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Article: Analysis of polycyclic aromatic hydrocarbons (PAHs) and their derivatives in biochar treated stormwater.

Celma, Alberto / Dahlberg, Anna-Karin / Wiberg, Karin

2023 Volume 10, Page(s) 102232

Abstract: Polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (oxy-PAHs) and nitrogen heterocyclic polycyclic aromatic compounds (N-PACs) are persistent and semi-volatile organic compounds primarily formed due to incomplete combustion of organic material or, ... ...

Abstract	Polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (oxy-PAHs) and nitrogen heterocyclic polycyclic aromatic compounds (N-PACs) are persistent and semi-volatile organic compounds primarily formed due to incomplete combustion of organic material or, in the case of the derivatives, through transformation reactions of PAHs. Their presence in the environment is ubiquitous and many of them have been proven carcinogenic, teratogenic, and mutagenic. These toxic pollutants can therefore pose a threat to both ecosystem and human health and urges for remediation strategies for PAHs and derivatives from water bodies. Biochar is a carbon-rich material resulting from the pyrolysis of biomass resulting in a very porous matter with high surface area for an enhanced interaction with chemicals. This makes biochar a promising alternative for filtering micropollutants from contaminated aquatic bodies. In this work, a previously developed and validated methodology for the analysis of PAHs, oxy-PAHs and N-PACs in surface water samples was adapted for its utilization in biochar treated stormwater with special emphasis on scaling down the solid-phase extraction as well as including an additional filtering step for the removal of particulate matter in the media.•Optimized extraction method for PAHs, oxy-PAHs and N-PACs from stormwater treated with biochar.•Biochar strongly impacts the stormwater matrix and, therefore, additional steps are required in the extraction methodology.•Solid-phase extraction combined with GC-MS have been used to analyse PAHs, oxy-PAHs and N-PACs in stormwater treated with biochar.
Language	English
Publishing date	2023-05-30
Publishing country	Netherlands
Document type	Journal Article
ZDB-ID	2830212-6
ISSN	2215-0161
ISSN	2215-0161
DOI	10.1016/j.mex.2023.102232
Database	MEDical Literature Analysis and Retrieval System OnLINE

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Article ; Online: Integrated Treatment of Per- and Polyfluoroalkyl Substances in Existing Wastewater Treatment Plants-Scoping the Potential of Foam Partitioning.

Smith, Sanne J / Keane, Chantal / Ahrens, Lutz / Wiberg, Karin

ACS ES&T engineering

2023 Volume 3, Issue 9, Page(s) 1276–1285

Abstract: Foam fractionation is becoming increasingly popular as a treatment technology for water contaminated with per- and polyfluoroalkyl substances (PFAS). At many existing wastewater treatment facilities, particularly in aerated treatment steps, foam ... ...

Abstract	Foam fractionation is becoming increasingly popular as a treatment technology for water contaminated with per- and polyfluoroalkyl substances (PFAS). At many existing wastewater treatment facilities, particularly in aerated treatment steps, foam formation is frequently observed. This study aimed to investigate if foam fractionation for the removal of PFAS could be integrated with such existing treatment processes. Influent, effluent, water under the foam, and foam were sampled from ten different wastewater treatment facilities where foam formation was observed. These samples were analyzed for the concentration of 29 PFAS, also after the total oxidizable precursor (TOP) assay. Enrichment factors were defined as the PFAS concentration in the foam divided by the PFAS concentration in the influent. Although foam partitioning did not lead to decreased ∑PFAS concentrations from influent to effluent in any of the plants, certain long-chain PFAS were removed with efficiencies up to 76%. Moreover, ∑PFAS enrichment factors in the foam ranged up to 10
Language	English
Publishing date	2023-08-01
Publishing country	United States
Document type	Journal Article
ISSN	2690-0645
ISSN (online)	2690-0645
DOI	10.1021/acsestengg.3c00091
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Article ; Online: Mass flow of per- and polyfluoroalkyl substances (PFAS) in a Swedish municipal wastewater network and wastewater treatment plant.

