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  1. Article ; Online: Experimental and theoretical studies of pH-responsive iridium(III) complexes of azole and N-heterocyclic carbene ligands.

    Hashemzadeh, Tahmineh / Christofferson, Andrew J / White, Keith F / Barnard, Peter J

    Dalton transactions (Cambridge, England : 2003)

    2024  Volume 53, Issue 19, Page(s) 8478–8493

    Abstract: A series of nine luminescent iridium(III) complexes with pH-responsive imidazole and benzimidazole ligands have been prepared and characterized. The first series of complexes were of the form [Ir(ppy) ...

    Abstract A series of nine luminescent iridium(III) complexes with pH-responsive imidazole and benzimidazole ligands have been prepared and characterized. The first series of complexes were of the form [Ir(ppy)
    Language English
    Publishing date 2024-05-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt03766e
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: An extremely electron poor Au(III) trication bearing acetonitrile ligands.

    Barwise, Lachlan / Moon, Lachlan J / Dhakal, Bibidh / Hogan, Conor F / White, Keith F / Dutton, Jason L

    Chemical communications (Cambridge, England)

    2024  

    Abstract: The synthesis and structural characterization of an electron poor Au(III) trication bearing 2 imidazole and 2 acetonitrile ligands is described. The new complex is capable of aryl C-H metalation with the formation of a monomesitylene complex and also ... ...

    Abstract The synthesis and structural characterization of an electron poor Au(III) trication bearing 2 imidazole and 2 acetonitrile ligands is described. The new complex is capable of aryl C-H metalation with the formation of a monomesitylene complex and also demonstrated to be highly oxidizing in the rapid room temperature conversion of cyclohexene to benzene.
    Language English
    Publishing date 2024-05-03
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d4cc00818a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Synthesis, structural characterization, reactivity and catalytic activity of mixed halo/triflate ArI(OTf)(X) species.

    Sharp-Bucknall, Lachlan / Sceney, Marcus / White, Keith F / Dutton, Jason L

    Dalton transactions (Cambridge, England : 2003)

    2023  Volume 52, Issue 11, Page(s) 3358–3370

    Abstract: Both mixed ... ...

    Abstract Both mixed λ
    Language English
    Publishing date 2023-03-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt00275f
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: ArI(NTf

    Barwise, Lachlan / Bennetts, Jason D / White, Keith F / Dutton, Jason L

    Chemical communications (Cambridge, England)

    2023  Volume 59, Issue 89, Page(s) 13340–13343

    Abstract: Synthesis and crystallographic characterization of ... ...

    Abstract Synthesis and crystallographic characterization of NO
    Language English
    Publishing date 2023-11-07
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/d3cc04563c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: C-H, Si-H and C-F abstraction with an extremely electron poor I(III) reagent.

    Tania / Sceney, Marcus / Bennetts, Jason D / Barwise, Lachlan / White, Keith F / Dutton, Jason L

    Dalton transactions (Cambridge, England : 2003)

    2023  Volume 52, Issue 43, Page(s) 15866–15870

    Abstract: The recently discovered I(III) reagent ... ...

    Abstract The recently discovered I(III) reagent NO
    Language English
    Publishing date 2023-11-07
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt03266c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Structural verification and new reactivity for Stang's reagent, [PhI(CN)][OTf].

    Bennetts, Jason D / Barwise, Lachlan / Sharp-Bucknall, Lachlan / White, Keith F / Hogan, Conor F / Dutton, Jason L

    Dalton transactions (Cambridge, England : 2003)

    2023  Volume 52, Issue 25, Page(s) 8536–8539

    Abstract: The structure of Stang's reagent [PhI(CN)][OTf] is confirmed by X-ray crystallography and is determined to be best described as an ion-pair in organic solution. It is found to be a strong Lewis acid, but reaction with pyridine ligands gives [Pyr-CN][OTf] ...

    Abstract The structure of Stang's reagent [PhI(CN)][OTf] is confirmed by X-ray crystallography and is determined to be best described as an ion-pair in organic solution. It is found to be a strong Lewis acid, but reaction with pyridine ligands gives [Pyr-CN][OTf] salts
    Language English
    Publishing date 2023-06-27
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/d3dt01765f
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Cage hydrocarbons as linkers in dimeric drug design: Case studies with trimethoprim and tedizolid.

    Vujcic, Biljana / Wyllie, Jessica / Tania / Burns, Jed / White, Keith F / Cromwell, Simon / Lupton, David W / Dutton, Jason L / Soares da Costa, Tatiana P / Houston, Sevan D

    Bioorganic & medicinal chemistry letters

    2022  Volume 80, Page(s) 129086

    Abstract: The looming threat of a "post-antibiotic era" has been caused by a rapid rise in antibacterial resistance and subsequent depletion of effective antibiotic agents in the clinic. An efficient strategy to address this shortfall lies in the reengineering of ... ...

