Article: [PdS2C2(COOMe)2](6n) (n = 0, -1, -2, -3, -4): hexanuclear homoleptic palladium dithiolene complexes.
Journal of the American Chemical Society
2002 Volume 124, Issue 33, Page(s) 9664–9665
Abstract: Reaction of a stoichiometric equivalent of the zinc-dithiolene complex, (tmeda)ZnS2C2(COOMe)2 (tmeda = tetramethylethylenediamine), with (MeCN)2PdCl2 results in a 1:1 homoleptic dithiolene that forms the hexanuclear cluster [PdS2C2(COOMe)2]6 (1). X-ray ... ...
| Abstract | Reaction of a stoichiometric equivalent of the zinc-dithiolene complex, (tmeda)ZnS2C2(COOMe)2 (tmeda = tetramethylethylenediamine), with (MeCN)2PdCl2 results in a 1:1 homoleptic dithiolene that forms the hexanuclear cluster [PdS2C2(COOMe)2]6 (1). X-ray structure analysis of 1 indicates a Pd6S12 core comprised of six face-centered palladium atoms and 12 edge-centered sulfur atoms situated on an imaginary approximate cube. Complex 1 undergoes four distinct and reversible one-electron redox steps in dichloromethane at -186, -484, -1174, and -1524 mV versus a standard calomel electrode (ferrocenium+/ferrocene redox couple 409 mV). The two-electron reduction product of 1, [Bu4N]2[(PdS2C2(COOMe)2)6] (2), has been chemically isolated and characterized. |
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| Language | English | ||||||||||
| Publishing date | 2002-08-21 | ||||||||||
| Publishing country | United States | ||||||||||
| Document type | Journal Article | ||||||||||
| ZDB-ID | 3155-0 | ||||||||||
| ISSN | 1520-5126 ; 0002-7863 | ||||||||||
| ISSN (online) | 1520-5126 | ||||||||||
| ISSN | 0002-7863 | ||||||||||
| DOI | 10.1021/ja026079k | ||||||||||
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| Database | MEDical Literature Analysis and Retrieval System OnLINE |
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