Gobelius, Laura / Glimstedt, Linda / Olsson, Jesper / Wiberg, Karin / Ahrens, Lutz

Chemosphere

2023 Volume 336, Page(s) 139182

Abstract: PER: and polyfluoroalkyl substances (PFAS) are ubiquitously distributed in wastewater, due to their numerous uses in industry and consumer products, but little is known of PFAS mass flows in municipal wastewater network systems and within wastewater ... ...

Abstract	PER: and polyfluoroalkyl substances (PFAS) are ubiquitously distributed in wastewater, due to their numerous uses in industry and consumer products, but little is known of PFAS mass flows in municipal wastewater network systems and within wastewater treatment plants (WWTPs). This study assessed mass flows of 26 PFAS in a wastewater network and WWTP, to provide new insights into their sources, transport, and fate in different treatment steps. Wastewater and sludge samples were collected from pumping stations and the main WWTP in Uppsala, Sweden. PFAS composition profiles and mass flows were used to identify sources within the sewage network. Wastewater from one pumping station showed elevated concentrations of C
MeSH term(s)	Wastewater ; Sewage ; Sweden ; Fluorocarbons/analysis ; Water Pollutants, Chemical/analysis ; Water Purification
Chemical Substances	Wastewater ; Sewage ; Fluorocarbons ; Water Pollutants, Chemical
Language	English
Publishing date	2023-06-09
Publishing country	England
Document type	Journal Article
ZDB-ID	120089-6
ISSN	1879-1298 ; 0045-6535 ; 0366-7111
ISSN (online)	1879-1298
ISSN	0045-6535 ; 0366-7111
DOI	10.1016/j.chemosphere.2023.139182
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Article ; Online: Capping fiberbank sediments to reduce persistent organic pollutants (POPs) fluxes: A large-scale laboratory column experiment.

Dahlberg, Anna-Karin / Wiberg, Karin / Snowball, Ian / Lehoux, Alizée P

Environmental pollution (Barking, Essex : 1987)

2023 Volume 333, Page(s) 122019

Abstract: Deposits of contaminated wood fiber waste (fiberbanks), originating from sawmills and pulp and paper industries, have been found in the aquatic environment in boreal countries. In-situ isolation capping has been proposed as a remediation solution because ...

Abstract	Deposits of contaminated wood fiber waste (fiberbanks), originating from sawmills and pulp and paper industries, have been found in the aquatic environment in boreal countries. In-situ isolation capping has been proposed as a remediation solution because it has the potential to prevent dispersal of persistent organic pollutants (POPs) from this type of sediment. However, knowledge about the performance of such caps when placed on very soft (unconsolidated), gaseous organic rich sediment is scarce. We investigated the effectiveness of conventional in-situ capping to limit POPs fluxes to the water column from contaminated fibrous sediments that produce gas. A controlled, large-scale laboratory column (40 cm diameter, 2 m height) experiment was performed over 8 months to study changes in sediment-to-water fluxes of POPs and particle resuspension before and after capping the sediment with crushed stones (≥4 mm grain size). Two different cap thicknesses were tested (20 and 45 cm) on two types of fiberbank sediment with different fiber type composition. Results showed that capping fiberbank sediment with a 45 cm gravel cap reduced the sediment-to-water flux by 91-95% for p,p'-DDD, o,p'-DDD, by 39-82% for CB-101, CB-118, CB-138, CB-153, CB-180 and by 12-18% for HCB, whereas for less hydrophobic PCBs, capping was largely ineffective (i.e. CB-28 and CB-52). Although cap application caused particle resuspension, the long-term effect of the cap was reduced particle resuspension. On the other hand, substantial sediment consolidation released large volumes of contaminated pore water into the overlying water body. Importantly, both sediment types produced large amount of gas, observed as gas voids forming inside the sediment and gas ebullition events, which increased pore water advection and affected the structural integrity of the cap. This may limit the practical applicability of this method on fiberbank sediments.
MeSH term(s)	Persistent Organic Pollutants ; Geologic Sediments/chemistry ; Environmental Pollutants/analysis ; Water ; Water Pollutants, Chemical/analysis
Chemical Substances	Persistent Organic Pollutants ; Environmental Pollutants ; Water (059QF0KO0R) ; Water Pollutants, Chemical
Language	English
Publishing date	2023-06-12
Publishing country	England
Document type	Journal Article
ZDB-ID	280652-6
ISSN	1873-6424 ; 0013-9327 ; 0269-7491
ISSN (online)	1873-6424
ISSN	0013-9327 ; 0269-7491
DOI	10.1016/j.envpol.2023.122019
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Article ; Online: Spatial distribution and load of per- and polyfluoroalkyl substances (PFAS) in background soils in Sweden.

