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  1. Article ; Online: Monitoring the Simultaneous Implantation of Ti and Tb Cations to a Sacrificial Template and the Sol-Gel Synthesis of Tb-Doped TiO

    Colomer, María Teresa / Vattier, Florencia

    International journal of molecular sciences

    2022  Volume 23, Issue 21

    Abstract: ... Tb-doped ... ...

    Abstract Tb-doped TiO
    MeSH term(s) Titanium/chemistry ; Catalysis ; Cations ; Water
    Chemical Substances titanium dioxide (15FIX9V2JP) ; Titanium (D1JT611TNE) ; Cations ; Water (059QF0KO0R)
    Language English
    Publishing date 2022-10-29
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2019364-6
    ISSN 1422-0067 ; 1422-0067 ; 1661-6596
    ISSN (online) 1422-0067
    ISSN 1422-0067 ; 1661-6596
    DOI 10.3390/ijms232113162
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Ruthenium nanoparticles stabilized by 1,2,3-triazolylidene ligands in the hydrogen isotope exchange of E-H bonds (E = B, Si, Ge, Sn) using deuterium gas.

    Molinillo, Pablo / Puyo, Maxime / Vattier, Florencia / Lacroix, Bertrand / Rendón, Nuria / Lara, Patricia / Suárez, Andrés

    Nanoscale

    2023  Volume 15, Issue 35, Page(s) 14488–14495

    Abstract: A series of ruthenium nanoparticles (Ru·MIC) stabilized with different mesoionic 1,2,3-triazolylidene (MIC) ligands were prepared by decomposition of the Ru(COD)(COT) (COD = 1,5-cyclooctadiene; COT = 1,3,5-cyclooctatriene) precursor with ... ...

    Abstract A series of ruthenium nanoparticles (Ru·MIC) stabilized with different mesoionic 1,2,3-triazolylidene (MIC) ligands were prepared by decomposition of the Ru(COD)(COT) (COD = 1,5-cyclooctadiene; COT = 1,3,5-cyclooctatriene) precursor with H
    Language English
    Publishing date 2023-09-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 2515664-0
    ISSN 2040-3372 ; 2040-3364
    ISSN (online) 2040-3372
    ISSN 2040-3364
    DOI 10.1039/d3nr02637j
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Reduction of N₂O with hydrosilanes catalysed by RuSNS nanoparticles

    Molinillo, Pablo / Lacroix, Bertrand / Vattier, Florencia / Rendón, Nuria / Suárez, Andrés / Lara, Patricia

    Chemical communications. 2022 June 23, v. 58, no. 51

    2022  

    Abstract: A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with H₂ in the presence of an SNS ligand, have been found to catalyse the reduction of the greenhouse gas N₂O to N₂ employing different hydrosilanes. ...

    Abstract A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with H₂ in the presence of an SNS ligand, have been found to catalyse the reduction of the greenhouse gas N₂O to N₂ employing different hydrosilanes.
    Keywords chemical communication ; greenhouse gases ; ligands ; nanoparticles
    Language English
    Dates of publication 2022-0623
    Size p. 7176-7179.
    Publishing place The Royal Society of Chemistry
    Document type Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc01470j
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  4. Article ; Online: Reduction of N

    Molinillo, Pablo / Lacroix, Bertrand / Vattier, Florencia / Rendón, Nuria / Suárez, Andrés / Lara, Patricia

    Chemical communications (Cambridge, England)

    2022  Volume 58, Issue 51, Page(s) 7176–7179

    Abstract: A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with ... ...

    Abstract A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with H
    Language English
    Publishing date 2022-06-23
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d2cc01470j
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Platinum nanoparticles stabilized by N-heterocyclic thiones. Synthesis and catalytic activity in mono- and di-hydroboration of alkynes.

    Moraes, Leonardo C / Figueiredo, Rute C / Espinós, Juan P / Vattier, Florencia / Franconetti, Antonio / Jaime, Carlos / Lacroix, Bertrand / Rojo, Javier / Lara, Patricia / Conejero, Salvador

    Nanoscale

    2020  Volume 12, Issue 12, Page(s) 6821–6831

    Abstract: N-Heterocyclic Thiones (NHT) proved to be efficient ligands for the stabilization of small platinum nanoparticles (1.3-1.7 nm), synthesized by decomposition of [Pt(dba) ...

    Abstract N-Heterocyclic Thiones (NHT) proved to be efficient ligands for the stabilization of small platinum nanoparticles (1.3-1.7 nm), synthesized by decomposition of [Pt(dba)
    Language English
    Publishing date 2020-03-17
    Publishing country England
    Document type Journal Article
    ZDB-ID 2515664-0
    ISSN 2040-3372 ; 2040-3364
    ISSN (online) 2040-3372
    ISSN 2040-3364
    DOI 10.1039/d0nr00251h
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: A Diels-Alder reaction triggered by a [4 + 3] metallacycloaddition.

    Vivancos, Ángela / Vattier, Florencia / López-Serrano, Joaquín / Paneque, Margarita / Poveda, Manuel L / Álvarez, Eleuterio

    Journal of the American Chemical Society

    2015  Volume 137, Issue 12, Page(s) 4074–4077

    Abstract: The Tp(Me2)Ir(III) complex 1-OH2 (Tp(Me2) = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water and an iridium-bonded alkenyl moiety (-C(R)═C(R)-(R=CO2Me)) as part of a benzo-annulated five-membered iridacycle, reacts ... ...

