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  1. Article ; Online: Relaxation dynamics of phase oscillators with generic heterogeneous coupling.

    Xu, Can / Jin, Xin / Wu, Yonggang

    Physical review. E

    2023  Volume 107, Issue 2-1, Page(s) 24206

    Abstract: The coupled phase oscillator model serves as a paradigm that has been successfully used to shed light on the collective dynamics occurring in large ensembles of interacting units. It was widely known that the system experiences a continuous (second-order) ...

    Abstract The coupled phase oscillator model serves as a paradigm that has been successfully used to shed light on the collective dynamics occurring in large ensembles of interacting units. It was widely known that the system experiences a continuous (second-order) phase transition to synchronization by gradually increasing the homogeneous coupling among the oscillators. As the interest in exploring synchronized dynamics continues to grow, the heterogeneous patterns between phase oscillators have received ample attention during the past years. Here, we consider a variant of the Kuramoto model with quenched disorder in their natural frequencies and coupling. Correlating these two types of heterogeneity via a generic weighted function, we systematically investigate the impacts of the heterogeneous strategies, the correlation function, and the natural frequency distribution on the emergent dynamics. Importantly, we develop an analytical treatment for capturing the essential dynamical properties of the equilibrium states. In particular, we uncover that the critical threshold corresponding to the onset of synchronization is unaffected by the location of the inhomogeneity, which, however, does depend crucially on the value of the correlation function at its center. Furthermore, we reveal that the relaxation dynamics of the incoherent state featuring the responses to external perturbations is significantly shaped by all the considered effects, thereby leading to various decaying mechanisms of the order parameters in the subcritical region. Moreover, we untangle that synchronization is facilitated by the out-coupling strategy in the supercritical region. Our study is a step forward in highlighting the potential importance of the inhomogeneous patterns involved in the complex systems, and could thus provide theoretical insights for profoundly understanding the generic statistical mechanical properties of the steady states toward synchronization.
    Language English
    Publishing date 2023-03-17
    Publishing country United States
    Document type Journal Article
    ZDB-ID 2844562-4
    ISSN 2470-0053 ; 2470-0045
    ISSN (online) 2470-0053
    ISSN 2470-0045
    DOI 10.1103/PhysRevE.107.024206
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Tandem Suzuki Polymerization/Heck Cyclization Reaction to Form Ladder-Type 9,9'-Bifluorenylidene-Based Conjugated Polymer.

    Zhu, Xiaoyan / Liu, Feng / Ba, Xinwu / Wu, Yonggang

    Polymers

    2023  Volume 15, Issue 16

    Abstract: The synthesis of ladder-type 9,9'-bifluorenylidene-based conjugated polymer is reported. Unlike the typical synthetic strategy, the new designed ladder-type conjugated polymer is achieved via tandem Suzuki polymerization/Heck cyclization reaction in one- ... ...

    Abstract The synthesis of ladder-type 9,9'-bifluorenylidene-based conjugated polymer is reported. Unlike the typical synthetic strategy, the new designed ladder-type conjugated polymer is achieved via tandem Suzuki polymerization/Heck cyclization reaction in one-pot. In the preparation process, Suzuki polymerization reaction occurred first and then the intramolecular Heck cyclization followed smoothly under the same catalyst Pd(PPh
    Language English
    Publishing date 2023-08-10
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2527146-5
    ISSN 2073-4360 ; 2073-4360
    ISSN (online) 2073-4360
    ISSN 2073-4360
    DOI 10.3390/polym15163360
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  3. Article ; Online: Synthesis of Fused-Ring Derivatives Containing Bifluorenylidene Units via Pd-Catalyzed Tandem Multistep Suzuki Coupling/Heck Cyclization Reaction.