Mattias, Sörengård / Kikuchi, Johannes / Wiberg, Karin / Lutz, Ahrens

Chemosphere

2022 Volume 295, Page(s) 133944

Abstract: Per- and polyfluoroalkyl substances (PFAS) are known to be persistent, bioaccumulative, and have adverse health effects, but very little is known about PFAS in the terrestrial environment and factors influencing their distribution. This paper presents ... ...

Abstract	Per- and polyfluoroalkyl substances (PFAS) are known to be persistent, bioaccumulative, and have adverse health effects, but very little is known about PFAS in the terrestrial environment and factors influencing their distribution. This paper presents one of the first comprehensive studies investigating PFAS (n = 28) in background forest soils (n = 27) on national scale across Sweden. The results showed that 16 of 28 target PFAS were present and all sites contained at least three PFAS compounds, with total concentrations ranging between 0.40 ng/g dry weight (dw) and 6.6 ng/g dw. Perfluorooctanesulfonic acid (PFOS) showed the highest detection frequency of 89% and a median concentration of 0.39 ng/g dw. The PFOS loads (ng/m
MeSH term(s)	Alkanesulfonic Acids/analysis ; Environmental Monitoring ; Fluorocarbons/analysis ; Soil ; Sweden ; Water Pollutants, Chemical/analysis
Chemical Substances	Alkanesulfonic Acids ; Fluorocarbons ; Soil ; Water Pollutants, Chemical
Language	English
Publishing date	2022-02-09
Publishing country	England
Document type	Journal Article
ZDB-ID	120089-6
ISSN	1879-1298 ; 0045-6535 ; 0366-7111
ISSN (online)	1879-1298
ISSN	0045-6535 ; 0366-7111
DOI	10.1016/j.chemosphere.2022.133944
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Article: Spatial distribution and load of per- and polyfluoroalkyl substances (PFAS) in background soils in Sweden

Sörengård, Mattias / Kikuchi, Johannes / Wiberg, Karin / Ahrens, Lutz

Chemosphere. 2022 May, v. 295

2022

Abstract	Per- and polyfluoroalkyl substances (PFAS) are known to be persistent, bioaccumulative, and have adverse health effects, but very little is known about PFAS in the terrestrial environment and factors influencing their distribution. This paper presents one of the first comprehensive studies investigating PFAS (n = 28) in background forest soils (n = 27) on national scale across Sweden. The results showed that 16 of 28 target PFAS were present and all sites contained at least three PFAS compounds, with total concentrations ranging between 0.40 ng/g dry weight (dw) and 6.6 ng/g dw. Perfluorooctanesulfonic acid (PFOS) showed the highest detection frequency of 89% and a median concentration of 0.39 ng/g dw. The PFOS loads (ng/m³) showed a distinct spatial distribution, with a significant exponential increase from north to south (R² = 0.55; p < 0.001) and west to east (R² = 0.35; p < 0.01). In some parts of Sweden, the compound 6:2 fluorotelomer sulfonate (6:2 FTSA) had a higher median concentration (1.4 ng/g dw), but was in comparison to PFOS more impacted by local sources. Partial least squares discriminant analysis (PLS-DA) showed regional clustering of PFAS compositional profiles, indicating that PFAS soil background concentrations are functions of spatial variations at local, regional, and countrywide scale. Such spatial trends have not been observed previously and it could not be deduced whether they are indicative of trends on a global scale, or country-specific and better explained by proximity to densely populated urban areas. An interpolation and extrapolation raster map created from the results was used to calculate the average total PFAS load on Swedish soils. Estimated total load in the top 10-cm soil layer was 2.7 ± 2.4 tons for PFOS and 16 ± 14 tons for ∑PFAS, indicating that soil carries a considerable legacy of past PFAS release.
Keywords	discriminant analysis ; forests ; perfluorooctane sulfonic acid ; sulfonates ; Sweden
Language	English
Dates of publication	2022-05
Publishing place	Elsevier Ltd
Document type	Article
ZDB-ID	120089-6
ISSN	1879-1298 ; 0045-6535 ; 0366-7111
ISSN (online)	1879-1298
ISSN	0045-6535 ; 0366-7111
DOI	10.1016/j.chemosphere.2022.133944
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Seasonal trends and retention of polycyclic aromatic compounds (PACs) in a remote sub-Arctic catchment

