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  1. AU="Vane, Christopher H"
  2. AU="Mabbott, Donald"
  3. AU="Martín-Trejo, Jorge Alfonso"
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  1. Article ; Online: Detecting tropical peatland degradation: Combining remote sensing and organic geochemistry.

    Brown, Chloe / Boyd, Doreen S / Sjögersten, Sofie / Vane, Christopher H

    PloS one

    2023  Volume 18, Issue 3, Page(s) e0280187

    Abstract: Tropical peatlands are important carbon stores that are vulnerable to drainage and conversion to agriculture. Protection and restoration of peatlands are increasingly recognised as key nature based solutions that can be implemented as part of climate ... ...

    Abstract Tropical peatlands are important carbon stores that are vulnerable to drainage and conversion to agriculture. Protection and restoration of peatlands are increasingly recognised as key nature based solutions that can be implemented as part of climate change mitigation. Identification of peatland areas that are important for protection and restauration with regards to the state of their carbon stocks, are therefore vital for policy makers. In this paper we combined organic geochemical analysis by Rock-Eval (6) pyrolysis of peat collected from sites with different land management history and optical remote sensing products to assess if remotely sensed data could be used to predict peat conditions and carbon storage. The study used the North Selangor Peat Swamp forest, Malaysia, as the model system. Across the sampling sites the carbon stocks in the below ground peat was ca 12 times higher than the forest (median carbon stock held in ground vegetation 114.70 Mg ha-1 and peat soil 1401.51 Mg ha-1). Peat core sub-samples and litter collected from Fire Affected, Disturbed Forest, and Managed Recovery locations (i.e. disturbed sites) had different decomposition profiles than Central Forest sites. The Rock-Eval pyrolysis of the upper peat profiles showed that surface peat layers at Fire Affected, Disturbed Forest, and Managed Recovery locations had lower immature organic matter index (I-index) values (average I-index range in upper section 0.15 to -0.06) and higher refractory organic matter index (R -index) (average R-index range in upper section 0.51 to 0.65) compared to Central Forest sites indicating enhanced decomposition of the surface peat. In the top 50 cm section of the peat profile, carbon stocks were negatively related to the normalised burns ratio (NBR) (a satellite derived parameter) (Spearman's rho = -0.664, S = 366, p-value = <0.05) while there was a positive relationship between the hydrogen index and the normalised burns ratio profile (Spearman's rho = 0.7, S = 66, p-value = <0.05) suggesting that this remotely sensed product is able to detect degradation of peat in the upper peat profile. We conclude that the NBR can be used to identify degraded peatland areas and to support identification of areas for conversation and restoration.
    MeSH term(s) Remote Sensing Technology ; Forests ; Wetlands ; Carbon/analysis ; Soil/chemistry
    Chemical Substances Carbon (7440-44-0) ; Soil
    Language English
    Publishing date 2023-03-29
    Publishing country United States
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2267670-3
    ISSN 1932-6203 ; 1932-6203
    ISSN (online) 1932-6203
    ISSN 1932-6203
    DOI 10.1371/journal.pone.0280187
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: X-ray computed tomography: A novel non-invasive approach for the detection of microplastics in sediments?

    Trusler, Megan M. / Sturrock, Craig J. / Vane, Christopher H. / Cook, Sarah / Lomax, Barry H.

    Marine Pollution Bulletin. 2023 Sept., v. 194 p.115350-

    2023  

    Abstract: As a non-invasive imaging technique, this study explores the application of Computed Tomography (CT) in microplastics research, assessing its potential to distinguish different types and sizes of microplastics (polypropylene, polyethylene terephthalate, ... ...

    Abstract As a non-invasive imaging technique, this study explores the application of Computed Tomography (CT) in microplastics research, assessing its potential to distinguish different types and sizes of microplastics (polypropylene, polyethylene terephthalate, polyethylene, and polyvinyl chloride) from homogenised river-estuarine sediment. When examined in layers within artificial cores, all microplastic types could be observed by CT imagery, with good contrast in X-ray attenuation (based on image gray level intensity) against background sediments. Large microplastics (4 mm diameter) were also detectable when distributed randomly amongst the sediment. These spiked cores had sufficient difference in attenuation to allow segmentation between type, and therefore isolate individual microplastics. Due to limitations on scan resolution, smaller microplastics (≤125 μm diameter) could not be detected in spiked cores. Scans of two sediment cores from a Thames River tributary (UK) revealed two distinctive sediment structures which could influence microplastic accumulation. This information would be lost using conventional recovery procedures.
    Keywords X-radiation ; computed tomography ; marine pollution ; microplastics ; poly(vinyl chloride) ; polyethylene ; polyethylene terephthalates ; polypropylenes ; rivers ; sediments ; Particle imaging ; Plastic polymer ; Sediment core ; Microplastic pollution ; Image analysis ; River Thames
    Language English
    Dates of publication 2023-09
    Publishing place Elsevier Ltd
    Document type Article ; Online
    ZDB-ID 2001296-2
    ISSN 1879-3363 ; 0025-326X
    ISSN (online) 1879-3363
    ISSN 0025-326X
    DOI 10.1016/j.marpolbul.2023.115350
    Database NAL-Catalogue (AGRICOLA)

