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  1. Article ; Online: Evaluation of Queen Palm residues and kraft lignin in the production of biofuels using densification and slow pyrolysis technology.

    van Els, Pedro Paulo Dunice / Setter, Carine / de Oliveira, Tiago José Pires

    Environmental science and pollution research international

    2022  Volume 29, Issue 60, Page(s) 90011–90022

    Abstract: This study aims to enhance the energy use of two products of industry - Queen Palm residue and kraft lignin (KF) - through the combination of two technologies - briquetting and slow pyrolysis. The addition of 20% KF provided briquettes with higher ... ...

    Abstract This study aims to enhance the energy use of two products of industry - Queen Palm residue and kraft lignin (KF) - through the combination of two technologies - briquetting and slow pyrolysis. The addition of 20% KF provided briquettes with higher physical, energy, and mechanical properties. The yields of the pyrolysis products were affected by both the pyrolysis temperature and the addition of KF. In the bio-oil, the presence of phenols, methyl phenols, and methoxy phenols was highlighted; these compounds were present in greater quantities in the treatments with KF. It is concluded that combining the briquetting and pyrolysis processes produces both energy and economic benefits because it is possible to transport lighter loads with the same amount of energy per volume. Under the briquetting conditions adopted in this study, the addition of KF as a binder is necessary because this results in briquettes with better physical, energy and mechanical properties.
    MeSH term(s) Biofuels ; Technology
    Chemical Substances Biofuels
    Language English
    Publishing date 2022-07-21
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1178791-0
    ISSN 1614-7499 ; 0944-1344
    ISSN (online) 1614-7499
    ISSN 0944-1344
    DOI 10.1007/s11356-022-22075-z
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  2. Article ; Online: Impact of Extraction Methods and Transportation Conditions on Lipid Profiles of Bovine Oocytes.

    de Lima, Camila Bruna / Milazzotto, Marcella Pecora / Vireque, Alessandra Aparecida / Joaquim, Daniel Carlino / Sobreira, Tiago Jose Paschoal / Ferreira, Christina Ramires

    Reproductive sciences (Thousand Oaks, Calif.)

    2024  

    Abstract: Lipids play numerous pivotal physiological roles in mammalian reproduction, being indispensable for oocyte competence acquisition and post-fertilization embryonic development. Profiling lipids in minute samples, such as oocytes, presents challenges but ... ...

    Abstract Lipids play numerous pivotal physiological roles in mammalian reproduction, being indispensable for oocyte competence acquisition and post-fertilization embryonic development. Profiling lipids in minute samples, such as oocytes, presents challenges but has been accomplished through mass spectrometry technologies like Multiple Reaction Monitoring (MRM) profiling. With the dual objectives of simplifying workflow and examining the influence of preanalytical conditions, we assessed whether transportation at room temperature affects the lipid profile of bovine oocytes. To this end, samples were prepared using either monophasic (methanol only) or biphasic liquid extraction protocols (Bligh & Dyer method) and transported either on dry ice or at room temperature inside sealed-vacuum packages to prevent lipid oxidation. Subsequently, employing a comprehensive method, we screened a list of 316 MRMs from 10 different lipid subclasses in oocyte lipid extracts. Principal Component Analysis (PCA) revealed similar lipid profiles concerning temperature during transportation, whereas clear differentiation among samples was observed based on the lipid extraction method. Univariate analysis indicated that the one-phase methanol extraction resulted in higher relative abundances of phospholipids, except for phosphatidylserines. Conversely, the Bligh & Dyer extraction favored the detection of neutral intracellular lipids (triacylglycerols, free fatty acids, cholesteryl esters, and acyl-carnitines). Consequently, lipid recovery was directly correlated with the polarity of lipid class and the extraction method. Regarding transportation temperature, phosphatidylethanolamine, triacylglycerol, and free fatty acids exhibited lower abundances when samples were transported at room temperature. Based on multivariate and univariate analyses, we conclude that if samples undergo the same lipid extraction protocol and are transported in the same batch at room temperature inside vacuum-sealed bags, it is feasible to analyze lipid extracts of bovine oocytes and still obtain informative lipid profiling results.
    Language English
    Publishing date 2024-04-01
    Publishing country United States
    Document type Journal Article
    ZDB-ID 2276411-2
    ISSN 1933-7205 ; 1933-7191
    ISSN (online) 1933-7205
    ISSN 1933-7191
    DOI 10.1007/s43032-024-01524-9
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  3. Article: Infrapopliteal Bypass In Patients On Dialysis: Patency And Survival.

