelastic collisions of highly vibrationally excited NO molecules prepared in single rotational and parity levels at
    Language English
    Publishing date 2023-08-30
    Publishing country England
    Document type Journal Article ; Review
    ZDB-ID 1476244-4
    ISSN 1463-9084 ; 1463-9076
    ISSN (online) 1463-9084
    ISSN 1463-9076
    DOI 10.1039/d3cp02071a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Multichannel Radical-Radical Reaction Dynamics of NO + Propargyl Probed by Broadband Rotational Spectroscopy.

    Dias, Nureshan / Gurusinghe, Ranil M / Suits, Arthur G

    The journal of physical chemistry. A

    2022  Volume 126, Issue 32, Page(s) 5354–5362

    Abstract: Chirped-pulse rotational spectroscopy in a quasi-uniform flow has been used to investigate the reaction dynamics of a multichannel radical-radical reaction of relevance to planetary atmospheres and combustion. In this work, the NO + propargyl ( ... ...

    Abstract Chirped-pulse rotational spectroscopy in a quasi-uniform flow has been used to investigate the reaction dynamics of a multichannel radical-radical reaction of relevance to planetary atmospheres and combustion. In this work, the NO + propargyl (C
    Language English
    Publishing date 2022-08-08
    Publishing country United States
    Document type Journal Article
    ISSN 1520-5215
    ISSN (online) 1520-5215
    DOI 10.1021/acs.jpca.2c01629
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Universal crossed beam imaging studies of polyatomic reaction dynamics.

    Li, Hongwei / Suits, Arthur G

    Physical chemistry chemical physics : PCCP

    2020  Volume 22, Issue 20, Page(s) 11126–11138

    Abstract: The marriage between high level quantum calculations and experimental advances in laser technology, quantum state control, and detection techniques have opened the door to the study of molecular collision dynamics at a new level of detail. However, one ... ...

    Abstract The marriage between high level quantum calculations and experimental advances in laser technology, quantum state control, and detection techniques have opened the door to the study of molecular collision dynamics at a new level of detail. However, one current challenge lies in adapting these powerful strategies to address questions beyond the scope of the small ground state systems that have largely been the focus of reaction dynamics investigations to-date. For molecules with intermediate or large size (more than 6 atoms), lack of spectroscopic information and spectral congestion limit quantum state preparation, control and detection for experiment, and the large number of degrees of freedom of the system makes accurate quantum dynamics calculations prohibitively expensive. Nevertheless, studies of the chemical dynamics of such systems can reveal novel aspects of reactivity not anticipated based upon the behavior of smaller model systems. This Perspective will highlight applications of soft vacuum ultraviolet photoionization at 157 nm as a universal probe in combination with crossed beams and DC slice velocity map ion imaging to study bimolecular reaction dynamics of molecules of intermediate or large size, illuminated with support of high-level ab initio calculations. Here, we report on the chemical dynamics of atomic oxygen or chlorine reactions with organic compounds: propanol isomers, alkylamines (N(CH
    Language English
    Publishing date 2020-03-30
    Publishing country England
    Document type Journal Article
    ZDB-ID 1476244-4
    ISSN 1463-9084 ; 1463-9076
    ISSN (online) 1463-9084
    ISSN 1463-9076
    DOI 10.1039/d0cp00522c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Quantum resonances and roaming dynamics in formaldehyde photodissociation.

    Foley, Casey D / Xie, Changjian / Guo, Hua / Suits, Arthur G

    Faraday discussions

    2022  Volume 238, Page(s) 249–265

    Abstract: The unimolecular dissociation of formaldehyde is ... ...

    Abstract The unimolecular dissociation of formaldehyde is studied
    Language English
    Publishing date 2022-10-21
    Publishing country England
    Document type Journal Article
    ISSN 1364-5498
    ISSN (online) 1364-5498
    DOI 10.1039/d2fd00050d
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Differential Cross Sections for Cold, State-to-State Spin-Orbit Changing Collisions of NO(

    Perera, Chatura A / Zuo, Junxiang / Guo, Hua / Suits, Arthur G

    The journal of physical chemistry. A

    2022  Volume 126, Issue 21, Page(s) 3338–3346

    Abstract: Inelastic scattering processes have proven a powerful means of investigating molecular interactions, and much current effort is focused on the cold and ultracold regime where quantum phenomena are clearly manifested. Studies of collisions of the open ... ...

    Abstract Inelastic scattering processes have proven a powerful means of investigating molecular interactions, and much current effort is focused on the cold and ultracold regime where quantum phenomena are clearly manifested. Studies of collisions of the open shell nitric oxide (NO) molecule have been central in this effort since the pioneering work of Houston and co-workers in the early 1990s. State-to-state scattering of vibrationally excited molecules in the cold regime introduces challenges that test the suitability of current theoretical methods for
    Language English
    Publishing date 2022-05-23
    Publishing country United States
    Document type Journal Article
    ISSN 1520-5215
    ISSN (online) 1520-5215
    DOI 10.1021/acs.jpca.2c02698
    Database MEDical Literature Analysis and Retrieval System OnLINE

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