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  1. Article ; Online: A highly augmented, (12,3)-connected Zr-MOF containing hydrated coordination sites for the catalytic transformation of gaseous CO

    Jin, Guanghua / Sensharma, Debobroto / Zhu, Nianyong / Vaesen, Sebastien / Schmitt, Wolfgang

    Dalton transactions (Cambridge, England : 2003)

    2019  Volume 48, Issue 41, Page(s) 15487–15492

    Abstract: A porous Zr-based MOF, [ ... ...

    Abstract A porous Zr-based MOF, [Zr
    Language English
    Publishing date 2019-07-10
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c9dt02117e
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Bio-inspired synthetic approaches: from hierarchical, hybrid supramolecular assemblies to CaCO

    Marzec, Bartosz / Zhang, Lei / Zhu, Nianyong / Schmitt, Wolfgang

    Dalton transactions (Cambridge, England : 2003)

    2017  Volume 46, Issue 19, Page(s) 6456–6463

    Abstract: A bio-inspired synthetic approach to unprecedented hybrid supramolecular assemblies [Ca( ... ...

    Abstract A bio-inspired synthetic approach to unprecedented hybrid supramolecular assemblies [Ca(Me
    Language English
    Publishing date 2017-05-16
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c7dt00914c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article: Accelerating water oxidation - a mixed Co/Fe polyoxometalate with improved turnover characteristics.

    Soriano-López, Joaquín / Steuber, Friedrich W / Mulahmetović, Muhamed / Besora, Maria / Clemente-Juan, Juan Modesto / O'Doherty, Mariah / Zhu, Nian-Yong / Hill, Craig L / Coronado, Eugenio / Poblet, Josep M / Schmitt, Wolfgang

    Chemical science

    2023  Volume 14, Issue 47, Page(s) 13722–13733

    Abstract: Water oxidation is a bottleneck reaction for the establishment of solar-to-fuel energy conversion systems. Earth-abundant metal-based polyoxometalates are promising heterogeneous water oxidation catalysts that can operate in a wide pH range. However, ... ...

    Abstract Water oxidation is a bottleneck reaction for the establishment of solar-to-fuel energy conversion systems. Earth-abundant metal-based polyoxometalates are promising heterogeneous water oxidation catalysts that can operate in a wide pH range. However, detailed structure-reactivity relationships are not yet comprehensively understood, hampering the design and synthesis of more effective polyoxometalate-based oxidation catalysts. Here we report the synthesis of an ordered, mixed-metal cobalt-iron Weakley archetype [Co
    Language English
    Publishing date 2023-10-31
    Publishing country England
    Document type Journal Article
    ZDB-ID 2559110-1
    ISSN 2041-6539 ; 2041-6520
    ISSN (online) 2041-6539
    ISSN 2041-6520
    DOI 10.1039/d3sc04002j
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: 2D Porphyrinic Metal-Organic Frameworks Featuring Rod-Shaped Secondary Building Units.

    Elliott, Rory / Ryan, Aoife A / Aggarwal, Aviral / Zhu, Nianyong / Steuber, Friedrich W / Senge, Mathias O / Schmitt, Wolfgang

    Molecules (Basel, Switzerland)

    2021  Volume 26, Issue 10

    Abstract: Metal-organic frameworks (MOFs) encompass a rapidly expanding class of materials with diverse potential applications including gas storage, molecular separation, sensing and catalysis. So-called 'rod MOFs', which comprise infinitely extended 1D secondary ...

    Abstract Metal-organic frameworks (MOFs) encompass a rapidly expanding class of materials with diverse potential applications including gas storage, molecular separation, sensing and catalysis. So-called 'rod MOFs', which comprise infinitely extended 1D secondary building units (SBUs), represent an underexplored subclass of MOF. Further, porphyrins are considered privileged ligands for MOF synthesis due to their tunable redox and photophysical properties. In this study, the Cu
    Language English
    Publishing date 2021-05-16
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 1413402-0
    ISSN 1420-3049 ; 1431-5165 ; 1420-3049
    ISSN (online) 1420-3049
    ISSN 1431-5165 ; 1420-3049
    DOI 10.3390/molecules26102955
    Database MEDical Literature Analysis and Retrieval System OnLINE

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    In stock of ZB MED Cologne/Königswinter

    Zs.MO 81: Show issues

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  5. Article ; Online: Flexible Metal-Organic Frameworks for Light-Switchable CO

    Sensharma, Debobroto / Zhu, Nianyong / Tandon, Swetanshu / Vaesen, Sebastien / Watson, Graeme W / Schmitt, Wolfgang

    Inorganic chemistry

    2019  Volume 58, Issue 15, Page(s) 9766–9772

    Abstract: We report the synthesis and characterization of two photoactive metal-organic frameworks (MOFs), ...

    Abstract We report the synthesis and characterization of two photoactive metal-organic frameworks (MOFs),
    Language English
    Publishing date 2019-07-09
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.9b00768
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article ; Online: Nanoimprint Lithography-Directed Self-Assembly of Bimetallic Iron-M (M=Palladium, Platinum) Complexes for Magnetic Patterning.

    Meng, Zhengong / Li, Guijun / Yiu, Sze-Chun / Zhu, Nianyong / Yu, Zhen-Qiang / Leung, Chi-Wah / Manners, Ian / Wong, Wai-Yeung

    Angewandte Chemie (International ed. in English)

    2020  Volume 59, Issue 28, Page(s) 11521–11526

    Abstract: Self-assembly of ... ...

    Abstract Self-assembly of d
    Language English
    Publishing date 2020-05-07
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2011836-3
    ISSN 1521-3773 ; 1433-7851
    ISSN (online) 1521-3773
    ISSN 1433-7851
    DOI 10.1002/anie.202002685
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Introduction of luminescent rhenium(I), ruthenium(II), iridium(III) and rhodium(III) systems into rhodamine-tethered ligands for the construction of bichromophoric chemosensors.