    Abstract The looming threat of a "post-antibiotic era" has been caused by a rapid rise in antibacterial resistance and subsequent depletion of effective antibiotic agents in the clinic. An efficient strategy to address this shortfall lies in the reengineering of pre-existing and commercially available antibiotic drugs. This is exemplified by dimerization, a design concept in which two pharmacophores are covalently linked to form a new chemical entity. The cage hydrocarbons cubane (1), bicyclo[2.2.2]octane (BCO) (2), adamantane (3), and bicyclo[1.1.1]pentane (BCP) (4) present themselves as an attractive family of linkers in this regard. In this report, all four hydrocarbon cages were employed as linkers in a series of dimers based on the commercially available antibiotics trimethoprim and tedizolid. A detailed synthetic roadmap for the protection and deprotection of each pharmacophore is outlined. Several members of the trimethoprim series showed activity on par with that of their trimethoprim progenitor, although this was not the case for the tedizolid series. The design strategy outlined herein highlights the utility of the group as a platform for the rapid and modular construction of future novel antibiotics.
    MeSH term(s) Trimethoprim/pharmacology ; Oxazolidinones ; Anti-Bacterial Agents/pharmacology ; Anti-Bacterial Agents/therapeutic use ; Hydrocarbons
    Chemical Substances tedizolid (97HLQ82NGL) ; Trimethoprim (AN164J8Y0X) ; Oxazolidinones ; Anti-Bacterial Agents ; Hydrocarbons
    Language English
    Publishing date 2022-11-21
    Publishing country England
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 1063195-1
    ISSN 1464-3405 ; 0960-894X
    ISSN (online) 1464-3405
    ISSN 0960-894X
    DOI 10.1016/j.bmcl.2022.129086
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Cologne/Königswinter

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  8. Article ; Online: Lightweight Ionic Networks Composed of Li

    White, Keith F / Abrahams, Brendan F / Hudson, Timothy A / Robson, Richard

    ChemPlusChem

    2016  Volume 81, Issue 8, Page(s) 877–884

    Abstract: The combination of lightweight metal cations with a range of dicarboxylate ligands has led to the generation of ionic network materials that possess channels occupied by solvent molecules. The compounds [ ... ...

    Abstract The combination of lightweight metal cations with a range of dicarboxylate ligands has led to the generation of ionic network materials that possess channels occupied by solvent molecules. The compounds [Li
    Language English
    Publishing date 2016-07-05
    Publishing country Germany
    Document type Journal Article
    ISSN 2192-6506
    ISSN (online) 2192-6506
    DOI 10.1002/cplu.201600274
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  9. Article ; Online: Multifunctional Coordination Polymer Exhibiting Reversible Mechanical Motion Allowing Selective Uptake of Guests and Leading to Enhanced Electrical Conductivity.

    Elliott, Robert W / Sutton, Ashley L / Abrahams, Brendan F / D'Alessandro, Deanna M / Goerigk, Lars / Hua, Carol / Hudson, Timothy A / Robson, Richard / White, Keith F

    Inorganic chemistry

    2021  Volume 60, Issue 17, Page(s) 13658–13668

    Abstract: A remarkably flexible, multifunctional, 2D coordination polymer exhibiting an unprecedented mode of reversible mechanical motion, enabling pores to open and close, is reported. Such multifunctional materials are highly sought after, owing to the ... ...

    Abstract A remarkably flexible, multifunctional, 2D coordination polymer exhibiting an unprecedented mode of reversible mechanical motion, enabling pores to open and close, is reported. Such multifunctional materials are highly sought after, owing to the potential to exploit coexisting electronic and mechanical functionalities that underpin useful technological applications such as actuators and ultrasensitive detectors. The coordination polymer, of composition Mn(F
    Language English
    Publishing date 2021-08-24
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.1c01979
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Guest-induced Assembly of Bis(thiosemicarbazonato) Zinc(II) Coordination Nanotubes.

    Paterson, Brett M / White, Keith F / White, Jonathan M / Abrahams, Brendan F / Donnelly, Paul S

    Angewandte Chemie (International ed. in English)

    2017  Volume 56, Issue 29, Page(s) 8370–8374

    Abstract: ... A ... ...

    Abstract A Zn
    Language English
    Publishing date 2017-03-23
    Publishing country Germany
    Document type Journal Article ; Research Support, Non-U.S. Gov't
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.201701596
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