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  1. Article ; Online: Spatio-temporal evolution and gravity center change of carbon emissions in the Guangdong-Hong Kong-Macao greater bay area and the influencing factors

    Li, Lei / Li, Junfeng / Wang, Xilong / Sun, Shujie

    Heliyon. 2023 June, v. 9, no. 6 p.e16596-

    2023  

    Abstract: The Guangdong-Hong Kong-Macao Greater Bay Area (GBA) is one of the most densely built and economically vibrant regions in China, it is of vital importance to study the spatio-temporal heterogeneity and influence mechanisms of its carbon emissions against ...

    Abstract The Guangdong-Hong Kong-Macao Greater Bay Area (GBA) is one of the most densely built and economically vibrant regions in China, it is of vital importance to study the spatio-temporal heterogeneity and influence mechanisms of its carbon emissions against the backdrop of peaking carbon dioxide emissions and achieving carbon neutrality. However, systematic research on this area is still lacking. Therefore, this study uses spatial autocorrelation, kernel density estimation, and standard deviation ellipses to construct an exploratory spatial data analysis (ESDA) framework to analyze the spatio-temporal evolutionary characteristics of carbon emissions from GBA and combine it with the geographically and temporally weighted regression (GTWR) model to identify the various influencing factors of carbon emissions in GBA and reveal its implications. The results showed that: (1) Between 2009 and 2019, the total carbon emissions in GBA remained stable and gradually decreased. The gap between the carbon emission intensity of the cities narrowed. (2) The GBA urban agglomeration exhibited spatial autocorrelation, but characteristics of the global spatial pattern had not yet formed a steady state. The kernel density of carbon emissions in GBA showed an obvious "monopolar" phenomenon. (3) The gravity centre of carbon emissions in GBA was located to the southeast of the geometric centre of the whole region, shifting toward the northwest. (4) Population size, level of economic development and energy intensity have a strong positive contribution to carbon emissions, compared to the level of opening up and industrialization level, which has a weaker impact. There is significant spatial heterogeneity in the distribution of regression coefficients for each factor, and GBA should take full account of the characteristics of different types of cities in terms of carbon emissions and implement targeted emission reduction strategies. Our research provides a comprehensive analytical framework for regional carbon emissions, offering theoretical support for low-carbon development in the GBA.
    Keywords autocorrelation ; carbon ; carbon dioxide ; center of gravity ; emissions factor ; energy ; geometry ; gravity ; industrialization ; population size ; spatial data ; spatial variation ; standard deviation ; China ; Guangdong-Hong Kong-Macao Greater bay area ; Carbon emission ; Sustainable development ; Spatiotemporal evolution ; Influencing factors
    Language English
    Dates of publication 2023-06
    Publishing place Elsevier Ltd
    Document type Article ; Online
    Note Use and reproduction
    ZDB-ID 2835763-2
    ISSN 2405-8440
    ISSN 2405-8440
    DOI 10.1016/j.heliyon.2023.e16596
    Database NAL-Catalogue (AGRICOLA)

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  2. Article ; Online: Effects of physical aging processes on the bioavailability of heavy metals in contaminated site soil amended with chicken manure and wheat straw biochars

    Yang, Kai / Wang, Xilong / Cheng, Hefa / Tao, Shu

    Environmental Pollution. 2023 May, v. 324 p.121414-

    2023  

    Abstract: The physicochemical properties of biochars undergo slow changes in soils due to the natural aging processes, which influences their interaction with heavy metals. The effects of aging on immobilization of co-existing heavy metals in contaminated soils ... ...