    Zhu, Xiaoyan / Liu, Feng / Ba, Xinwu / Wu, Yonggang

    The Journal of organic chemistry

    2023  Volume 88, Issue 22, Page(s) 15964–15968

    Abstract: A series of bifluorenylidene derivatives has been facilely synthesized via a palladium-catalyzed tandem multistep Suzuki cross-coupling and Heck cyclization in one pot. The tandem reaction involves two sequential Suzuki couplings and a subsequent Heck ... ...

    Abstract A series of bifluorenylidene derivatives has been facilely synthesized via a palladium-catalyzed tandem multistep Suzuki cross-coupling and Heck cyclization in one pot. The tandem reaction involves two sequential Suzuki couplings and a subsequent Heck cyclization. The target products are obtained in good yields up to 94%. Even in an extended conjugated substrate, the anticipated products can be prepared.
    Language English
    Publishing date 2023-10-28
    Publishing country United States
    Document type Journal Article
    ZDB-ID 123490-0
    ISSN 1520-6904 ; 0022-3263
    ISSN (online) 1520-6904
    ISSN 0022-3263
    DOI 10.1021/acs.joc.3c01140
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  4. Article: Synthesis of Ladder-Type 9,9′-Bifluorenylidene-Based Conjugated Oligomers via a Pd-Catalyzed Tandem Suzuki Coupling/Heck Cyclization Approach

    Zhu, Xiaoyan / Liu, Feng / Ba, Xinwu / Wu, Yonggang

    Organic letters. 2022 July 29, v. 24, no. 31

    2022  

    Abstract: For new ladder-type oligomers and polymers with versatile and robust synthetic strategies, in this study, four fully conjugated ladder-type overcrowded 9,9′-bifluorenylidene-based compounds and oligomers (BFY1, BFY2, BFY3, and BFY4) were synthesized via ... ...

    Abstract For new ladder-type oligomers and polymers with versatile and robust synthetic strategies, in this study, four fully conjugated ladder-type overcrowded 9,9′-bifluorenylidene-based compounds and oligomers (BFY1, BFY2, BFY3, and BFY4) were synthesized via a Pd-catalyzed tandem Suzuki coupling/Heck cyclization reaction. By monomer screening and route optimization, the target products were obtained in high yields and characterized by ¹H and ¹³C NMR spectroscopy and high resolution mass spectroscopy.
    Keywords cyclization reactions ; mass spectrometry ; nuclear magnetic resonance spectroscopy
    Language English
    Dates of publication 2022-0729
    Size p. 5851-5854.
    Publishing place American Chemical Society
    Document type Article
    ISSN 1523-7052
    DOI 10.1021/acs.orglett.2c02418
    Database NAL-Catalogue (AGRICOLA)

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  5. Article: Deep Learning to Predict the Cell Proliferation and Prognosis of Non-Small Cell Lung Cancer Based on FDG-PET/CT Images.

    Hu, Dehua / Li, Xiang / Lin, Chao / Wu, Yonggang / Jiang, Hao

    Diagnostics (Basel, Switzerland)

    2023  Volume 13, Issue 19

    Abstract: 1) Background: Cell proliferation (Ki-67) has important clinical value in the treatment and prognosis of non-small cell lung cancer (NSCLC). However, current detection methods for Ki-67 are invasive and can lead to incorrect results. This study aimed to ...