Nguyen, Minh A. / Ahrens, Lutz / Josefsson, Sarah / Gustavsson, Jakob / Laudon, Hjalmar / Wiberg, Karin

Environmental Pollution. 2023 Sept., v. 333 p.121992-

2023

Abstract: Atmospheric deposition is the most dominant source of polycyclic aromatic hydrocarbons (PAHs) in remote and pristine areas. Despite low bioaccumulation potential, PAHs and their persistent transformation products (PAH-derivatives) are chemicals of ... ...

Abstract	Atmospheric deposition is the most dominant source of polycyclic aromatic hydrocarbons (PAHs) in remote and pristine areas. Despite low bioaccumulation potential, PAHs and their persistent transformation products (PAH-derivatives) are chemicals of concern as they can harm human and animal health through chronic low dose exposure. In this study, atmospheric deposition fluxes of polycyclic aromatic compounds (PACs) were measured on a seasonal basis (3-month periods) from 2012 to 2016 in a remote subarctic forest catchment in northern Europe. The target PACs included 19 PAHs and 15 PAH-derivatives (oxygenated, nitrogenated, and methylated PAHs). The deposition fluxes of ƩPAHs and ƩPAH-derivatives were in the same range and averaged 530 and 500 ng m² day⁻¹, respectively. The fluxes were found to be higher with a factor of 2.5 for ƩPAHs and a factor of 3 for ƩPAH-derivatives during cold (<0 °C) in comparison to warm (>10 °C) periods. PAHs and PAH-derivatives showed similar seasonal patterns, which suggests that these two compound classes have similar sources and deposition mechanisms, and that the source strength of the PAH-derivatives in air follows that of the PAHs. The terrestrial export of PACs via the outlet of the catchment stream was estimated to be 1.1% for ƩPAHs and 1.7% for ƩPAH-derivatives in relation to the annual amounts deposited to the catchment, which suggests that boreal forests are sinks for PACs derived from the atmosphere. Some individual PACs showed higher export than others (i.e. chrysene, cyclopenta(c,d)pyrene, carbazole, quinoline, and benzo(f)quinoline), with high export PACs mostly characterized by low molecular weight and low hydrophobicity (2–3 benzene rings; log Kₒw<6.0).
Keywords	air ; animal and human health ; atmospheric deposition ; benzene ; bioaccumulation ; cold ; exports ; forested watersheds ; hydrophobicity ; methylation ; molecular weight ; pollution ; quinoline ; streams ; Northern European region ; Polycyclic aromatic compounds (PACs) ; Boreal catchment ; Seasonal trends ; Terrestrial retention ; PAHs and PAH-Derivatives ; Polycyclic aromatic hydrocarbons (PAHs) ; Oxygenated ; Nitrogenated, and methylated PAHs ; Wet and dry deposition ; Snow ; Cold climate ; Terrestrial export
Language	English
Dates of publication	2023-09
Publishing place	Elsevier Ltd
Document type	Article ; Online
ZDB-ID	280652-6
ISSN	1873-6424 ; 0013-9327 ; 0269-7491
ISSN (online)	1873-6424
ISSN	0013-9327 ; 0269-7491
DOI	10.1016/j.envpol.2023.121992
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Capping fiberbank sediments to reduce persistent organic pollutants (POPs) fluxes: A large-scale laboratory column experiment

Dahlberg, Anna-Karin / Wiberg, Karin / Snowball, Ian / Lehoux, Alizée P.