    Duarte, Armanda / Soares, Tony R / Cabral, Gonçalo / Costa, Tiago / Tiago, José / Gimenez, José / Cunha E Sá, Diogo

    Portuguese journal of cardiac thoracic and vascular surgery

    2024  Volume 31, Issue 1, Page(s) 33–39

    Abstract: Introduction: Portugal has one of the highest prevalence of patients on a regular dialysis program. This population has a higher incidence of peripheral arterial disease with higher rates of postoperative morbidity and mortality. Our goal was to compare ...

    Abstract Introduction: Portugal has one of the highest prevalence of patients on a regular dialysis program. This population has a higher incidence of peripheral arterial disease with higher rates of postoperative morbidity and mortality. Our goal was to compare outcomes between dialysis and non-dialysis patients with chronic limb threatening ischemia (CLTI) submitted to infrapopliteal bypass.
    Materials and methods: A retrospective single-center study of infrapopliteal bypass for CLTI was performed between 2012 and 2019. Patients were divided in two groups based on dialysis status (group 1 incorporated patients on dialysis). Primary end point was 1-year freedom from CLTI. Secondary end points were limb-salvage, survival and primary (PP) and tertiary patency (TP) rates at 3 years of follow-up.
    Results: A total of 352 infrapopliteal bypasses were performed in 310 patients with CLTI. Fourteen percent of the revascularizations were performed on dialysis patients (48/352). Median age was 73 years (interquartile range - IQR 15) and 74% (259/352) were male. Median follow-up was 26 months (IQR 42). Overall, 92% (325/352) had tissue loss and 44% (154/352) had some degree of infection. The majority of revascularization procedures were performed with vein grafts (61%, 214/352). The 30-day mortality was 4% (11/310), with no difference between groups (p = 0.627). Kaplan-Meier analysis showed no difference between groups regarding freedom from CLTI (76% vs. 79%; HR 0.96, CI 0.65-1.44, p=0.857), limb-salvage (70% vs. 82%; HR 1.40, CI 0.71-2.78, p=0.327) and survival (62% vs. 64%; HR 1.08, CI 0.60-1.94, p=0.799). PP rates were 39% in group 1 and 64% in group 2 (HR 1.71, CI 1.05-2.79, p=0.030). TP rates were not different between groups (57% and 78%; HR 1.79, CI 0.92-3.47, p=0.082).
    Conclusion: Infrapopliteal bypass for CLTI, on dialysis patients, resulted in lower PP rates. No differences were observed in freedom from CLTI, TP, limb salvage and survival.
    MeSH term(s) Humans ; Male ; Female ; Renal Dialysis ; Aged ; Retrospective Studies ; Vascular Patency ; Peripheral Arterial Disease/surgery ; Peripheral Arterial Disease/mortality ; Popliteal Artery/surgery ; Limb Salvage ; Portugal/epidemiology ; Middle Aged ; Aged, 80 and over ; Ischemia/mortality ; Ischemia/surgery ; Treatment Outcome ; Vascular Grafting/adverse effects ; Risk Factors
    Language English
    Publishing date 2024-05-13
    Publishing country Portugal
    Document type Journal Article
    ISSN 2184-9927
    ISSN 2184-9927
    DOI 10.48729/pjctvs.421
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  4. Article ; Online: Dataset complexity impacts both MOTU delimitation and biodiversity estimates in eukaryotic 18S rRNA metabarcoding studies

    Alejandro De Santiago / Tiago José Pereira / Sarah L. Mincks / Holly M. Bik

    Environmental DNA, Vol 4, Iss 2, Pp 363-

    2022  Volume 384

    Abstract: Abstract How does the evolution of bioinformatics tools impact the biological interpretation of high‐throughput sequencing datasets? For eukaryotic metabarcoding studies, in particular, researchers often rely on tools originally developed for the ... ...