    Abstract The Tp(Me2)Ir(III) complex 1-OH2 (Tp(Me2) = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water and an iridium-bonded alkenyl moiety (-C(R)═C(R)-(R=CO2Me)) as part of a benzo-annulated five-membered iridacycle, reacts readily with the conjugated dienes butadiene and 2,3-dimethylbutadiene to afford the corresponding Diels-Alder products. Experimental and DFT studies are in accordance with an initial [4 + 3] cyclometalation reaction between the diene and the five-coordinated 16-electron organometallic fragment 1 (generated from 1-OH2 by facile water dissociation). The reaction can be extended to a related TpIr(III) complex (Tp = hydrotris(pyrazolyl)borate) that also features a labile ligand (i.e., 2-THF).
    Language English
    Publishing date 2015-04-01
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.5b01532
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article: A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition

    Vivancos, Ángela / Álvarez Eleuterio / López-Serrano Joaquín / Paneque Margarita / Poveda Manuel L / Vattier Florencia

    Journal of the American Chemical Society. 2015 Apr. 01, v. 137, no. 12

    2015  

    Abstract: The Tpᴹᵉ²Ir(III) complex 1-OH₂ (Tpᴹᵉ² = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water and an iridium-bonded alkenyl moiety (−C(R)C(R)–(R=CO₂Me)) as part of a benzo-annulated five-membered ... ...

    Abstract The Tpᴹᵉ²Ir(III) complex 1-OH₂ (Tpᴹᵉ² = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water and an iridium-bonded alkenyl moiety (−C(R)C(R)–(R=CO₂Me)) as part of a benzo-annulated five-membered iridacycle, reacts readily with the conjugated dienes butadiene and 2,3-dimethylbutadiene to afford the corresponding Diels–Alder products. Experimental and DFT studies are in accordance with an initial [4 + 3] cyclometalation reaction between the diene and the five-coordinated 16-electron organometallic fragment 1 (generated from 1-OH₂ by facile water dissociation). The reaction can be extended to a related TpIr(III) complex (Tp = hydrotris(pyrazolyl)borate) that also features a labile ligand (i.e., 2-THF).
    Keywords borates ; cycloaddition reactions ; dissociation ; ligands
    Language English
    Dates of publication 2015-0401
    Size p. 4074-4077.
    Publishing place American Chemical Society
    Document type Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021%2Fjacs.5b01532
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    In stock of ZB MED Bonn / Germany

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  8. Article: Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2′′-terpyridine

    Paneque, Margarita / Alvarez, Eleuterio / Carmona, Ernesto / Poveda, Manuel L / Vattier, Florencia

    Chemical communications. 2009 Sept. 15, , no. 37

    2009  

    Abstract: Thermal activation of terpyridine in the presence of an unsaturated Ir(iii) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a ... ...

    Abstract Thermal activation of terpyridine in the presence of an unsaturated Ir(iii) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.
    Keywords borates ; carbenes ; chemical communication ; chemical reactions ; heterocyclic nitrogen compounds ; iridium ; ligands
    Language English
    Dates of publication 2009-0915
    Size p. 5561-5563.
    Publishing place The Royal Society of Chemistry
    Document type Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/b909837b
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  9. Article ; Online: Experimental evidences in favour of the hydroxylamine→nitrene-water tautomerization on the coordination sphere of Ir(III) centres.

    Cristóbal, Crispín / López-Serrano, Joaquín / Lozano-Vila, Ana M / Paneque, Margarita / Poveda, Manuel L / Vattier, Florencia / Vivancos, Ángela / Álvarez, Eleuterio

    Chemistry (Weinheim an der Bergstrasse, Germany)

    2013  Volume 19, Issue 31, Page(s) 10128–10131

    Abstract: And, to round off … A series of Ir(III) 5-membered metallacycles with an Ir-CH2 bond, react with aq. NH2OH with formation of hydride 6-membered iridacyclic complexes, which contain an Ir-NH=CH- imine functionality (see scheme). ...

    Abstract And, to round off … A series of Ir(III) 5-membered metallacycles with an Ir-CH2 bond, react with aq. NH2OH with formation of hydride 6-membered iridacyclic complexes, which contain an Ir-NH=CH- imine functionality (see scheme).
    Language English
    Publishing date 2013-07-29
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 1478547-x
    ISSN 1521-3765 ; 0947-6539
    ISSN (online) 1521-3765
    ISSN 0947-6539
    DOI 10.1002/chem.201300624
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  10. Article ; Online: Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2':6',2''-terpyridine.

    Paneque, Margarita / Poveda, Manuel L / Vattier, Florencia / Alvarez, Eleuterio / Carmona, Ernesto

    Chemical communications (Cambridge, England)

    2009  , Issue 37, Page(s) 5561–5563

    Abstract: Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex and binuclear , in which the polypyridine behaves, respectively, as a mono- or a bi- ... ...

    Abstract Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex and binuclear , in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.
    Language English
    Publishing date 2009-10-07
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/b909837b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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