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  1. Article: Research on the Method of Reducing Dynamic Cutting Force in Aspheric Machining.

    Zhuang, Guilin / Liu, Hanzhong / Zong, Wenjun

    Micromachines

    2023  Volume 14, Issue 5

    Abstract: With the rapid development of photoelectric communication and other fields, the demand for high-precision aspheric mirrors has been increasing. Predicting dynamic cutting forces is vital in selecting machining parameters and also affects the surface ... ...

    Abstract With the rapid development of photoelectric communication and other fields, the demand for high-precision aspheric mirrors has been increasing. Predicting dynamic cutting forces is vital in selecting machining parameters and also affects the surface quality of the machined surface. This study comprehensively considers the effects of different cutting parameters and workpiece shape parameters on dynamic cutting force. The actual width of cut, depth of cut, and shear angle are modelled while considering the effects of vibration. A dynamic cutting-force model considering the aforementioned factors is then established. Using experimental results, the model accurately predicts the average value of dynamic cutting force under different parameters and the range of fluctuation of dynamic cutting force, with a controlled relative error of about 15%. The influence of workpiece shape and workpiece radial size on dynamic cutting force is also considered. The experimental results show that the greater the surface slope, the more dramatic the dynamic cutting force fluctuations. This lays the foundation for subsequent writing on vibration suppression interpolation algorithms. The influence of the radius of the tool tip on dynamic cutting forces leads to the conclusion that to achieve the goal of reducing the fluctuation of cutting forces, diamond tools with different parameters should be selected for different feed rates. Finally, a new interpolation-point planning algorithm is used to optimize the position of interpolation points in the machining process. This proves the reliability and practicability of the optimization algorithm. The results of this study are of great significance to the processing of high-reflectivity spherical/aspheric surfaces.
    Language English
    Publishing date 2023-04-28
    Publishing country Switzerland
    Document type Journal Article
    ZDB-ID 2620864-7
    ISSN 2072-666X
    ISSN 2072-666X
    DOI 10.3390/mi14050960
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  2. Article ; Online: Influence of cutting parameters on system vibration and optical performance of diamond turned optics.

    Zhuang, Guilin / Liu, Hanzhong / Zong, Wenjun

    Applied optics

    2023  Volume 62, Issue 18, Page(s) 4978–4986

    Abstract: In this paper the influence of vibration on reflectivity is systematically analyzed. A three-dimensional topography model of a machined surface considering vibration is established first. Based on the three-dimensional morphology model, the reflectivity ... ...

    Abstract In this paper the influence of vibration on reflectivity is systematically analyzed. A three-dimensional topography model of a machined surface considering vibration is established first. Based on the three-dimensional morphology model, the reflectivity of a diamond turned surface is calculated by a rigorous coupled wave method. The influences of cutting parameters on the diffraction effect of a diamond turned surface are discussed. The predicted and experimental results reveal that as the vibration intensifies with an increase in cutting depth and feed rate, the peak-valley (PV) roughness of the machined surface increases, which yields an increasing diffraction effect, i.e., resulting in a decrease in reflectivity. When the spindle speed is low, the tool and workpiece have a small sliding velocity, causing a great deal of friction, which amplifies the deformation of the workpiece surface. In this case, the PV value of the machined surface roughness is large, leading to a greater diffraction effect and bad reflectivity. With the increment of spindle rotation speed, the friction is relieved quickly, but the vibration is intensified, which produces increasing reflectivity. When the spindle speed is set to about 1200r/min, the reflectivity reaches the maximum value. When the spindle speed is larger than 1200r/min, the increase of vibration is dominant, resulting in a gradual increase in PV surface roughness and a decrease in reflectivity.
    Language English
    Publishing date 2023-09-14
    Publishing country United States
    Document type Journal Article
    ISSN 1539-4522
    ISSN (online) 1539-4522
    DOI 10.1364/AO.491374
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  3. Article ; Online: Plastic side flow and elastic recovery influences on optical diffraction effect of diamond turning: theoretical simulation and experimental verification.

    Zhuang, Guilin / Liu, Hanzhong / Zong, Wenjun

    Applied optics

    2023  Volume 62, Issue 16, Page(s) 4187–4196

    Abstract: Spherical/aspherical mirrors are widely used in optical systems and imaging systems, but their reflectivity is affected by the surface roughness. In this study, the effects of plastic side flow and elastic recovery on the diffraction phenomenon and ... ...