    Abstract Abstract How does the evolution of bioinformatics tools impact the biological interpretation of high‐throughput sequencing datasets? For eukaryotic metabarcoding studies, in particular, researchers often rely on tools originally developed for the analysis of 16S ribosomal RNA (rRNA) datasets. Such tools do not adequately account for the complexity of eukaryotic genomes, the ubiquity of intragenomic variation in eukaryotic metabarcoding loci, or the differential evolutionary rates observed across eukaryotic genes and taxa. Recently, metabarcoding workflows have shifted away from the use of operational taxonomic units (OTUs) toward delimitation of amplicon sequence variants (ASVs). We assessed how the choice of bioinformatics algorithm impacts the downstream biological conclusions that are drawn from eukaryotic 18S rRNA metabarcoding studies. We focused on four workflows including UCLUST and VSearch algorithms for OTU clustering, and DADA2 and Deblur algorithms for ASV delimitation. We used two 18S rRNA datasets to further evaluate whether dataset complexity had a major impact on the statistical trends and ecological metrics: a “high complexity” (HC) environmental dataset generated from community DNA in Arctic marine sediments, and a “low complexity” (LC) dataset representing individually barcoded nematodes. Our results indicate that ASV algorithms produce more biologically realistic metabarcoding outputs, with DADA2 being the most consistent and accurate pipeline regardless of dataset complexity. In contrast, OTU clustering algorithms inflate the metabarcoding‐derived estimates of biodiversity, consistently returning a high proportion of “rare” molecular operational taxonomic units (MOTUs) that appear to represent computational artifacts and sequencing errors. However, species‐specific MOTUs with high relative abundance are often recovered regardless of the bioinformatics approach. We also found high concordance across pipelines for downstream ecological analysis based on beta‐diversity and alpha‐diversity ...
    Keywords 18S rRNA gene ; ASVs ; biodiversity ; metabarcoding ; microbial eukaryotes ; nematodes ; Environmental sciences ; GE1-350 ; Microbial ecology ; QR100-130
    Subject code 333
    Language English
    Publishing date 2022-03-01T00:00:00Z
    Publisher Wiley
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  5. Article ; Online: Evaluation of Queen Palm residues and kraft lignin in the production of biofuels using densification and slow pyrolysis technology

    van Els, Pedro Paulo Dunice / Setter, Carine / de Oliveira, Tiago José Pires

    Environ Sci Pollut Res. 2022 Dec., v. 29, no. 60 p.90011-90022

    2022  

    Abstract: This study aims to enhance the energy use of two products of industry — Queen Palm residue and kraft lignin (KF) — through the combination of two technologies — briquetting and slow pyrolysis. The addition of 20% KF provided briquettes with higher ... ...

    Abstract This study aims to enhance the energy use of two products of industry — Queen Palm residue and kraft lignin (KF) — through the combination of two technologies — briquetting and slow pyrolysis. The addition of 20% KF provided briquettes with higher physical, energy, and mechanical properties. The yields of the pyrolysis products were affected by both the pyrolysis temperature and the addition of KF. In the bio-oil, the presence of phenols, methyl phenols, and methoxy phenols was highlighted; these compounds were present in greater quantities in the treatments with KF. It is concluded that combining the briquetting and pyrolysis processes produces both energy and economic benefits because it is possible to transport lighter loads with the same amount of energy per volume. Under the briquetting conditions adopted in this study, the addition of KF as a binder is necessary because this results in briquettes with better physical, energy and mechanical properties.
    Keywords biofuels ; energy ; industry ; lignin ; pyrolysis ; temperature
    Language English
    Dates of publication 2022-12
    Size p. 90011-90022.
    Publishing place Springer Berlin Heidelberg
    Document type Article ; Online
    ZDB-ID 1178791-0
    ISSN 1614-7499 ; 0944-1344
    ISSN (online) 1614-7499
    ISSN 0944-1344
    DOI 10.1007/s11356-022-22075-z
    Database NAL-Catalogue (AGRICOLA)

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    In stock of ZB MED Bonn / Germany

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  6. Article: Briquettes of acai seeds: characterization of the biomass and influence of the parameters of production temperature and pressure in the physical-mechanical and energy quality [Erratum: February 2022, v.29(6); p.8559]

    de Oliveira, Paulo Renato Souza / Trugilho, Paulo Fernando / de Oliveira, Tiago José Pires

    Environmental science and pollution research. 2022 Feb., v. 29, no. 6

    2022  

    Abstract: Agro-industries, leveraged by the high demand of acai products, promote environmental impact through the generation of wastes in several locals in Amazon. The use with bioenergetic purposes has capacity to mitigate these scenario. Thus, the aim of the ... ...