    Abstract (1) Background: Cell proliferation (Ki-67) has important clinical value in the treatment and prognosis of non-small cell lung cancer (NSCLC). However, current detection methods for Ki-67 are invasive and can lead to incorrect results. This study aimed to explore a deep learning classification model for the prediction of Ki-67 and the prognosis of NSCLC based on FDG-PET/CT images. (2) Methods: The FDG-PET/CT scan results of 159 patients with NSCLC confirmed via pathology were analyzed retrospectively, and the prediction models for the Ki-67 expression level based on PET images, CT images and PET/CT combined images were constructed using Densenet201. Based on a Ki-67 high expression score (HES) obtained from the prediction model, the survival rate of patients with NSCLC was analyzed using Kaplan-Meier and univariate Cox regression. (3) Results: The statistical analysis showed that Ki-67 expression was significantly correlated with clinical features of NSCLC, including age, gender, differentiation state and histopathological type. After a comparison of the three models (i.e., the PET model, the CT model, and the FDG-PET/CT combined model), the combined model was found to have the greatest advantage in Ki-67 prediction in terms of AUC (0.891), accuracy (0.822), precision (0.776) and specificity (0.902). Meanwhile, our results indicated that HES was a risk factor for prognosis and could be used for the survival prediction of NSCLC patients. (4) Conclusions: The deep-learning-based FDG-PET/CT radiomics classifier provided a novel non-invasive strategy with which to evaluate the malignancy and prognosis of NSCLC.
    Language English
    Publishing date 2023-09-30
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2662336-5
    ISSN 2075-4418
    ISSN 2075-4418
    DOI 10.3390/diagnostics13193107
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  6. Article ; Online: Synthesis of Ladder-Type 9,9'-Bifluorenylidene-Based Conjugated Oligomers via a Pd-Catalyzed Tandem Suzuki Coupling/Heck Cyclization Approach.

    Zhu, Xiaoyan / Liu, Feng / Ba, Xinwu / Wu, Yonggang

    Organic letters

    2022  Volume 24, Issue 31, Page(s) 5851–5854

    Abstract: For new ladder-type oligomers and polymers with versatile and robust synthetic strategies, in this study, four fully conjugated ladder-type overcrowded 9,9'-bifluorenylidene-based compounds and oligomers ( ...

    Abstract For new ladder-type oligomers and polymers with versatile and robust synthetic strategies, in this study, four fully conjugated ladder-type overcrowded 9,9'-bifluorenylidene-based compounds and oligomers (
    Language English
    Publishing date 2022-07-29
    Publishing country United States
    Document type Journal Article
    ISSN 1523-7052
    ISSN (online) 1523-7052
    DOI 10.1021/acs.orglett.2c02418
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  7. Article ; Online: Partial locking in phase-oscillator populations with heterogenous coupling.

    Xu, Can / Wu, Yonggang / Zheng, Zhigang / Tang, Longkun

    Chaos (Woodbury, N.Y.)

    2022  Volume 32, Issue 6, Page(s) 63106

    Abstract: We consider a variant of the mean-field model of coupled phase oscillators with uniform distribution of natural frequencies. By establishing correlations between the quenched disorder of intrinsic frequencies and coupling strength with both in- and out- ... ...

    Abstract We consider a variant of the mean-field model of coupled phase oscillators with uniform distribution of natural frequencies. By establishing correlations between the quenched disorder of intrinsic frequencies and coupling strength with both in- and out-coupling heterogeneities, we reveal a generic criterion for the onset of partial locking that takes place in a domain with the coexistence of phase-locked oscillators and drifters. The critical points manifesting the instability of the stationary states are obtained analytically. In particular, the bifurcation mechanism of the equilibrium states is uncovered by the use of frequency-dependent version of the Ott-Antonsen reduction consistently with the analysis based on the self-consistent approach. We demonstrate that both the manner of coupling heterogeneity and correlation exponent have influence on the emergent patterns of partial locking. Our research could find applicability in better understanding the phase transitions and related collective phenomena involving synchronization control in networked systems.
    Language English
    Publishing date 2022-04-05
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1472677-4
    ISSN 1089-7682 ; 1054-1500
    ISSN (online) 1089-7682
    ISSN 1054-1500
    DOI 10.1063/5.0093318
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  8. Article: The stability and electronic and photocatalytic properties of the ZnWO₄ (010) surface determined from first-principles and thermodynamic calculations

    Wu, Yonggang / Zhang, Jihua / Long, Bingwei / Zhang, Hong

    RSC advances. 2021 July 05, v. 11, no. 38

    2021  

    Abstract: We present the results of the generalized-gradient approximation of Perdew, Burke and Ernzerhof (GGA-PBE) and the Heyd–Scuseria–Ernzerhof (HSE06) hybrid functional calculations of the atomic and the electronic structures of ZnWO₄ (010) surfaces. The ... ...

