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  1. Article ; Online: Synthesis of Phosphet-2-one Derivatives via Phosphinidene Transfer to Cyclopropenones.

    Xin, Tiansi / Cummins, Christopher C

    Journal of the American Chemical Society

    2023  Volume 145, Issue 48, Page(s) 25989–25994

    Abstract: We report the first synthesis and structural characterization of free, uncomplexed phosphet-2-ones. These unsaturated four-membered phosphacycles were prepared by phosphinidene transfer from dibenzo-7-phosphanorbornadiene compounds, ... ...

    Abstract We report the first synthesis and structural characterization of free, uncomplexed phosphet-2-ones. These unsaturated four-membered phosphacycles were prepared by phosphinidene transfer from dibenzo-7-phosphanorbornadiene compounds, RP
    Language English
    Publishing date 2023-11-27
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.3c11263
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Bonn / Germany

    Z 4' 55/32: Show issues
    Z 7.3: Show issues

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  2. Article: Mechanochemical Phosphorylation of Acetylides Using Condensed Phosphates: A Sustainable Route to Alkynyl Phosphonates.

    Xin, Tiansi / Cummins, Christopher C

    ACS central science

    2023  Volume 9, Issue 8, Page(s) 1575–1580

    Abstract: In pursuit of a more sustainable route to phosphorus-carbon (P-C) bond-containing chemicals, we herein report that phosphonates can be prepared by mechanochemical phosphorylation of acetylides using polyphosphates in a single step, redox-neutral process, ...

    Abstract In pursuit of a more sustainable route to phosphorus-carbon (P-C) bond-containing chemicals, we herein report that phosphonates can be prepared by mechanochemical phosphorylation of acetylides using polyphosphates in a single step, redox-neutral process, bypassing white phosphorus (P
    Language English
    Publishing date 2023-07-21
    Publishing country United States
    Document type Journal Article
    ISSN 2374-7943
    ISSN 2374-7943
    DOI 10.1021/acscentsci.3c00725
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Stabilized Molecular Diphosphorus Pentoxide, P

    Qian, Kevin / Shepard, Scott M / Xin, Tiansi / Park, Gyeongjin / Cummins, Christopher C

    Journal of the American Chemical Society

    2023  Volume 145, Issue 11, Page(s) 6045–6050

    Abstract: Commercial phosphorus pentoxide reacts with ... ...

    Abstract Commercial phosphorus pentoxide reacts with some
    Language English
    Publishing date 2023-03-13
    Publishing country United States
    Document type Journal Article
    ZDB-ID 3155-0
    ISSN 1520-5126 ; 0002-7863
    ISSN (online) 1520-5126
    ISSN 0002-7863
    DOI 10.1021/jacs.3c00211
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Bonn / Germany

    Z 4' 55/32: Show issues
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  4. Article: Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite.

    Zhai, Feng / Xin, Tiansi / Geeson, Michael B / Cummins, Christopher C

    ACS central science

    2022  Volume 8, Issue 3, Page(s) 332–339

    Abstract: In pursuit of a more sustainable production of phosphorous acid ( ... ...

    Abstract In pursuit of a more sustainable production of phosphorous acid (H
    Language English
    Publishing date 2022-02-14
    Publishing country United States
    Document type Journal Article
    ISSN 2374-7943
    ISSN 2374-7943
    DOI 10.1021/acscentsci.1c01381
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Rare Earth Metal Complexes Supported by a Tripodal Tris(amido) Ligand System Featuring an Arene Anchor.

    Xin, Tiansi / Wang, Xinrui / Yang, Kexin / Liang, Jiefeng / Huang, Wenliang

    Inorganic chemistry

    2021  Volume 60, Issue 20, Page(s) 15321–15329

    Abstract: A new tripodal tris(amido) ligand system featuring an arene anchor was developed and applied to the coordination chemistry of rare earth metals. Two tris(amido) ligands with a 1,3,5-triphenylbenzene backbone were prepared in two steps from commercially ... ...

    Abstract A new tripodal tris(amido) ligand system featuring an arene anchor was developed and applied to the coordination chemistry of rare earth metals. Two tris(amido) ligands with a 1,3,5-triphenylbenzene backbone were prepared in two steps from commercially available reagents on a gram scale. Salt metathesis and alkane elimination reactions were exploited to prepare mononuclear rare earth metal complexes in moderate to good yields. For salt metathesis reactions, while metal tribromides yielded neutral metal tris(amido) complexes, metal trichlorides led to the formation of ate complexes with an additional chloride bound to the metal center. The new compounds were characterized by X-ray crystallography, elemental analysis, and
    Language English
    Publishing date 2021-09-27
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.1c01922
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article: Synthesis of phosphiranes

    Xin, Tiansi / Geeson, Michael B / Zhu, Hui / Qu, Zheng-Wang / Grimme, Stefan / Cummins, Christopher C

    Chemical science

    2022  Volume 13, Issue 43, Page(s) 12696–12702

    Abstract: Herein is reported the structural characterization and scalable preparation of the elusive iron-phosphido complex FpP( ...

    Abstract Herein is reported the structural characterization and scalable preparation of the elusive iron-phosphido complex FpP(
    Language English
    Publishing date 2022-10-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 2559110-1
    ISSN 2041-6539 ; 2041-6520
    ISSN (online) 2041-6539
    ISSN 2041-6520
    DOI 10.1039/d2sc05011k
    Database MEDical Literature Analysis and Retrieval System OnLINE

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