    Abstract Spherical/aspherical mirrors are widely used in optical systems and imaging systems, but their reflectivity is affected by the surface roughness. In this study, the effects of plastic side flow and elastic recovery on the diffraction phenomenon and reflectivity are analyzed systematically. The energy ratio of an ultra-precision turning surface is calculated by rigorous coupled-wave method, the influence of aberration on diffraction efficiency is considered in combination with the specific structural parameters of spherical/aspherical surface, and the appropriate measuring beam diameter is selected. Through predicted results and experimental observations, it can be found that with the increase of plastic side flow height, the energy ratio of zero-order diffracted light reduces, the brightness weakens, and the diffraction light spots become more obvious. This is because large plastic side flow height leads to more complex three-dimensional surface topography and great roughness P-V value. The influence of elastic recovery on the reflectivity is different from that of plastic side flow. As the elastic recovery increases, the roughness P-V value lessens. As a result, the energy ratio of zero-order diffracted light enlarges, and the brightness strengthens. This paper provides a theoretical basis for machining of spherical/aspheric mirrors with high reflectivity.
    Language English
    Publishing date 2023-09-14
    Publishing country United States
    Document type Journal Article
    ISSN 1539-4522
    ISSN (online) 1539-4522
    DOI 10.1364/AO.491979
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  4. Article ; Online: An unexpected dual-emissive luminogen with tunable aggregation-induced emission and enhanced chiroptical property.

    Zhang, Xinyu / Liu, Huiqing / Zhuang, Guilin / Yang, Shangfeng / Du, Pingwu

    Nature communications

    2022  Volume 13, Issue 1, Page(s) 3543

    Abstract: In the literature, organic materials with both aggregation-induced emission (AIE) and aggregation-caused quenching (ACQ) effects that can emit with multiple bands both in the solution and aggregated state are rarely reported. Herein we report a novel ... ...

    Abstract In the literature, organic materials with both aggregation-induced emission (AIE) and aggregation-caused quenching (ACQ) effects that can emit with multiple bands both in the solution and aggregated state are rarely reported. Herein we report a novel chiral dual-emissive bismacrocycle with tunable aggregation-induced emission colors. A facile four-step synthesis strategy is developed to construct this rigid bismacrocycle, (1,4)[8]cycloparaphenylenophane (SCPP[8]), which possesses a 1,2,4,5-tetraphenylbenzene core locked by two intersecting polyphenylene-based macrocycles. The luminescent behavior of SCPP[8] shows the unique characteristics of both ACQ effect and AIE effect, inducing remarkable redshift emission with near white-light emission. SCPP[8] is configurationally stable and possesses a novel shape-persistent bismacrocycle scaffold with a high strain energy. In addition, SCPP[8] displays enhanced circularly polarized luminescence properties due to AIE effect.
    Language English
    Publishing date 2022-06-21
    Publishing country England
    Document type Journal Article
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-022-31281-9
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  5. Article ; Online: Effect of Orbital-Symmetry Matching in a Metal-Organic Framework for Highly Efficient C

    Chen, Jing / Wu, Jing / Zhuang, Guilin / Li, Bao / Li, Jia

    Inorganic chemistry

    2022  Volume 61, Issue 27, Page(s) 10263–10266

    Abstract: The detailed mechanism of metal-organic-framework (MOF)-based separation materials is still obscure, which obviously hinders their actual application. To address this problem, a trinuclear Cu-cluster-based MOF with a minimum metal-active plane was ... ...

    Abstract The detailed mechanism of metal-organic-framework (MOF)-based separation materials is still obscure, which obviously hinders their actual application. To address this problem, a trinuclear Cu-cluster-based MOF with a minimum metal-active plane was synthesized for the study of the very challenging C
    Language English
    Publishing date 2022-06-29
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.2c01218
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  6. Article: Regulating supramolecular interactions in dimeric macrocycles.

    Fang, Pengwei / Chen, Muqing / Yin, Nan / Zhuang, Guilin / Chen, Tianyun / Zhang, Xinyu / Du, Pingwu

    Chemical science

    2023  Volume 14, Issue 20, Page(s) 5425–5430

    Abstract: Supramolecular behavior is highly dependent on many factors, including complicated microenvironments and weak interactions. Herein, we describe tuning supramolecular architectures of rigid macrocycles by synergistic effects of their geometric ... ...

    Abstract Supramolecular behavior is highly dependent on many factors, including complicated microenvironments and weak interactions. Herein, we describe tuning supramolecular architectures of rigid macrocycles by synergistic effects of their geometric configurations, sizes, and guests. Two paraphenylene-based macrocycles are anchored onto different positions in a triphenylene derivative, resulting in dimeric macrocycles with different shapes and configurations. Interestingly, these dimeric macrocycles show tunable supramolecular interactions with guests. In solid state, a 2 : 1 host-guest complex was observed between 1a and C
    Language English
    Publishing date 2023-04-26
    Publishing country England
    Document type Journal Article
    ZDB-ID 2559110-1
    ISSN 2041-6539 ; 2041-6520
    ISSN (online) 2041-6539
    ISSN 2041-6520
    DOI 10.1039/d3sc00035d
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  7. Article ; Online: Electrocatalytic Overall Water Splitting Induced by Surface Reconstruction of an Iron-Modified Ni

    Chen, Qiong / Yu, Yifan / Zhou, Shuo / Sha, Linna / Zhuang, Guilin / Wang, Po / Han, Xiguang

    Inorganic chemistry

    2023  Volume 62, Issue 16, Page(s) 6518–6526

    Abstract: Reasonable development of high-efficiency and robust electrocatalysts for efficient electrocatalytic water splitting at high current density is hopeful for renewable energy, but the real challenge is substituting the precious metal catalysts. Herein, ... ...