    Abstract The physicochemical properties of biochars undergo slow changes in soils due to the natural aging processes, which influences their interaction with heavy metals. The effects of aging on immobilization of co-existing heavy metals in contaminated soils amended with fecal and plant biochars possessing contrasting properties remain unclear. This study investigated the effects of wet–dry and freeze–thaw aging on the bioavailability (extractable by 0.01 M CaCl₂) and chemical fractionation of Cd and Pb in a contaminated site soil amended with 2.5% (w/w) chicken manure (CM) biochar and wheat straw (WS) biochar. Compared to that in the unamended soil, the contents of bioavailable Cd and Pb in CM biochar-amended soil decreased by 18.0% and 30.8%, respectively, after 60 wet–dry cycles, and by 16.9% and 52.5%, respectively, after 60 freeze–thaw cycles. CM biochar, which contained significant levels of phosphates and carbonates, effectively reduced the bioavailability of Cd and Pb and transformed them from the labile chemical fractions to the more stable ones in the soil during the accelerated aging processes, mainly through precipitation and complexation. In contrast, WS biochar failed to immobilize Cd in the co-contaminated soil in both aging regimes, and was only effective at immobilizing Pb under freeze–thaw aging. The changes in the immobilization of co-existing Cd and Pb in the contaminated soil resulted from aging-induced increase in oxygenated functional groups on biochar surface, destruction of the biochar's porous structure, and release of dissolved organic carbon from the aged biochar and soil. These findings could help guide the selection of suitable biochars for simultaneous immobilization of multiple heavy metals in co-contaminated soil under changing environmental conditions (e.g., rainfall, and freezing and thawing of soils).
    Keywords bioavailability ; biochar ; dissolved organic carbon ; fractionation ; freeze-thaw cycles ; polluted soils ; pollution ; poultry manure ; rain ; wheat straw ; Biochar aging ; Cadmium ; Lead ; Immobilization ; Complexation ; Precipitation
    Language English
    Dates of publication 2023-05
    Publishing place Elsevier Ltd
    Document type Article ; Online
    ZDB-ID 280652-6
    ISSN 1873-6424 ; 0013-9327 ; 0269-7491
    ISSN (online) 1873-6424
    ISSN 0013-9327 ; 0269-7491
    DOI 10.1016/j.envpol.2023.121414
    Database NAL-Catalogue (AGRICOLA)

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  3. Article: Spatio-temporal evolution and gravity center change of carbon emissions in the Guangdong-Hong Kong-Macao greater bay area and the influencing factors.

    Li, Lei / Li, Junfeng / Wang, Xilong / Sun, Shujie

    Heliyon

    2023  Volume 9, Issue 6, Page(s) e16596

    Abstract: The Guangdong-Hong Kong-Macao Greater Bay Area (GBA) is one of the most densely built and economically vibrant regions in China, it is of vital importance to study the spatio-temporal heterogeneity and influence mechanisms of its carbon emissions against ...

    Abstract The Guangdong-Hong Kong-Macao Greater Bay Area (GBA) is one of the most densely built and economically vibrant regions in China, it is of vital importance to study the spatio-temporal heterogeneity and influence mechanisms of its carbon emissions against the backdrop of peaking carbon dioxide emissions and achieving carbon neutrality. However, systematic research on this area is still lacking. Therefore, this study uses spatial autocorrelation, kernel density estimation, and standard deviation ellipses to construct an exploratory spatial data analysis (ESDA) framework to analyze the spatio-temporal evolutionary characteristics of carbon emissions from GBA and combine it with the geographically and temporally weighted regression (GTWR) model to identify the various influencing factors of carbon emissions in GBA and reveal its implications. The results showed that: (1) Between 2009 and 2019, the total carbon emissions in GBA remained stable and gradually decreased. The gap between the carbon emission intensity of the cities narrowed. (2) The GBA urban agglomeration exhibited spatial autocorrelation, but characteristics of the global spatial pattern had not yet formed a steady state. The kernel density of carbon emissions in GBA showed an obvious "monopolar" phenomenon. (3) The gravity centre of carbon emissions in GBA was located to the southeast of the geometric centre of the whole region, shifting toward the northwest. (4) Population size, level of economic development and energy intensity have a strong positive contribution to carbon emissions, compared to the level of opening up and industrialization level, which has a weaker impact. There is significant spatial heterogeneity in the distribution of regression coefficients for each factor, and GBA should take full account of the characteristics of different types of cities in terms of carbon emissions and implement targeted emission reduction strategies. Our research provides a comprehensive analytical framework for regional carbon emissions, offering theoretical support for low-carbon development in the GBA.
    Language English
    Publishing date 2023-05-24
    Publishing country England
    Document type Journal Article
    ZDB-ID 2835763-2
    ISSN 2405-8440
    ISSN 2405-8440
    DOI 10.1016/j.heliyon.2023.e16596
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: CPA-catalyzed asymmetric domino thia-Michael/aldol reactions for simultaneous chiral center and axial chirality formation.