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  3. Article ; Online: Dermal absorption of high molecular weight parent and alkylated polycyclic aromatic hydrocarbons from manufactured gas plant soils using in vitro assessment.

    Williams-Clayson, Alison M / Vane, Christopher H / Jones, Matthew D / Thomas, Russell / Taylor, Christopher / Beriro, Darren J

    Journal of hazardous materials

    2024  Volume 469, Page(s) 133858

    Abstract: An enhanced in vitro human dermal bioavailability method was developed to measure the release of twenty parent and seven alkylated high molecular weight (HMW) polycyclic aromatic hydrocarbons (PAHs) from contaminated soils collected from five former ... ...

    Abstract An enhanced in vitro human dermal bioavailability method was developed to measure the release of twenty parent and seven alkylated high molecular weight (HMW) polycyclic aromatic hydrocarbons (PAHs) from contaminated soils collected from five former manufactured Gas Plants (MGP) in England. GC-MS/MS was used to quantify HMW PAHs in soil, Strat-M artificial membrane representing skin, and synthetic receptor solution (RS) representing systemic circulation at 1-h, 10-h, and 24-h timesteps. Fluoranthene and pyrene exhibited the highest fluxes from soils to membrane (ranging from 9.5 - 281 ng/cm
    MeSH term(s) Humans ; Polycyclic Aromatic Hydrocarbons/analysis ; Soil ; Tandem Mass Spectrometry ; Molecular Weight ; Soil Pollutants/analysis ; Pyrenes ; Environmental Monitoring/methods ; Fluorenes
    Chemical Substances Polycyclic Aromatic Hydrocarbons ; fluoranthene (360UOL779Z) ; Soil ; Soil Pollutants ; pyrene (9E0T7WFW93) ; Pyrenes ; Fluorenes
    Language English
    Publishing date 2024-02-22
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 1491302-1
    ISSN 1873-3336 ; 0304-3894
    ISSN (online) 1873-3336
    ISSN 0304-3894
    DOI 10.1016/j.jhazmat.2024.133858
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: Tracking the history of polycyclic aromatic compounds in London through a River Thames sediment core and ultrahigh resolution mass spectrometry.

    Downham, Rory P / Gannon, Benedict / Lozano, Diana Catalina Palacio / Jones, Hugh E / Vane, Christopher H / Barrow, Mark P

    Journal of hazardous materials

    2024  Volume 473, Page(s) 134605

    Abstract: Polycyclic aromatic compounds (PACs), including polycyclic aromatic hydrocarbons (PAHs) and heteroatom-containing analogues, constitute an important environmental contaminant class. For decades, limited numbers of priority PAHs have been routinely ... ...

    Abstract Polycyclic aromatic compounds (PACs), including polycyclic aromatic hydrocarbons (PAHs) and heteroatom-containing analogues, constitute an important environmental contaminant class. For decades, limited numbers of priority PAHs have been routinely targeted in pollution investigations, however, there is growing awareness for the potential occurrence of thousands of PACs in the environment. In this study, untargeted Fourier transform ion cyclotron resonance mass spectrometry was used for the molecular characterisation of PACs in a sediment core from Chiswick Ait, in the River Thames, London, UK. Using complex mixture analysis approaches, including aromaticity index calculations, the number of molecular PAC components was determined for eight core depths, extending back to the 1930s. A maximum of 1676 molecular compositions representing PACs was detected at the depth corresponding to the 1950s, and a decline in PAC numbers was observed up the core. A case linking the PACs to London's coal consumption history is presented, alongside other possible sources, with some data features indicating pyrogenic origins. The overall core profile trend in PAC components, including compounds with oxygen, sulfur, nitrogen, and chlorine atoms, is shown to broadly correspond to the 16 priority PAH concentration profile trend previously determined for this core. These findings have implications for other industry-impacted environments.
    Language English
    Publishing date 2024-05-14
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 1491302-1
    ISSN 1873-3336 ; 0304-3894
    ISSN (online) 1873-3336
    ISSN 0304-3894
    DOI 10.1016/j.jhazmat.2024.134605
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: X-ray computed tomography: A novel non-invasive approach for the detection of microplastics in sediments?