    Abstract Reasonable development of high-efficiency and robust electrocatalysts for efficient electrocatalytic water splitting at high current density is hopeful for renewable energy, but the real challenge is substituting the precious metal catalysts. Herein, ultrathin Fe-modified Ni
    Language English
    Publishing date 2023-04-11
    Publishing country United States
    Document type Journal Article
    ZDB-ID 1484438-2
    ISSN 1520-510X ; 0020-1669
    ISSN (online) 1520-510X
    ISSN 0020-1669
    DOI 10.1021/acs.inorgchem.3c00703
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  8. Article ; Online: Axially Coordinated Gold Nanoclusters Tailoring Fe-N-C Nanozymes for Enhanced Oxidase-Like Specificity and Activity.

    Xie, Yameng / Sun, Fuli / Chang, Kuan / Li, Guang / Song, Zhijia / Huang, Jiayu / Cheng, Xiqing / Zhuang, Guilin / Kuang, Qin

    Advanced science (Weinheim, Baden-Wurttemberg, Germany)

    2024  Volume 11, Issue 11, Page(s) e2306911

    Abstract: Metal-organic frameworks (MOF) derived nitrogen-doped carbon-supported monodisperse Fe (Fe-N-C) catalysts are intensively studied, but great challenges remain in understanding the relationship between the coordination structure and the performance of Fe- ... ...

    Abstract Metal-organic frameworks (MOF) derived nitrogen-doped carbon-supported monodisperse Fe (Fe-N-C) catalysts are intensively studied, but great challenges remain in understanding the relationship between the coordination structure and the performance of Fe-N-C nanozymes. Herein, a novel nanocluster ligand-bridging strategy is proposed for constructing Fe-S
    MeSH term(s) Acetylcholinesterase ; Gold/chemistry ; Ligands ; Oxidoreductases
    Chemical Substances Acetylcholinesterase (EC 3.1.1.7) ; Gold (7440-57-5) ; Ligands ; Oxidoreductases (EC 1.-)
    Language English
    Publishing date 2024-01-09
    Publishing country Germany
    Document type Journal Article
    ZDB-ID 2808093-2
    ISSN 2198-3844 ; 2198-3844
    ISSN (online) 2198-3844
    ISSN 2198-3844
    DOI 10.1002/advs.202306911
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  9. Article ; Online: Anomalous anti-Kasha excited-state luminescence from symmetry-breaking heterogeneous carbon bisnanohoops.

    Zhang, Xinyu / Chen, Cheng / Zhang, Wen / Yin, Nan / Yuan, Bing / Zhuang, Guilin / Wang, Xiao-Ye / Du, Pingwu

    Nature communications

    2024  Volume 15, Issue 1, Page(s) 2684

    Abstract: It is a long-standing scientific controversy to achieve anti-Kasha-type multiple emissions by tuning the structures at a molecular level. Although it is known that some conjugated structures have excitation-dependent multiple emissions, no all-benzenoid ... ...

    Abstract It is a long-standing scientific controversy to achieve anti-Kasha-type multiple emissions by tuning the structures at a molecular level. Although it is known that some conjugated structures have excitation-dependent multiple emissions, no all-benzenoid molecules have yet been reported, the emissions of which originate from different excited states. Herein, we report the design of two symmetry-breaking heterogeneous carbon bisnanohoops that in solution become multiple fluorescent emitters with unusual anti-Kasha characteristics. This phenomenon can be spectroscopically and theoretically explained and will find applications in a wide range of sensing and imaging technologies.
    Language English
    Publishing date 2024-03-27
    Publishing country England
    Document type Journal Article
    ZDB-ID 2553671-0
    ISSN 2041-1723 ; 2041-1723
    ISSN (online) 2041-1723
    ISSN 2041-1723
    DOI 10.1038/s41467-024-46848-x
    Database MEDical Literature Analysis and Retrieval System OnLINE

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  10. Article ; Online: Visible-Light Photocatalytic Overall Water Splitting on a B

    Lin, Cun-Biao / Sheng, Yin-Xiao / Sun, Fu-Li / Chen, Wen-Xian / Zhuang, Gui-Lin

    The journal of physical chemistry letters

    2023  Volume 14, Issue 50, Page(s) 11447–11456

    Abstract: Herein, combining density functional theory (DFT) calculations with nonadiabatic molecular dynamics (NAMD), we built a computational framework to rationally screen from a series of 2D conjugated carbon nitrides (CNs) to match with ... ...

    Abstract Herein, combining density functional theory (DFT) calculations with nonadiabatic molecular dynamics (NAMD), we built a computational framework to rationally screen from a series of 2D conjugated carbon nitrides (CNs) to match with B
    Language English
    Publishing date 2023-12-12
    Publishing country United States
    Document type Journal Article
    ISSN 1948-7185
    ISSN (online) 1948-7185
    DOI 10.1021/acs.jpclett.3c02784
    Database MEDical Literature Analysis and Retrieval System OnLINE

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