    Wang, Xilong / Luo, Yu / Zhao, Jiaji / Luo, Shuang

    Organic & biomolecular chemistry

    2023  Volume 21, Issue 33, Page(s) 6697–6701

    Abstract: A highly enantio- and diastereoselective domino thia-Michael/aldol reaction applying ... ...

    Abstract A highly enantio- and diastereoselective domino thia-Michael/aldol reaction applying 5
    Language English
    Publishing date 2023-08-23
    Publishing country England
    Document type Journal Article
    ZDB-ID 2097583-1
    ISSN 1477-0539 ; 1477-0520
    ISSN (online) 1477-0539
    ISSN 1477-0520
    DOI 10.1039/d3ob01087b
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Effects of physical aging processes on the bioavailability of heavy metals in contaminated site soil amended with chicken manure and wheat straw biochars.

    Yang, Kai / Wang, Xilong / Cheng, Hefa / Tao, Shu

    Environmental pollution (Barking, Essex : 1987)

    2023  Volume 324, Page(s) 121414

    Abstract: The physicochemical properties of biochars undergo slow changes in soils due to the natural aging processes, which influences their interaction with heavy metals. The effects of aging on immobilization of co-existing heavy metals in contaminated soils ... ...

    Abstract The physicochemical properties of biochars undergo slow changes in soils due to the natural aging processes, which influences their interaction with heavy metals. The effects of aging on immobilization of co-existing heavy metals in contaminated soils amended with fecal and plant biochars possessing contrasting properties remain unclear. This study investigated the effects of wet-dry and freeze-thaw aging on the bioavailability (extractable by 0.01 M CaCl
    MeSH term(s) Animals ; Cadmium/chemistry ; Manure ; Triticum ; Chickens ; Biological Availability ; Lead ; Soil Pollutants/analysis ; Metals, Heavy/analysis ; Charcoal/chemistry ; Soil/chemistry
    Chemical Substances biochar ; Cadmium (00BH33GNGH) ; Manure ; Lead (2P299V784P) ; Soil Pollutants ; Metals, Heavy ; Charcoal (16291-96-6) ; Soil
    Language English
    Publishing date 2023-03-07
    Publishing country England
    Document type Journal Article
    ZDB-ID 280652-6
    ISSN 1873-6424 ; 0013-9327 ; 0269-7491
    ISSN (online) 1873-6424
    ISSN 0013-9327 ; 0269-7491
    DOI 10.1016/j.envpol.2023.121414
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article: Impact of exercise training on gut microbiome imbalance in obese individuals: a study based on Mendelian randomization analysis.

    Qian, Haonan / Zuo, Yuxin / Wen, Shixiong / Wang, Xilong / Liu, Yaowen / Li, Tianwei

    Frontiers in physiology

    2024  Volume 14, Page(s) 1264931

    Abstract: Objective: ...

    Abstract Objective:
    Language English
    Publishing date 2024-01-03
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2564217-0
    ISSN 1664-042X
    ISSN 1664-042X
    DOI 10.3389/fphys.2023.1264931
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article: Enhanced immobilization of cadmium and lead adsorbed on crop straw biochars by simulated aging processes

    Yang, Kai / Wang, Xilong / Cheng, Hefa / Tao, Shu

    Environmental pollution. 2022 June 01, v. 302

    2022  

    Abstract: Aging is an important natural process affecting the physiochemical properties of biochar, while mechanistic understanding of its effect on the adsorbed heavy metals is still lacking. After adsorption of Cd²⁺ and Pb²⁺, biochars produced from wheat straw ( ... ...

