Article ; Online: A Thiol-Michael Approach Towards Versatile Functionalized Cyclic Titanium-Oxo Clusters.
Chemistry (Weinheim an der Bergstrasse, Germany)
2023 Volume 29, Issue 63, Page(s) e202302352
Abstract: In expanding our research activities of superlattice engineering, designing new giant molecules is the necessary first step. One attempt is to use inorganic transition metal clusters as building blocks. Efficient functionalization of chemically precise ... ...
| Abstract | In expanding our research activities of superlattice engineering, designing new giant molecules is the necessary first step. One attempt is to use inorganic transition metal clusters as building blocks. Efficient functionalization of chemically precise transition metal clusters, however, remains a great challenge to material scientists. Herein, we report an efficient thiol-Michael addition approach for the modifications of cyclic titanium-oxo cluster (CTOC). Several advantages, including high efficiency, mild reaction condition, capability of complete addition, high atom economy, as well as high functional group tolerance were demonstrated. This approach can afford high yields of fully functionalized CTOCs, which provides a powerful platform for achieving versatile functionalization of precise transition metal clusters and further applications. |
|---|---|
| Language | English |
| Publishing date | 2023-10-02 |
| Publishing country | Germany |
| Document type | Journal Article |
| ZDB-ID | 1478547-X |
| ISSN | 1521-3765 ; 0947-6539 |
| ISSN (online) | 1521-3765 |
| ISSN | 0947-6539 |
| DOI | 10.1002/chem.202302352 |
| Database | MEDical Literature Analysis and Retrieval System OnLINE |
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