Environmental Pollution. 2023 Sept., v. 333 p.122019-

2023

Abstract	Deposits of contaminated wood fiber waste (fiberbanks), originating from sawmills and pulp and paper industries, have been found in the aquatic environment in boreal countries. In-situ isolation capping has been proposed as a remediation solution because it has the potential to prevent dispersal of persistent organic pollutants (POPs) from this type of sediment. However, knowledge about the performance of such caps when placed on very soft (unconsolidated), gaseous organic rich sediment is scarce. We investigated the effectiveness of conventional in-situ capping to limit POPs fluxes to the water column from contaminated fibrous sediments that produce gas. A controlled, large-scale laboratory column (40 cm diameter, 2 m height) experiment was performed over 8 months to study changes in sediment-to-water fluxes of POPs and particle resuspension before and after capping the sediment with crushed stones (≥4 mm grain size). Two different cap thicknesses were tested (20 and 45 cm) on two types of fiberbank sediment with different fiber type composition. Results showed that capping fiberbank sediment with a 45 cm gravel cap reduced the sediment-to-water flux by 91–95% for p,p’-DDD, o,p’-DDD, by 39–82% for CB-101, CB-118, CB-138, CB-153, CB-180 and by 12–18% for HCB, whereas for less hydrophobic PCBs, capping was largely ineffective (i.e. CB-28 and CB-52). Although cap application caused particle resuspension, the long-term effect of the cap was reduced particle resuspension. On the other hand, substantial sediment consolidation released large volumes of contaminated pore water into the overlying water body. Importantly, both sediment types produced large amount of gas, observed as gas voids forming inside the sediment and gas ebullition events, which increased pore water advection and affected the structural integrity of the cap. This may limit the practical applicability of this method on fiberbank sediments.
Keywords	DDD (pesticide) ; advection ; aquatic environment ; gravel ; hydrophobicity ; long term effects ; pollution ; remediation ; surface water ; wastes ; wood fibers ; Sediment remediation ; In-situ capping ; Contaminant transport
Language	English
Dates of publication	2023-09
Publishing place	Elsevier Ltd
Document type	Article ; Online
ZDB-ID	280652-6
ISSN	1873-6424 ; 0013-9327 ; 0269-7491
ISSN (online)	1873-6424
ISSN	0013-9327 ; 0269-7491
DOI	10.1016/j.envpol.2023.122019
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Mass flow of per- and polyfluoroalkyl substances (PFAS) in a Swedish municipal wastewater network and wastewater treatment plant

Gobelius, Laura / Glimstedt, Linda / Olsson, Jesper / Wiberg, Karin / Ahrens, Lutz

Chemosphere. 2023 Sept., v. 336 p.139182-

2023

Abstract: and polyfluoroalkyl substances (PFAS) are ubiquitously distributed in wastewater, due to their numerous uses in industry and consumer products, but little is known of PFAS mass flows in municipal wastewater network systems and within wastewater treatment ...