    Abstract Aging is an important natural process affecting the physiochemical properties of biochar, while mechanistic understanding of its effect on the adsorbed heavy metals is still lacking. After adsorption of Cd²⁺ and Pb²⁺, biochars produced from wheat straw (WS) and maize straw (MS) at 300 and 500 °C (denoted as WS300, WS500, MS300, and MS500, respectively) were subjected to 60 cycles of wet–dry or freeze–thaw aging. The results showed that simulated aging treatment transformed the Cd²⁺ and Pb²⁺ adsorbed on the low-temperature biochars from the readily and potentially bioavailable fractions into the non-bioavailable one, while the fractionation of Cd²⁺ and Pb²⁺ adsorbed on WS500 and Pb²⁺ on MS500 barely changed. Spectroscopic characterization revealed that simulated aging enhanced the complexation of Cd²⁺ and precipitation of Pb²⁺ on the biochars. These findings suggest that heavy metals could be effectively immobilized on low-temperature biochars amended to contaminated soils in the long term.
    Keywords adsorption ; bioavailability ; biochar ; cadmium ; corn straw ; fractionation ; freeze-thaw cycles ; pollution ; spectral analysis ; wheat straw
    Language English
    Dates of publication 2022-0601
    Publishing place Elsevier Ltd
    Document type Article
    ZDB-ID 280652-6
    ISSN 1873-6424 ; 0013-9327 ; 0269-7491
    ISSN (online) 1873-6424
    ISSN 0013-9327 ; 0269-7491
    DOI 10.1016/j.envpol.2022.119064
    Database NAL-Catalogue (AGRICOLA)

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  8. Article ; Online: Spatiotemporal evolution and influencing factors of land-use emissions in the Guangdong-Hong Kong-Macao Greater Bay Area using integrated nighttime light datasets.

    Li, Lei / Li, Junfeng / Peng, Liang / Wang, Xilong / Sun, Shujie

    The Science of the total environment

    2023  Volume 893, Page(s) 164723

    Abstract: Carbon emissions from land-use and land-cover change (together referred to as 'land-use emissions') are an important way to influence the regional carbon balance. However, due to the limitations and complexity of obtaining carbon emissions data at ... ...

    Abstract Carbon emissions from land-use and land-cover change (together referred to as 'land-use emissions') are an important way to influence the regional carbon balance. However, due to the limitations and complexity of obtaining carbon emissions data at spatial scales, previous studies rarely reveal the long-term evolution characteristics of regional land-use emissions. Therefore, we propose a method to integrate DMSP/OLS and NPP/VIIRS nighttime light images to calculate land-use emissions over a long time series. The accuracy validation results show that the integrated nighttime light images and land-use emissions have a good fit and can accurately assess the long-term evolution of regional carbon emissions. In addition, by combining the Exploratory Spatial Analysis (ESTDA) model and the Vector Autoregressive Regression (VAR) model, we found significant spatial variation in carbon emissions in the Guangdong-Hong Kong-Macao Greater Bay Area (GBA), with the two regional emission centres spreading outwards between 1995 and 2020, with an increase in construction land area of 3445 km
    Language English
    Publishing date 2023-06-12
    Publishing country Netherlands
    Document type Journal Article
    ZDB-ID 121506-1
    ISSN 1879-1026 ; 0048-9697
    ISSN (online) 1879-1026
    ISSN 0048-9697
    DOI 10.1016/j.scitotenv.2023.164723
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Enhanced immobilization of cadmium and lead adsorbed on crop straw biochars by simulated aging processes.

    Yang, Kai / Wang, Xilong / Cheng, Hefa / Tao, Shu

    Environmental pollution (Barking, Essex : 1987)

    2022  Volume 302, Page(s) 119064

    Abstract: Aging is an important natural process affecting the physiochemical properties of biochar, while mechanistic understanding of its effect on the adsorbed heavy metals is still lacking. After adsorption of ... ...

