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  1. Article ; Online: Revealing the photochemical damage behavior of acidified Xuan paper based on the spectroscopic investigation and principal component analysis.

    Dang, Rui / Yang, Yang / Kang, Yafang / Tan, Huijiao

    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy

    2023  Volume 303, Page(s) 123244

    Abstract: In museums, there is a huge storage of Xuan paper cultural relics with profound historical and artistic significances. Exploring the photochemical damage behavior of Xuan paper that is generally in acidification, namely its damage mechanisms and laws, is ...

    Abstract In museums, there is a huge storage of Xuan paper cultural relics with profound historical and artistic significances. Exploring the photochemical damage behavior of Xuan paper that is generally in acidification, namely its damage mechanisms and laws, is crucial for the preventive lighting protection for paper cultural relics. In this study, the accelerated aging experiments in the range of visible light were conducted on Xuan paper samples with different degrees of acidification. The photochemical damage mechanisms of samples were traced, which is related with the synergistic effects of oxidation and hydrolysis reactions. It can be found that there is an effect of acidification, a long-standing material property of Xuan paper, on its damage, which further defines its preservation state in museums. On this basis, a spectral quantification method of infrared spectra combined with the principal component analysis was proposed to comprehensively analyze the photochemical damage law of Xuan paper in different preservation states. The analysis shows that the effect of acidification degree (pH values), spectra wavelength (λ), and their interaction on the damage to Xuan paper are statistically significant. Furthermore, the fitted mathematical function of pH values and λ is of great importance for evaluating photochemical damage, in order to further develop preventive lighting protection applications.
    Language English
    Publishing date 2023-08-06
    Publishing country England
    Document type Journal Article
    ZDB-ID 210413-1
    ISSN 1873-3557 ; 0370-8322 ; 0584-8539 ; 1386-1425
    ISSN (online) 1873-3557
    ISSN 0370-8322 ; 0584-8539 ; 1386-1425
    DOI 10.1016/j.saa.2023.123244
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Raman spectroscopy-based method for evaluating LED illumination-induced damage to pigments in high-light-sensitivity art.

    Dang, Rui / Tan, Huijiao / Wang, Nan / Liu, Gang / Zhang, Fenghui / Song, Xiangyang

    Applied optics

    2020  Volume 59, Issue 15, Page(s) 4599–4605

    Abstract: Because commonly used organic pigments are highly responsive to visible light, high-light-sensitivity art is vulnerable to irreversible illumination-induced damage caused by radiation from light sources. With application of the four primary white light- ... ...

    Abstract Because commonly used organic pigments are highly responsive to visible light, high-light-sensitivity art is vulnerable to irreversible illumination-induced damage caused by radiation from light sources. With application of the four primary white light-emitting diodes (fp-WLEDs) in museums, it is urgent to evaluate the illumination-induced damage to high-light-sensitivity art caused by the fp-WLEDs. Four narrowband LEDs with different peak wavelengths of 450, 510, 583, and 650 nm that constitute the spectra of the fp-WLEDs were used to irradiate three commonly used organic pigments: safflower, gamboge, and indigo. Based on the fundamental reason for the illumination-induced damage, that is, photochemical reactions, Raman spectroscopy was introduced into the study. The Raman spectra of pigments were measured before and after illumination. The characteristic Raman peaks corresponding to the functional groups that determine color and structure of pigments were selected, and the variations in their peak intensities were calculated. The illumination-induced damage coefficients of four narrowband LEDs on three organic pigments were obtained, providing a data basis for illumination-induced damage evaluation equation proposed in this study, which was expected to further realize museum admission evaluation of the new fp-WLEDs.
    Language English
    Publishing date 2020-06-08
    Publishing country United States
    Document type Journal Article
    ISSN 1539-4522
    ISSN (online) 1539-4522
    DOI 10.1364/AO.379398
    Database MEDical Literature Analysis and Retrieval System OnLINE

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