Artikel ; Online: Custom-designed polyphenol lignin for the enhancement of poly(vinyl alcohol)-based wood adhesive.
International journal of biological macromolecules
2024 Band 258, Heft Pt 2, Seite(n) 129132
Abstract: Adhesives are used extensively in the wood industry. As resource and environmental issues become increasingly severe, the development of green and sustainable biomass-based adhesives has attracted increasing attention. In this work, a green wood adhesive ...
Abstract | Adhesives are used extensively in the wood industry. As resource and environmental issues become increasingly severe, the development of green and sustainable biomass-based adhesives has attracted increasing attention. In this work, a green wood adhesive is developed from poly(vinyl alcohol) and lignin with molecular designs of lignin extending beyond those in nature. The lignin undergoes extraction from corncob residue, aldehydration, and phenolisation (phenol, resorcinol, and catechol) to significantly increase the phenolic hydroxyl groups (over 7.92 mmol/g), which has the effect of enhancing the hydrogen bonding force between the adhesive and the wood, thereby greatly improving adhesive performance. Compared with pure PVA, polyphenol lignin-containing PVA showed improved adhesion strength and hydrophobicity. PVA/resorcinol-lignin has the significantly improved wood lap shear strength (6.27 MPa, 77.6 % improvement) and hydrophobicity (almost 100 % increase in wet shear strength). This research not only provides a green and high-performance alternative raw material for wood adhesives but also broadens the path for large-scale application of biomass. |
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Mesh-Begriff(e) | Polyphenols/analysis ; Lignin/chemistry ; Polyvinyl Alcohol ; Adhesives/chemistry ; Wood/chemistry ; Phenols/chemistry ; Methanol ; Polyvinyl Chloride ; Resorcinols |
Chemische Substanzen | Polyphenols ; Lignin (9005-53-2) ; Polyvinyl Alcohol (9002-89-5) ; Adhesives ; Phenols ; Methanol (Y4S76JWI15) ; Polyvinyl Chloride (9002-86-2) ; resorcinol (YUL4LO94HK) ; Resorcinols |
Sprache | Englisch |
Erscheinungsdatum | 2024-01-02 |
Erscheinungsland | Netherlands |
Dokumenttyp | Journal Article |
ZDB-ID | 282732-3 |
ISSN | 1879-0003 ; 0141-8130 |
ISSN (online) | 1879-0003 |
ISSN | 0141-8130 |
DOI | 10.1016/j.ijbiomac.2023.129132 |
Datenquelle | MEDical Literature Analysis and Retrieval System OnLINE |
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