    Abstract Agro-industries, leveraged by the high demand of acai products, promote environmental impact through the generation of wastes in several locals in Amazon. The use with bioenergetic purposes has capacity to mitigate these scenario. Thus, the aim of the study was to characterize the biomass of acai seeds and establish the technical parameters of temperature and pressure of work to the production of briquettes of physical, mechanical and thermal quality. Temperatures of 120, 140 and 160 °C; and pressures of 15, 20 and 25 MPa were studied. We analyzed the briquettes mechanical compressive strength, rate of water absorption, rate of volumetric expansion and energy and apparent density. To the characterization of in natura seeds, the proximate analysis, chemical composition (extractives, holocellulose and lignin contents), higher, lower and useful heating value were determined. The proximate analysis indicated biomass thermal resistance, potential to direct burning and conversion by thermochemical processes. The lignin content may increase briquettes compressive strength produced in high temperatures. It was observed that the temperature had more influence in the evaluated briquettes characteristics than the pressure. The compressive strength was greater in 160 °C and 15 MPa briquettes, indicating that the lignin works as binder in this temperature, however, with pressure improvement the resistance is not favored due to the limit of resistance to compaction. The rate of water absorption decreased with the pressure increase and the temperature statistically affected in 140 °C briquettes. We observed volumetric expansion values in consonance to other found in dense biofuels of the literature. Further, the apparent density and energy density were favored by pressure improvement and the temperature helped in the increase of the apparent density. Moreover, the produced briquettes presented gain in the apparent density regarding the in natura biomass and had energy density comparable to coal and adequate to co-firing in boilers.
    Keywords agricultural industry ; biofuels ; biomass ; compression strength ; energy ; energy density ; environmental impact ; heat tolerance ; lignin ; lignin content ; pollution ; polysaccharides ; proximate composition ; research ; temperature ; water uptake
    Language English
    Dates of publication 2022-02
    Size p. 8549-8558.
    Publishing place Springer Berlin Heidelberg
    Document type Article
    ZDB-ID 1178791-0
    ISSN 1614-7499 ; 0944-1344
    ISSN (online) 1614-7499
    ISSN 0944-1344
    DOI 10.1007/s11356-021-15847-6
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  7. Article ; Online: OS DETERMINANTES SOCIOECONÔMICOS DA MORTALIDADE INFANTIL NOS ANOS DE 2000 E 2010

    Tiago José Jesus da Silva

    Perspectivas Online: Humanas e Sociais Aplicadas, Vol 6, Iss

    EVIDÊNCIAS EMPÍRICAS PARA OS MUNICÍPIOS PERNAMBUCANOS

    2016  Volume 17

    Abstract: Este artigo se propõe a desenvolver uma análise empírica dos determinantes socioeconômicos da Taxa de Mortalidade Infantil nos municípios pernambucanos, entre os anos de 2000 e 2010, utilizando os dados do atlas de desenvolvimento humano da PNUD e da ... ...

    Abstract Este artigo se propõe a desenvolver uma análise empírica dos determinantes socioeconômicos da Taxa de Mortalidade Infantil nos municípios pernambucanos, entre os anos de 2000 e 2010, utilizando os dados do atlas de desenvolvimento humano da PNUD e da Secretaria do Tesouro Nacional. Para realizar esse estudo, utilizou-se de um modelo de dados em painel, onde foram utilizadas como variáveis explicativas o percentual de crianças vulneráveis a pobreza, o percentual de crianças em domicílios em que ninguém tem ensino fundamental completo, taxa de fecundidade total, o percentual de domicílios com coleta de lixo, o percentual de domicílios com banheiro e água encanada e o gasto municipal com saúde por habitante. De acordo com os resultados obtidos verificou-se que todas as variáveis foram significantes estatisticamente e apresentaram sinais esperados de acordo com o preconiza a literatura que estuda o tema. Em suma, diante dos resultados analisados as variáveis relacionadas à pobreza, educação, demografia, gastos com saúde, e saneamento básico são de grande importância para explicar a taxa de mortalidade infantil nessas localidades, devendo, pois ser alvo de políticas públicas, afim de que se possa mitigar esse problema social e de saúde pública.
    Keywords Social Sciences ; H
    Language English
    Publishing date 2016-12-01T00:00:00Z
    Publisher Institutos Superiores de Ensino do CENSA
    Document type Article ; Online
    Database BASE - Bielefeld Academic Search Engine (life sciences selection)

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  8. Article: Effect of lipid extraction and room temperature transportation of bovine oocytes determined by MRM profiling.

    de Lima, Camila Bruna / Milazzotto, Marcella Pecora / Vireque, Alessandra Aparecida / Joaquim, Daniel Carlino / Sobreira, Tiago Jose Paschoal / Ferreira, Christina Ramires

    Research square

    2023  

    Abstract: Lipids play many important physiological roles in mammalian reproduction, being essential for the acquisition of oocyte competence and post-fertilization embryonic development. Lipid profiling in samples of minute size, such as oocytes, is challenging ... ...