Abstract	and polyfluoroalkyl substances (PFAS) are ubiquitously distributed in wastewater, due to their numerous uses in industry and consumer products, but little is known of PFAS mass flows in municipal wastewater network systems and within wastewater treatment plants (WWTPs). This study assessed mass flows of 26 PFAS in a wastewater network and WWTP, to provide new insights into their sources, transport, and fate in different treatment steps. Wastewater and sludge samples were collected from pumping stations and the main WWTP in Uppsala, Sweden. PFAS composition profiles and mass flows were used to identify sources within the sewage network. Wastewater from one pumping station showed elevated concentrations of C₃–C₈ PFCA, likely caused by an industrial source, and two stations had elevated concentrations of 6:2 FTSA, probably originating from a nearby firefighter training facility. Within the WWTP, short-chain PFAS dominated in wastewater, whereas long-chain PFAS dominated in sludge. The ratio of perfluoroalkyl sulfonates (PFSA) and ethylperfluorooctanesulfonamidoacetic acid (EtFOSAA) to ∑₂₆PFAS decreased during the WWTP process, likely due to sorption to sludge, but also transformation (EtFOSAA). Overall, PFAS were not efficiently removed in the WWTP, with mean removal efficiency of 10 ± 68% for individual PFAS, resulting in discharge of 7000 mg d⁻¹ ∑₂₆PFAS into the recipient. This shows that conventional WWTPs are inefficient in removing PFAS from wastewater and sludge, so advanced treatment techniques are needed.
Keywords	fire fighters ; industry ; mass flow ; municipal wastewater ; perfluorocarbons ; sewage ; sludge ; sorption ; sulfonates ; wastewater treatment ; Sweden ; PFAS ; Pipe network ; Removal efficiency
Language	English
Dates of publication	2023-09
Publishing place	Elsevier Ltd
Document type	Article ; Online
ZDB-ID	120089-6
ISSN	1879-1298 ; 0045-6535 ; 0366-7111
ISSN (online)	1879-1298
ISSN	0045-6535 ; 0366-7111
DOI	10.1016/j.chemosphere.2023.139182
Database	NAL-Catalogue (AGRICOLA)

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Article ; Online: Foam fractionation for removal of per- and polyfluoroalkyl substances: Towards closing the mass balance

Smith, Sanne J. / Lewis, Jeffrey / Wiberg, Karin / Wall, Erik / Ahrens, Lutz

Science of the Total Environment. 2023 May, v. 871 p.162050-

2023

Abstract: Foam fractionation has recently attracted attention as a low-cost and environmentally benign treatment technology for water contaminated with per- and polyfluoroalkyl substances (PFAS). However, data on the mass balance over the foam fractionation ... ...

Abstract	Foam fractionation has recently attracted attention as a low-cost and environmentally benign treatment technology for water contaminated with per- and polyfluoroalkyl substances (PFAS). However, data on the mass balance over the foam fractionation process are scarce and when available, gaps in the mass balance are often identified. This study verified the high treatment efficiency of a pilot-scale foam fractionation system for removal of PFAS from industrial water contaminated with aqueous film-forming foam. ΣPFAS removal reached up to 84 % and the removal of perfluorooctane sulfonic acid (PFOS) up to 97 %, but the short-chain perfluorobutanoic acid (PFBA) was only removed with a mean efficiency of 1.5 %. In general, mobile short-chain PFAS were removed less efficiently when the perfluorocarbon chain length was below six for carboxylic acids and below five for sulfonic acids. Fluctuations in treatment efficiency due to natural variations in the chemistry of the influent water were minor, confirming the robustness of the technology, but significant positive correlations between PFAS removal and influent metal concentration and conductivity were observed. Over all experiments, the mass balance closure did not differ significantly from 100 %. Nonetheless, PFAS sorption to the walls of the reactor was measured, as well as high PFAS emissions by the air exiting the reactor. PFAS emissions in aerosols correlated positively with mass balance closure. The elevated aerial PFAS concentrations measured in the experimental facility have implications for worker safety and prevention of PFAS-emissions to the atmosphere, and demonstrate the importance of installing appropriate filters on the air outlet of foam fractionation systems.
Keywords	air ; environment ; foams ; fractionation ; occupational health and safety ; perfluorocarbons ; perfluorooctane sulfonic acid ; sorption ; Per- and polyfluoroalkyl substances (PFAS) ; Water treatment ; Air emissions ; Foam fractionation ; Pilot-scale ; Remediation
Language	English
Dates of publication	2023-05
Publishing place	Elsevier B.V.
Document type	Article ; Online
Note	Use and reproduction
ZDB-ID	121506-1
ISSN	1879-1026 ; 0048-9697
ISSN (online)	1879-1026
ISSN	0048-9697
DOI	10.1016/j.scitotenv.2023.162050
Database	NAL-Catalogue (AGRICOLA)

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