Article ; Online: Highly Accurate Synthesis of Quasi-sub-nanoparticles by Dendron-assembled Supramolecular Templates.
Angewandte Chemie (International ed. in English)
2022 Volume 61, Issue 8, Page(s) e202114353
Abstract: Quasi-sub-nanomaterials (1-3 nm) have been predicted to exhibit unique properties originating from the gray structures considered both bulk solids and molecules, while their synthesis is extremely difficult. The present study describes a new template ... ...
| Abstract | Quasi-sub-nanomaterials (1-3 nm) have been predicted to exhibit unique properties originating from the gray structures considered both bulk solids and molecules, while their synthesis is extremely difficult. The present study describes a new template synthesis method for quasi-sub-nanosized materials using a combination of coordination chemistry and polymer chemistry. Utilizing self-assembly of guest basic phenylazomethine dendron units onto host acidic core units with six tritylium cations, the dendron-assembled supramolecules were constructed easily and quantitatively without costly techniques. This huge supramolecular capsule accumulating multiple acidic rhodium salts in its basic ligands enabled a precise synthesis of rhodium particles via formation of multinuclear complexes. The obtained particles (Rh |
|---|---|
| Language | English |
| Publishing date | 2022-01-27 |
| Publishing country | Germany |
| Document type | Journal Article |
| ZDB-ID | 2011836-3 |
| ISSN | 1521-3773 ; 1433-7851 |
| ISSN (online) | 1521-3773 |
| ISSN | 1433-7851 |
| DOI | 10.1002/anie.202114353 |
| Database | MEDical Literature Analysis and Retrieval System OnLINE |
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