    Abstract We present the results of the generalized-gradient approximation of Perdew, Burke and Ernzerhof (GGA-PBE) and the Heyd–Scuseria–Ernzerhof (HSE06) hybrid functional calculations of the atomic and the electronic structures of ZnWO₄ (010) surfaces. The total energies obtained from these calculations are used to analyze the thermodynamic stability of the surfaces. The surface phase diagrams are constructed by surface Gibbs free energies obtained as a function of temperature and oxygen partial pressure. Our results suggested that the stable area of the surface terminations of ZnWO₄ (010) has little correlation with the functional selected. The stability phase diagram shows that O-Zn, DL-W, and DL-Zn terminations of ZnWO₄ (010) can be stabilized under certain thermodynamic equilibrium conditions. Based on the HSE06 hybrid functional, we calculate the electronic structures for three possible stability surface terminations. It is found that there is a fat band of the surface states in DL-W termination, which shows a delocalized feature. This fat band acts as an electron transition bridge between the valence band (VB) and conduction band (CB). It contributes to visible-light absorption by two-step optical transition with the first transition from the VB to the fat band and the second from the fat band to the CB. Significantly, the conduction band minimum (CBM) band edge position of DL-W termination is favourable for H₂ evolution as the CBM edge is located above the water reduction level (H⁺/H₂). Simultaneously, DL-W termination's valence band maximum (VBM) potential shows a strong potential for O₂ generation from water oxidation because of the higher VBM edge with respect to the water oxidation level (H₂O/O₂). These results may help explore ZnWO₄ (010) surfaces' intrinsic properties, providing a helpful strategy for experimental studies of ZnWO₄-based photocatalysts in the future.
    Keywords absorption ; light ; oxidation ; oxygen partial pressure ; photocatalysis ; photocatalysts ; physical phases ; temperature
    Language English
    Dates of publication 2021-0705
    Size p. 23477-23490.
    Publishing place The Royal Society of Chemistry
    Document type Article
    ISSN 2046-2069
    DOI 10.1039/d1ra03218f
    Database NAL-Catalogue (AGRICOLA)

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  9. Article ; Online: The Thermodynamic Stability, Electronic and Photocatalytic Properties of the ZnWO

    Wu, Yonggang / Zhang, Jihua / Long, Bingwei / Zhang, Hong

    ACS omega

    2021  Volume 6, Issue 23, Page(s) 15057–15067

    Abstract: Zinc tungstate ( ... ...

    Abstract Zinc tungstate (ZnWO
    Language English
    Publishing date 2021-06-03
    Publishing country United States
    Document type Journal Article
    ISSN 2470-1343
    ISSN (online) 2470-1343
    DOI 10.1021/acsomega.1c01214
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  10. Article ; Online: The stability and electronic and photocatalytic properties of the ZnWO

    Wu, Yonggang / Zhang, Jihua / Long, Bingwei / Zhang, Hong

    RSC advances

    2021  Volume 11, Issue 38, Page(s) 23477–23490

    Abstract: We present the results of the generalized-gradient approximation of Perdew, Burke and Ernzerhof (GGA-PBE) and the Heyd-Scuseria-Ernzerhof (HSE06) hybrid functional calculations of the atomic and the electronic structures of ... ...

    Abstract We present the results of the generalized-gradient approximation of Perdew, Burke and Ernzerhof (GGA-PBE) and the Heyd-Scuseria-Ernzerhof (HSE06) hybrid functional calculations of the atomic and the electronic structures of ZnWO
    Language English
    Publishing date 2021-07-05
    Publishing country England
    Document type Journal Article
    ISSN 2046-2069
    ISSN (online) 2046-2069
    DOI 10.1039/d1ra03218f
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