    Abstract Lipids play many important physiological roles in mammalian reproduction, being essential for the acquisition of oocyte competence and post-fertilization embryonic development. Lipid profiling in samples of minute size, such as oocytes, is challenging but has been achieved by mass spectrometry technologies such as multiple reaction monitoring (MRM) profiling. With the goals of further simplifying sample workflow and investigating the influence of pre-analytical conditions, we have evaluated how different extraction methods and transportation of lipid extracts in vacuum and at room temperature impacted the lipid profile of bovine oocytes. Using a comprehensive method, 316 MRMs associated with lipids of 10 different classes were screened in oocyte lipid extracts prepared by 2 extraction methods (one-step methanol addition or Bligh and Dyer) and transporting them in dry ice or at room temperature inside vacuum packages. No changes in the multivariate analysis (PCA) were noticeable due to transportation temperature, while lipid profiles were more affected by the lipid extraction protocol. Sample extraction using pure methanol favored the detection of phospholipids uniformly, while Bligh and Dyer favored the detection of neutral intracellular lipids. Triacylglycerol lipids and free fatty acids yielded decreased abundances when samples were transported at room temperature. We conclude that if samples are submitted to the same lipid extraction protocol and same transportation batch at room temperature coupled with vacuum conditions it is possible to analyze lipid extracts of bovine oocytes and still obtain informative lipid profiling results.
    Language English
    Publishing date 2023-12-23
    Publishing country United States
    Document type Preprint
    DOI 10.21203/rs.3.rs-3788683/v1
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  9. Article: An Epithelioid Hemangioma Camouflaged As Radial Aneurysm.

    Ferreira, José / Tiago, José / Gerardo, Gonçalo / Soares, Tony / Cabral, Gonçalo / Costa, Tiago / Rossello, José / Cunha E Sá, Diogo / Gonçalo, Gerardo

    Portuguese journal of cardiac thoracic and vascular surgery

    2023  Volume 30, Issue 1, Page(s) 61–63

    Abstract: Epithelioid hemangioma (EH) is an uncommon benign vascular lesion usually present as subcutaneous nodules in the head and neck area. Sometimes, these lesions can occur in the peripheral arteries, and when they do, they can be mistaken for aneurysmal ... ...

    Abstract Epithelioid hemangioma (EH) is an uncommon benign vascular lesion usually present as subcutaneous nodules in the head and neck area. Sometimes, these lesions can occur in the peripheral arteries, and when they do, they can be mistaken for aneurysmal dilatations of that respective vessel. We report a case of a 43-year-old male who underwent surgical recession of a radial aneurysm, which after anatomopathological examination, revealed an EH.
    MeSH term(s) Male ; Humans ; Adult ; Hemangioma/diagnosis ; Aneurysm/diagnosis ; Arteries/pathology ; Head/pathology ; Neck/pathology
    Language English
    Publishing date 2023-04-04
    Publishing country Portugal
    Document type Case Reports ; Journal Article
    ISSN 2184-9927
    ISSN 2184-9927
    DOI 10.48729/pjctvs.236
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Biogas production from malt bagasse from craft beer industry: kinetic modeling and process simulation.

    Tschoeke, Isabelle Cristine Prohmann / Fraga, Tiago José Marques / da Silva, Maryne Patrícia / Costa E Souza, Thibério Pinho / Chinelate, Gerla Castello Branco

    Journal of material cycles and waste management

    2023  , Page(s) 1–13

    Abstract: In this work, biogas was synthesized from malt enriched-craft beer bagasse with the objective to generate clean energy. Thus, a kinetic model based on thermodynamic parameters was proposed to represent the process with coefficient determination (: ... ...

    Abstract In this work, biogas was synthesized from malt enriched-craft beer bagasse with the objective to generate clean energy. Thus, a kinetic model based on thermodynamic parameters was proposed to represent the process with coefficient determination (
    Supplementary information: The online version contains supplementary material available at 10.1007/s10163-023-01715-7.
    Language English
    Publishing date 2023-06-09
    Publishing country Japan
    Document type Journal Article
    ZDB-ID 2110671-X
    ISSN 1611-8227 ; 1438-4957
    ISSN (online) 1611-8227
    ISSN 1438-4957
    DOI 10.1007/s10163-023-01715-7
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