    Abstract Aging is an important natural process affecting the physiochemical properties of biochar, while mechanistic understanding of its effect on the adsorbed heavy metals is still lacking. After adsorption of Cd
    MeSH term(s) Cadmium/analysis ; Charcoal/chemistry ; Lead ; Soil/chemistry ; Soil Pollutants/analysis
    Chemical Substances Soil ; Soil Pollutants ; biochar ; Cadmium (00BH33GNGH) ; Charcoal (16291-96-6) ; Lead (2P299V784P)
    Language English
    Publishing date 2022-02-25
    Publishing country England
    Document type Journal Article
    ZDB-ID 280652-6
    ISSN 1873-6424 ; 0013-9327 ; 0269-7491
    ISSN (online) 1873-6424
    ISSN 0013-9327 ; 0269-7491
    DOI 10.1016/j.envpol.2022.119064
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: PdIr nanoparticles on NH2-functionalized dendritic mesoporous silica nanospheres for efficient dehydrogenation of formic acid

    Li, Song / Zhou, Chunhui / Hu, Jinsong / Duan, Aijun / Xu, Chunming / Wang, Xilong

    Journal of Catalysis. 2023 July 19,

    2023  

    Abstract: Developing highly efficient solid catalysts for formic acid (HCOOH, FA) dehydrogenation is essential to utilize FA as a hydrogen (H₂) carrier. In this work, ultrafine bimetallic PdIr nanoparticles (NPs) supported on the amine-functionalized dendritic ... ...

    Abstract Developing highly efficient solid catalysts for formic acid (HCOOH, FA) dehydrogenation is essential to utilize FA as a hydrogen (H₂) carrier. In this work, ultrafine bimetallic PdIr nanoparticles (NPs) supported on the amine-functionalized dendritic mesoporous silica nanospheres (PdIr/DMSNs-NH₂) have been successfully synthesized by the simple surface functionalization and co-reduction method. The optimized Pd₄Ir₁/DMSNs-NH₂ (Pd/Ir molar ratio = 4:1) catalyst displayed the remarkable catalytic performance with 100 % H₂ selectivity of the FA dehydrogenation, and the initial turnover frequency (TOF) could achieve 1333 h⁻¹ with the additive of sodium formate (SF) at 298 K, which is comparable to the most effective mesoporous silica supported Pd-containing solid catalysts. The activation energy (Ea) for the FA dehydrogenation of Pd₄Ir₁/DMSNs-NH₂ catalyst in the FA-SF mixture is 39.7 KJ/mol, lower than other reported catalysts. Furthermore, the optimized catalyst maintained 100 % H₂ selectivity even after five runs, only with a negligible decrease in the activity, displaying the excellent stability of the catalyst. The superior catalytic performance could be attributed to the synergistic effect of open dendritic pore channel, high dispersion and ultrafine size of PdIr NPs as the active sites on DMSNs-NH₂, and regulated electronic effects of Pd and Ir. More importantly, introducing -NH₂ groups to the DMSNs could facilitate the O-H bond dissociation of FA and improve the FA dehydrogenation activity under mild conditions. This work will significantly promote FA as a hydrogen carrier on fuel cells.
    Keywords activation energy ; catalysts ; catalytic activity ; dehydrogenation ; dissociation ; formic acid ; fuels ; hydrogen ; nanoparticles ; nanospheres ; porous media ; silica ; sodium formate ; synergism ; Dendritic mesoporous silica nanospheres ; NH2-functionalization ; Hydrogen production ; PdIr nanoparticles
    Language English
    Dates of publication 2023-0719
    Publishing place Elsevier Inc.
    Document type Article ; Online
    Note Pre-press version
    ZDB-ID 1468993-5
    ISSN 1090-2694 ; 0021-9517
    ISSN (online) 1090-2694
    ISSN 0021-9517
    DOI 10.1016/j.jcat.2023.07.014
    Database NAL-Catalogue (AGRICOLA)

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