    Trusler, Megan M / Sturrock, Craig J / Vane, Christopher H / Cook, Sarah / Lomax, Barry H

    Marine pollution bulletin

    2023  Volume 194, Issue Pt A, Page(s) 115350

    Abstract: As a non-invasive imaging technique, this study explores the application of Computed Tomography (CT) in microplastics research, assessing its potential to distinguish different types and sizes of microplastics (polypropylene, polyethylene terephthalate, ... ...

    Abstract As a non-invasive imaging technique, this study explores the application of Computed Tomography (CT) in microplastics research, assessing its potential to distinguish different types and sizes of microplastics (polypropylene, polyethylene terephthalate, polyethylene, and polyvinyl chloride) from homogenised river-estuarine sediment. When examined in layers within artificial cores, all microplastic types could be observed by CT imagery, with good contrast in X-ray attenuation (based on image gray level intensity) against background sediments. Large microplastics (4 mm diameter) were also detectable when distributed randomly amongst the sediment. These spiked cores had sufficient difference in attenuation to allow segmentation between type, and therefore isolate individual microplastics. Due to limitations on scan resolution, smaller microplastics (≤125 μm diameter) could not be detected in spiked cores. Scans of two sediment cores from a Thames River tributary (UK) revealed two distinctive sediment structures which could influence microplastic accumulation. This information would be lost using conventional recovery procedures.
    MeSH term(s) Microplastics ; Plastics/chemistry ; Water Pollutants, Chemical/analysis ; Environmental Monitoring/methods ; Geologic Sediments/chemistry ; Tomography, X-Ray Computed
    Chemical Substances Microplastics ; Plastics ; Water Pollutants, Chemical
    Language English
    Publishing date 2023-08-08
    Publishing country England
    Document type Journal Article
    ZDB-ID 2001296-2
    ISSN 1879-3363 ; 0025-326X
    ISSN (online) 1879-3363
    ISSN 0025-326X
    DOI 10.1016/j.marpolbul.2023.115350
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Contrasting sewage, emerging and persistent organic pollutants in sediment cores from the River Thames estuary, London, England, UK

    Vane, Christopher H. / Kim, Alexander W. / Lopes dos Santos, Raquel A. / Moss-Hayes, Vicky

    Marine Pollution Bulletin. 2022 Feb., v. 175 p.113340-

    2022  

    Abstract: Sedimentary organic pollution in the urban reaches of the Thames estuary is changing from fossil fuel hydrocarbons to emerging synthetic chemicals. De-industrialisation of London was assessed in three cores from Chiswick (Ait/Eyot) mud island using ... ...

    Abstract Sedimentary organic pollution in the urban reaches of the Thames estuary is changing from fossil fuel hydrocarbons to emerging synthetic chemicals. De-industrialisation of London was assessed in three cores from Chiswick (Ait/Eyot) mud island using pharmaceuticals, faecal sterols, hydrocarbons (TPH, PAH), Black Carbon (BC) and organotins (TBT). These ranked in the order; BC 7590-30219 mg/kg, mean 16,000 mg/kg > TPH 770-4301, mean 1316 mg/kg > Σ¹⁶PAH 6.93-107.64, mean 36.46 mg/kg > coprostanol 0.0091-0.42 mg/kg, mean of 0.146 mg/kg > pharmaceuticals 2.4-84.8 μg/kg, mean 25 μg/kg. Hydrocarbons co-varied down-profile revealing rise (1940s), peak (1950s -1960s) and fall (1980s) and an overall 3 to 25-fold decrease. In contrast, antibiotics, anti-inflammatory (ibuprofen, paracetamol) and hormone (17β-estradiol) increased 3 to 50-fold toward surface paralleling increasing use (1970s-2018). The anti-epileptics, carbamazepine and epoxcarbamazepine showed appreciable down-core mobility. Faecal sterols confirmed non-systematic incorporation of treated sewage. Comparison to UK sediment quality guidelines indicate exceedance of AL2 for PAH whereas TBT was below AL1.
    Keywords acetaminophen ; carbon ; coprostanol ; estuaries ; fossil fuels ; ibuprofen ; marine pollution ; organotin compounds ; rivers ; sediments ; sewage ; sewage treatment ; England ; Anthropocene ; Contamination ; Pharmaceuticals ; Black carbon (BC) ; Polycyclic aromatic hydrocarbons (PAH) ; Petroleum hydrocarbons (TPH)
    Language English
    Dates of publication 2022-02
    Publishing place Elsevier Ltd
    Document type Article ; Online
    Note Use and reproduction
    ZDB-ID 2001296-2
    ISSN 1879-3363 ; 0025-326X
    ISSN (online) 1879-3363
    ISSN 0025-326X
    DOI 10.1016/j.marpolbul.2022.113340
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  7. Article ; Online: Contrasting sewage, emerging and persistent organic pollutants in sediment cores from the River Thames estuary, London, England, UK.