    Wang, Chunyan / Lam, Ho-Chuen / Zhu, Nianyong / Wong, Keith Man-Chung

    Dalton transactions (Cambridge, England : 2003)

    2015  Volume 44, Issue 34, Page(s) 15250–15263

    Abstract: Several classes of luminescent transition metal complexes, including rhenium(I) tricarbonyl diimine, ruthenium(II) diimine, cyclometallated iridium(III) and rhodium(III) diimine, as well as ruthenium(II) and iridium(III) terpyridine systems, tethered ... ...

    Abstract Several classes of luminescent transition metal complexes, including rhenium(I) tricarbonyl diimine, ruthenium(II) diimine, cyclometallated iridium(III) and rhodium(III) diimine, as well as ruthenium(II) and iridium(III) terpyridine systems, tethered with rhodamine moieties, have been synthesized and characterized. The X-ray crystal structure of one cyclometallated rhodium(III) diimine (11) with a rhodamine pendant was determined. Most of the complexes were found to exhibit emission in fluid solution at room temperature. Depending on the nature of the transition metal system, the emission origin was mainly assigned to be derived from the triplet excited state of the metal-to-ligand charge transfer ((3)MLCT) or the intraligand ((3)IL) transition. The cation-binding properties of these complexes toward various cations were investigated by electronic absorption and emission spectroscopy. Some of them were found to exhibit new low-energy absorption and emission bands, attributed to the ring opening of the rhodamine moiety, with high selectivity and/or high sensitivity for various cations, in agreement with sensing and spectroscopic behaviours of the rhodamine derivative. Depending on the nature of the transition metal centres, the chelating ligands as well as the linker to the rhodamine derivative, different sensing properties in terms of selectivity, sensitivity and binding stability, could be obtained.
    Language English
    Publishing date 2015-09-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472887-4
    ISSN 1477-9234 ; 1364-5447 ; 0300-9246 ; 1477-9226
    ISSN (online) 1477-9234 ; 1364-5447
    ISSN 0300-9246 ; 1477-9226
    DOI 10.1039/c5dt00661a
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Luminescent metallogels of bis-cyclometalated alkynylgold(III) complexes.

    Au, Vonika Ka-Man / Zhu, Nianyong / Yam, Vivian Wing-Wah

    Inorganic chemistry

    2013  Volume 52, Issue 2, Page(s) 558–567

    Abstract: A series of luminescent bis-cyclometalated alkynylgold(III) complexes have been synthesized and characterized. Some of the complexes have been demonstrated to exhibit gelation properties driven by π-π stacking and hydrophobic-hydrophobic interactions. ... ...

    Abstract A series of luminescent bis-cyclometalated alkynylgold(III) complexes have been synthesized and characterized. Some of the complexes have been demonstrated to exhibit gelation properties driven by π-π stacking and hydrophobic-hydrophobic interactions. The gelation properties have been investigated in detail through variable-temperature UV-vis absorption and emission studies, and the morphology of the gels has also been characterized by scanning electron microscopy and transmission electron microscopy.
    Language English
    Publishing date 2013-01-18
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/ic3007519
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Extending the family of Zn-based MOFs: synthetic approaches to chiral framework structures and MOFs with large pores and channels.

    Zhu, Nianyong / Tobin, Gerard / Schmitt, Wolfgang

    Chemical communications (Cambridge, England)

    2012  Volume 48, Issue 30, Page(s) 3638–3640

    Abstract: Tri- and pentanuclear, kinetically stable SBUs were exploited for the preparation of the novel MOFs [Zn(3)(BTEB)(2)(DMF)(2)] and (Me(2)NH(2))[Zn(5)(BTEB)(3)(μ(3)-OH)(2)(DMF)(2)]. The applied synthetic approach results in topologies that are stabilised by ...

    Abstract Tri- and pentanuclear, kinetically stable SBUs were exploited for the preparation of the novel MOFs [Zn(3)(BTEB)(2)(DMF)(2)] and (Me(2)NH(2))[Zn(5)(BTEB)(3)(μ(3)-OH)(2)(DMF)(2)]. The applied synthetic approach results in topologies that are stabilised by tritopic benzene-trisethynylbenzoic acid (BTEB) linkers giving rise to chiral frameworks with large pores or channels.
    Language English
    Publishing date 2012-04-14
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/c2cc17357c
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Polymorphism of metal-organic frameworks: direct comparison of structures and theoretical N₂-uptake of topological pto- and tbo-isomers.

    Zhu, Nianyong / Lennox, Matthew J / Düren, Tina / Schmitt, Wolfgang

    Chemical communications (Cambridge, England)

    2014  Volume 50, Issue 32, Page(s) 4207–4210

    Abstract: The syntheses, calculated surface areas and N2 uptakes of two highly augmented {Cu}2 'paddlewheel'-based MOFs provide a direct comparison of tbo and pto framework polymorphs with identical composition. ...

    Abstract The syntheses, calculated surface areas and N2 uptakes of two highly augmented {Cu}2 'paddlewheel'-based MOFs provide a direct comparison of tbo and pto framework polymorphs with identical composition.
    Language English
    Publishing date 2014-04-25
    Publishing country England
    Document type Journal Article
    ZDB-ID 1472881-3
    ISSN 1364-548X ; 1359-7345 ; 0009-241X
    ISSN (online) 1364-548X
    ISSN 1359-7345 ; 0009-241X
    DOI 10.1039/c3cc49829h
    Database MEDical Literature Analysis and Retrieval System OnLINE

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