    Vane, Christopher H / Kim, Alexander W / Lopes Dos Santos, Raquel A / Moss-Hayes, Vicky

    Marine pollution bulletin

    2022  Volume 175, Page(s) 113340

    Abstract: Sedimentary organic pollution in the urban reaches of the Thames estuary is changing from fossil fuel hydrocarbons to emerging synthetic chemicals. De-industrialisation of London was assessed in three cores from Chiswick (Ait/Eyot) mud island using ... ...

    Abstract Sedimentary organic pollution in the urban reaches of the Thames estuary is changing from fossil fuel hydrocarbons to emerging synthetic chemicals. De-industrialisation of London was assessed in three cores from Chiswick (Ait/Eyot) mud island using pharmaceuticals, faecal sterols, hydrocarbons (TPH, PAH), Black Carbon (BC) and organotins (TBT). These ranked in the order; BC 7590-30219 mg/kg, mean 16,000 mg/kg > TPH 770-4301, mean 1316 mg/kg >
    MeSH term(s) Environmental Monitoring ; Estuaries ; Geologic Sediments ; London ; Persistent Organic Pollutants ; Polycyclic Aromatic Hydrocarbons/analysis ; Rivers ; Sewage/analysis ; Water Pollutants, Chemical/analysis
    Chemical Substances Polycyclic Aromatic Hydrocarbons ; Sewage ; Water Pollutants, Chemical
    Language English
    Publishing date 2022-02-03
    Publishing country England
    Document type Journal Article
    ZDB-ID 2001296-2
    ISSN 1879-3363 ; 0025-326X
    ISSN (online) 1879-3363
    ISSN 0025-326X
    DOI 10.1016/j.marpolbul.2022.113340
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Characterisation of former manufactured gas plant soils using parent and alkylated polycyclic aromatic hydrocarbons and Rock-Eval(6) pyrolysis.

    Williams-Clayson, Alison M / Vane, Christopher H / Jones, Matthew D / Thomas, Russell / Kim, Alexander W / Taylor, Christopher / Beriro, Darren J

    Environmental pollution (Barking, Essex : 1987)

    2023  Volume 339, Page(s) 122658

    Abstract: Soils sampled from 10 former manufactured gas plants (MGP) in the UK were investigated using gas chromatography mass spectrometry (GC-MS/MS) and Rock-Eval (6) Pyrolysis (RE). RE is a screening tool used to characterise bulk organic matter in soils via ... ...

    Abstract Soils sampled from 10 former manufactured gas plants (MGP) in the UK were investigated using gas chromatography mass spectrometry (GC-MS/MS) and Rock-Eval (6) Pyrolysis (RE). RE is a screening tool used to characterise bulk organic matter in soils via the release of carbon compounds during pyrolysis and oxidation. Both the distributions and concentrations of 30 parent and 21 alkylated polycyclic aromatic hydrocarbons (PAHs) and the parameters of RE were analysed to establish relationships between soils and the MGP processes history. Principal component analysis (PCA) using the PAHs distributions and RE parameters can assist with differentiating between MGP processes. MGP processes utilizing oil provided the clearest results, attributed to petrogenic signatures with high proportions of low molecular weight PAHs. Processes using lower temperature processes were distinguished by higher proportions of high molecular weight PAHs. RE parameters alone were unable to distinguish MGP processes but showed potential in estimating the lability and thus the amount of PAH that could be released from soils. This research provides new insights that may be useful in understanding and characterising the risks posed to human health from PAHs in soils.
    MeSH term(s) Humans ; Polycyclic Aromatic Hydrocarbons/analysis ; Soil/chemistry ; Pyrolysis ; Tandem Mass Spectrometry ; Soil Pollutants/analysis ; Environmental Monitoring/methods
    Chemical Substances Polycyclic Aromatic Hydrocarbons ; Soil ; Soil Pollutants
    Language English
    Publishing date 2023-09-29
    Publishing country England
    Document type Journal Article
    ZDB-ID 280652-6
    ISSN 1873-6424 ; 0013-9327 ; 0269-7491
    ISSN (online) 1873-6424
    ISSN 0013-9327 ; 0269-7491
    DOI 10.1016/j.envpol.2023.122658
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article: Molecular and bulk geochemical proxies in sediments from the Conwy Estuary, UK

    Lopes dos Santos, Raquel A / Vane, Christopher H

    Organic geochemistry. 2020 Dec., v. 150

    2020  

    Abstract: Owing to their restricted riverine flow and greater numbers, small estuaries (annual discharge < 2000 m³ s⁻¹) are important sites of organic carbon (OC) storage in sediments. The Conwy Estuary is an exemplar small rural-agricultural catchment which ... ...

    Abstract Owing to their restricted riverine flow and greater numbers, small estuaries (annual discharge < 2000 m³ s⁻¹) are important sites of organic carbon (OC) storage in sediments. The Conwy Estuary is an exemplar small rural-agricultural catchment which delivers a diverse pool of terrestrial OC to the Irish Sea. Thirty-nine surface sediments, covering a distance of 10.5 km, were taken transversal as well as longitudinal to the estuary to examine local and distant catchment inputs. Biomarkers (branched Glycerol Dialkyl Glycerol Tetraethers - brGDGTs, n-alkanes) and molecular and bulk proxies (BIT, Pₐq, TAR, δ¹³C, C/N), showed sediments were dominated by terrestrial inputs, with only sediments of the three most seaward sites showing stronger physical and geochemical characteristics of a marine influence (e.g., sandier sediments and lower BIT). Biomarker concentrations in the Conwy were comparable to the more urbanised Thames and the Clyde estuaries. The three estuaries showed similar fractional abundance of the brGDGTs, recording an inverse trend between the hexamethylated and the tetramethylated brGDGTs, and showing the pentamethylated brGDGTs as the dominant group. A systematic decrease in terrestrial biomarkers from bank to the main channel confirmed either a strong localised erosion/runoff process or a decrease in water velocity leading to a higher deposition.
    Keywords alkanes ; biomarkers ; estuaries ; geochemistry ; glycerol ; organic carbon ; riparian areas ; runoff ; urbanization ; watersheds ; Irish Sea
    Language English
    Dates of publication 2020-12
    Publishing place Elsevier Ltd
    Document type Article
    Note NAL-AP-2-clean
    ISSN 0146-6380
    DOI 10.1016/j.orggeochem.2020.104119
    Database NAL-Catalogue (AGRICOLA)

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  10. Article ; Online: Distribution and speciation of phosphorus in foreshore sediments of the Thames estuary, UK.

    Tye, Andrew M / Rushton, Jeremy / Vane, Christopher H

    Marine pollution bulletin

    2018  Volume 127, Page(s) 182–197

    Abstract: Estuarine sediments can be a source of Phosphorus (P) to coastal waters, contributing to nutrient budgets and geochemical cycles. In this work, the concentration and speciation of P in 47 cores were examined from the inter-tidal mud flats of the tidal ... ...

    Abstract Estuarine sediments can be a source of Phosphorus (P) to coastal waters, contributing to nutrient budgets and geochemical cycles. In this work, the concentration and speciation of P in 47 cores were examined from the inter-tidal mud flats of the tidal river Thames (~120km). Results of P concentration and speciation were combined with published data relating to known sediment dynamics and water chemistry (salinity) within the estuary to produce a conceptual model of sediment-P behaviour. Results demonstrated significant P desorption occurring after sediment passed through the Estuarine Turbidity Maximum and when the salinity of the river water exceeded ~6ppt. It was found that organic P was desorbed to a greater extent than inorganic P in the lower estuary. Models were used to identify those geochemical parameters that contributed to the Total P (R
    MeSH term(s) Environmental Monitoring ; Estuaries ; Geologic Sediments/analysis ; Phosphorus/analysis ; Rivers ; Salinity ; United Kingdom ; Water Pollutants, Chemical/analysis
    Chemical Substances Water Pollutants, Chemical ; Phosphorus (27YLU75U4W)
    Language English
    Publishing date 2018-02
    Publishing country England
    Document type Journal Article
    ZDB-ID 2001296-2
    ISSN 1879-3363 ; 0025-326X
    ISSN (online) 1879-3363
    ISSN 0025-326X
    DOI 10.1016/j.marpolbul.2017.11.044
    Database MEDical Literature Analysis and Retrieval System OnLINE

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